The synthesis and characterisation of [Pd(S2CNEt2)(Ph2PCH2CH2PPh2)](+) salts of some chloro- and bromo-metallate anions - X-ray crystal structure of [Pd(S2CNEt2)(Ph2PCH2CH2PPh2)](+)[MCl2](-) (M = Cu, Ag)

Exarchos G.; Robinson SD.; Nyburg SC.

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The synthesis and characterisation of [Pd(S2CNEt2)(Ph2PCH2CH2PPh2)](+) salts of some chloro- and bromo-metallate anions - X-ray crystal structure of [Pd(S2CNEt2)(Ph2PCH2CH2PPh2)](+)[MCl2](-) (M = Cu, Ag)

机译：某些氯和溴化金属阴离子的[Pd（S2CNEt2）（Ph2PCH2CH2PPh2）]（+）盐的合成和表征-[Pd（S2CNEt2）（Ph2PCH2CH2PPh2）]（+）[MCl2]（X射线晶体结构） -）（M =铜，银）

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The palladium complex [PdCl2(PhCN)(2)] reacts readily with metal bis(dialkyl dithiocarbamates) [M(S2CNR2)(2)] (M = Pb, Zn, Cd, Hg, Cu, Ni, MoO2, VO, R = Et, Bu-n), in refluxing dichloromethane, to afford the known complexes [{PdCl(S2CNR2)}(2)] in virtually quantitative yield. In boiling acetonitrile the diphosphine complexes [PdX2(Ph2PCH2CH2PPh2)] (X = Cl, Br) react readily with bi-and trivalent metal diethyl dithiocarbamates [M(S2CNEt2)(n)] (M = Pb, Zn, Cd, Hg, Ni, MoO2, VO n = 2; M = Co, Fe, Mn, n = 3) to afford salts of the general form [Pd(S2CNEt2) (Ph2PCH2CH2PPh2)](2)(+) [MX4](2-). Diethyl dithiocarbamates of copper(II) and silver(I) form salts of the [Pd(S2CNEt2)(Ph2PCH2CH2PPh2)](+) cation containing linear [CuX2](-) and [AgX2](-) anions respectively (X = Cl, Br). The X-ray crystal structures of [Pd(S2CNEt2) (Ph2PCH2CH2PPh2)][CuCl2] and [Pd(S2CNEt2) (Ph2PCH2CH2PPh2)][AgCl2] . 0.5CH(2)Cl(2) are reported. (C) 1998 Elsevier Science Ltd. All rights reserved. [References: 23]

机译：钯络合物[PdCl2（PhCN）（2）]与金属双（二烷基二硫代氨基甲酸酯）[M（S2CNR2）（2）]容易反应（M = Pb，Zn，Cd，Hg，Cu，Ni，MoO2，VO，R ＝ Et，Bu-n），在回流的二氯甲烷中，以实际上定量的产率得到已知的络合物[{PdCl（S2CNR2）}（2）]。在沸腾的乙腈中，二膦配合物[PdX2（Ph2PCH2CH2PPh2）]（X = Cl，Br）容易与二价和三价金属二乙基二硫代氨基甲酸酯[M（S2CNEt2）（n）]（M = Pb，Zn，Cd，Hg，Ni ，MoO 2，VO n ＝ 2; M ＝ Co，Fe，Mn，n ＝ 3）得到通式[Pd（S 2 CNEt 2）（Ph 2 PCH 2 CH 2 PPh 2）（2）（+）[MX4]（2-）的盐。铜（II）和银（I）的二乙基二硫代氨基甲酸酯分别形成[Pd（S2CNEt2）（Ph2PCH2CH2PPh2）]（+）阳离子的盐，它们分别包含线性[CuX2]（-）和[AgX2]（-）阴离子（X = Cl ，Br）。 [Pd（S2CNEt2）（Ph2PCH2CH2PPh2）] [CuCl2]和[Pd（S2CNEt2）（Ph2PCH2CH2PPh2）] [AgCl2]的X射线晶体结构。报告了0.5CH（2）Cl（2）。（C）1998 Elsevier ScienceLtd。保留所有权利。 [参考：23]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1998年第8期|共10页
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Exarchos G.; Robinson SD.; Nyburg SC.;
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1. The synthesis and characterisation of [Pd(S2CNEt2)(Ph2PCH2CH2PPh2)](+) salts of some chloro- and bromo-metallate anions - X-ray crystal structure of [Pd(S2CNEt2)(Ph2PCH2CH2PPh2)](+)[MCl2](-) (M = Cu, Ag) [J] . Exarchos G., Robinson SD., Nyburg SC. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第8期

