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首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Metal-containing dendritic polymers
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Metal-containing dendritic polymers

机译：含金属的树枝状聚合物

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摘要

Metal-containing dendrimers (metallodendrimers) have attracted a great deal of attention recently and their study is becoming a growing field. Many workers have entered the field and it is rapidly developing. In this review, the preparation, characterisation and applications of metal-containing dendrimers are discussed. The principal methodologies for the preparation of dendrimers are first demonstrated and then the derivatisation of organic dendrimers to form suitable potential ligands is presented. Finally the formation of transition-metal complexes of the dendrimers is discussed. The manuscript is organised such that the metallodendrimers are discussed by donor element in the dendrimer. As one might expect, phoshine and nitrogen-donor complexes have dominated this initial phase of synthesis. However, there are reports of metallodendrimers with a wide variety of donor atoms. In the few years since the first metallodendrimers were prepared, the field has moved rapidly towards potential applications, and this has been noted.
机译：含金属的树枝状大分子（metallodendridrimers）最近引起了极大的关注，并且它们的研究正在成为一个不断发展的领域。许多工人已经进入该领域，并且正在迅速发展。在这篇综述中，讨论了含金属的树枝状大分子的制备，表征和应用。首先说明了制备树枝状聚合物的主要方法，然后介绍了将有机树枝状聚合物衍生以形成合适的潜在配体的方法。最后讨论了树枝状大分子过渡金属配合物的形成。手稿的组织方式使得金属树状大分​​子通过树状大分子中的供体元素进行讨论。正如人们可能期望的那样，膦和氮供体配合物已主导了这一合成的初始阶段。然而，有报道称金属树枝状聚合物具有多种供体原子。自制备第一批金属树枝状大分子以来的几年中，该领域已迅速向潜在的应用领域发展，这一点已得到关注。

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