About the existence of Th(III) in aqueous solution

Ionova G.; Guillaumont R.; Madic C.

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About the existence of Th(III) in aqueous solution

机译：关于水溶液中Th（III）的存在

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Recently [1] it was claimed that (i) the reaction of ThCl4 with HN3 in slightly acidic aqueous solution produces the aqueous ion of Th(III) according to the thermodynamically-allowed reaction: Th4+ + HN3 --> Th3+ + 1.5N(2) + H+; (ii) Th(III) was identified by its absorption (UV-vis. 200-1300 nm) and ESR spectra. This paper is aimed to prove that the aqueous ion Th3+ (ag) is thermodynamically unstable and that the identification of Th(III) in the considered solutions ask for new experiments. (C) 1998 Elsevier Science Ltd. All rights reserved. [References: 22]

机译：最近[1]声称（i）根据热力学允许的反应，ThCl4与HN3在微酸性水溶液中的反应生成Th（III）的水离子：Th4 + + HN3-> Th3 + + 1.5N（ 2）+ H +; （ii）Th（III）由其吸收（紫外可见200-1300 nm）和ESR光谱鉴定。本文旨在证明水离子Th3 +（ag）在热力学上是不稳定的，并且在考虑的溶液中鉴定Th（III）要求进行新的实验。（C）1998 Elsevier ScienceLtd。保留所有权利。 [参考：22]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1998年第12期|共5页
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Ionova G.; Guillaumont R.; Madic C.;
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中图分类化学;无机化学;
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1. About the existence of Th(III) in aqueous solution [J] . Ionova G., Guillaumont R., Madic C. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第11a12期

机译：关于水溶液中Th（III）的存在
2. Studies of the Equilibria of Complexes of Pr(III), Nd(III), Eu(III), Gd(III), Dy(III) and Er(III) with Quercetin-5'-sulfonic Acid in Aqueous Solutions [J] . M.Kopacz, B.Bujonek, D.Nowak, Chemia Analityczna . 2001,第5期

机译：Pr（III），Nd（III），Eu（III），Gd（III），Dy（III）和Er（III）与槲皮素5'-磺酸的水溶液的平衡平衡研究
3. Highly efficient near-infrared-emitting lanthanide(III) complexes formed by heterogeneous self-assembly of Ag ~I, Ln ~(III), and thiacalix[4]arene-p-tetrasulfonate in aqueous solution (Ln ~(III) = Nd ~(III), Yb ~(III)) [J] . Iki N., Hiro-Oka S., Tanaka T., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2012,第3期

机译：Ag〜I，Ln〜（III）和硫代杯[4]芳烃-对-四磺酸盐在溶液中的异质自组装形成的高效近红外发射镧系元素（Ln〜（III）= Nd 〜（III），Yb〜（III））
4. Facilitated Extraction of Fe~(III) from the Aqueous Fe~(III)/Cu~(II) Solution [C] . B. Zhang, G. Gozzelino International symposium on membrane technology and environmental protection . 2000

机译：从Fe〜（III）/ Cu〜（II）水溶液中轻松提取Fe〜（III）
5. I. THE ELECTROCHEMISTRY OF NITRIC OXIDE AND A NITROUS ACID AT A MERCURY ELECTRODE IN AQUEOUS SOLUTIONS. II. ELECTROCHEMISTRY AND HYDROLYSIS KINETICS OF THE 2,2'-BIPYRIDINE COMPLEXES OF IRON(III) AND IRON(II); ELECTROCHEMICAL KINETIC PARAMETERS FOR SEVERAL IRON COMPLEXES. III. PROTON NUCLEAR MAGNETIC RESONANCE STUDIES OF URANIUM(IV)-ETHYLENE DIAMINETETRAACETIC ACID COMPLEXES IN AQUEOUS (DEUTERIUM-OXIDE) SOLUTIONS. [D] . EHMAN, DEWAYNE LEE. 1969

机译：I.水溶液中汞电极上一氧化二氮和亚硝酸的电化学二。铁（III）和铁（II）的2,2'-联吡啶络合物的电化学和水解动力学；多种铁络合物的电化学动力学参数。三，铀（IV）-水溶液（氧化氘）中铀（IV）-乙撑双氨基乙酸复合物的质子核磁共振研究
6. Chain Entanglement of 2-Ethylhexyl Hydrogen-2-Ethylhexylphosphonate into Methacrylate-Grafted Nonwoven Fabrics for Applications in Separation and Recovery of Dy (III) and Nd (III) from Aqueous Solution [O] . Hiroyuki Hoshina, Jinhua Chen, Haruyo Amada, 2020

机译：将2-乙基己基氢-2-乙基己基膦酸盐的链缠绕成甲基丙烯酸酯 - 接枝非织造织物用于从水溶液中分离和回收DY（III）和Nd（III）的应用
7. III. The measurement of Ionic velocities in aqueous solution, and the existence of complex ions [O] . 1902

机译：III。水溶液中离子速度的测量，以及复合离子的存在

About the existence of Th(III) in aqueous solution

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