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首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Reaction of 2-(diphenylphosphino)-pyridine and -thiazole organoiron(0) polydentate ligands with iron(III) salts X-ray structures of [#eta#~2-Ph_2P(O)py]_2Fe(#mu#-Cl)_2FeCl_2 and Fe(NCS)_2[[#eta#~2-Ph_2P(O)taz]_2 (taz = thiazole)
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Reaction of 2-(diphenylphosphino)-pyridine and -thiazole organoiron(0) polydentate ligands with iron(III) salts X-ray structures of [#eta#~2-Ph_2P(O)py]_2Fe(#mu#-Cl)_2FeCl_2 and Fe(NCS)_2[[#eta#~2-Ph_2P(O)taz]_2 (taz = thiazole)

机译:2-(二苯基膦基)-吡啶和-噻唑有机铁(0)多齿配体与[#eta#〜2-Ph_2P(O)py] _2Fe(#mu#-Cl)的铁(III)盐X射线结构的反应_2FeCl_2和Fe(NCS)_2 [[#eta#〜2-Ph_2P(O)taz] _2(taz =噻唑)

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摘要

The reaction of trans-Fe(CO)_2(CS_2)(Ph_2Ppy-P)_2 (Ph_2Ppy = 2-(diphenylphosphino)pyridine) with FeCl_3 resulted in the formation of the binuclear complex [[#eta#~2-Ph_2P(O)py]_2FeCl_2 (1), while the reaction of trans-Fe(CO)_3(Ph_2Ptaz-P)_2 (Ph_2Ptaz = 2-(diphenylphosphino)thiazole) with Fe(NCS)_3 gave Fe(NCS)_2[[#eta#~2-Ph_2P(O)]taz]_2 (2). The crystal structures of (1) and (2) centre dot C_6H_6 have been determined using X-ray crystallography.
机译:反式Fe(CO)_2(CS_2)(Ph_2Ppy-P)_2(Ph_2Ppy = 2-(二苯基膦基)吡啶)与FeCl_3的反应导致双核络合物[[#eta#〜2-Ph_2P(O )py] _2FeCl_2(1),而反式Fe(CO)_3(Ph_2Ptaz-P)_2(Ph_2Ptaz = 2-(二苯基膦基)噻唑)与Fe(NCS)_3的反应生成Fe(NCS)_2 [[# eta#〜2-Ph_2P(O)] taz] _2(2)。 (1)和(2)中心点C_6H_6的晶体结构已经使用X射线晶体学确定。

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