机译：某些氯和溴化金属阴离子的[Pd（S2CNEt2）（Ph2PCH2CH2PPh2）]（+）盐的合成和表征-[Pd（S2CNEt2）（Ph2PCH2CH2PPh2）]（+）[MCl2]（X射线晶体结构） -）（M =铜，银）
2. The synthesis of new bimetallic complex salts by halide/sulfur chelate cross transfer: X-ray crystal structures of the salts [Ni(S2CNEt2)(dppe)](2)[HgBr4], [Pt(S2CNEt2)(dppe)](2)[CdCl4], [Co(S2CNEt2)(2)(dppe)](2)[Cl3ZnO :(Ph)(2)PCH2CH2P(Ph)(2): OZnCl [J] . Exarchos G., Steed JW., Robinson SD. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2001,第24a25期

机译：卤化物/硫螯合物交叉转移合成新的双金属络合物盐：盐的X射线晶体结构[Ni（S2CNEt2）（dppe）]（2）[HgBr4]，[Pt（S2CNEt2）（dppe）]（2 ）[CdCl4]，[Co（S2CNEt2）（2）（dppe）]（2）[Cl3ZnO：（Ph）（2）PCH2CH2P（Ph）（2）：OZnCl
3. The synthesis and characterization of Ni, Pd and Pt maleonitriledithiolate complexes: X-ray crystal structures of the isomorphous Ni, Pd and Pt (Ph2PCH2CH2PPh2)M(maleonitriledithiolate) congeners [J] . Landis KG., Wagner TR., Curtin LS., Inorganica Chimica Acta . 1998,第2期

机译：Ni，Pd和Pt顺丁烯二腈金属盐配合物的合成与表征：Ni，Pd和Pt（Ph2PCH2CH2PPh2）M（顺丁烯二硫氰酸盐）同系物的X射线晶体结构
4. Synthesis and Crystal Structure of μ3-H(Ph)C=CFeCo2(CO)7dppe(deep=Ph2PCH2CH2PPh2) and (μ3-S)FeCo2(CO)7dppfe(dppfe= Ph2PC5H4PPh2) [C] . Yibin Wang 11th International Symposium of Fine Chemistry and Functional Polymers Jul 28-31, 2001 Hailar, Inner Mongolia, P.R. China . 2001

机译：μ3-H（Ph）C = C FeCo2（CO）7dppe（深= Ph2PCH2CH2PPh2）和（μ3-S）FeCo2（CO）7dppfe（dppfe = Ph2PC5H4PPh2）的合成和晶体结构
5. Synthesis of Pd-Cu Nanostructures by Seed-Mediated Co-Reduction [D] . Kunz, Meredith R. 2017

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机译：22-二甲基戊二酸（2dmepdaH2）和33-二甲基戊二酸（3dmepdaH2）的金属配合物的合成超氧化物歧化酶模拟和抗癌活性：Cu（3dmepda）（bipy） 2·6H2O的X射线晶体结构和Cu（2dmepda）（bipy）（EtOH） 2·4EtOH（Bipy = 22联吡啶）
7. Synthesis, Superoxide Dismutase Mimetic and Anticancer Activities of Metal Complexes of 2,2-Dimethylpentanedioic Acid(2dmepdaH2) and 3,3-Dimethylpentanedioic acid(3dmepdaH2): X-Ray Crystal Structures of [Cu(3dmepda)(bipy)]2· 6H2O and [Cu(2dmepda)(bipy)(EtOH)]2· 4EtOH (bipy = 2,2′Bipyridine) [O] . Devereux, Michael, McCann, Malachy, O'Shea, Denis, 2006

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机译：氟 - 羟基磷腈阴离子的合成，反应性和电子结构：（Li（THF）3）（N3p3F2H（BeT3）（eta-C5H4）2Fe）的X射线晶体结构

The synthesis and characterisation of [Pd(S2CNEt2)(Ph2PCH2CH2PPh2)](+) salts of some chloro- and bromo-metallate anions - X-ray crystal structure of [Pd(S2CNEt2)(Ph2PCH2CH2PPh2)](+)[MCl2](-) (M = Cu, Ag)

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