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首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >The photoelectric conversion and second harmonic generation properties of the transition metal-containing complexes [(CH_3)_2N C_6H_4-CH=CHC_5H_4N-C_(18)H_(37)]_2M(dmit)_2 (M = Cd, Ni)
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The photoelectric conversion and second harmonic generation properties of the transition metal-containing complexes [(CH_3)_2N C_6H_4-CH=CHC_5H_4N-C_(18)H_(37)]_2M(dmit)_2 (M = Cd, Ni)

机译：含过渡金属的配合物[（CH_3）_2N C_6H_4-CH = CHC_5H_4N-C_（18）H_（37）] _ 2M（dmit）_2（M = Cd，Ni）的光电转换和二次谐波生成特性

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摘要

The photoelectric conversion and second harmonic generation properties of the complex bis{N[(E)-N-octadecyl-4-N[2-(4-dimethylaminophenyl)ethenyl] pyridinium}bis(2-thione-1,3-dithiol-4,5-dimercapt)M.N[D_2M(dmit)_2 where M = Cd, Ni] have been investigated. The photoelectric conversion quantum yield of the complex of D_2Cd(dmit)_2 was evaluated to be 1.1% which is five-fold larger than that of bis{N[(E)-N-octadecyl-4-N[2-(4-dimethylaminophenyl)ethenyl] pyridinium} iodide (DI) itself, while the second order nonlinear optical susceptibility x_(zzz)~2 was measured as 149.8 pm V~(-1) which is about the same as DI.
机译：双（2-硫酮-1,3-二硫醇-）双{N [（E）-N-十八烷基-4-N [2-（4-二甲基氨基苯基）乙烯基]吡啶鎓}吡啶鎓的光电转换和二次谐波生成特性已经研究了4，5-二巯基）MN [D_2M（dmit）_2，其中M = Cd，Ni]。 D_2Cd（dmit）_2的配合物的光电转换量子产率为1.1％，是bis {N [（E）-N-十八烷基-4-N [2-（4-二甲基氨基苯基）乙烯基]吡啶鎓碘化物（DI）本身，而二阶非线性光学敏感性x_（zzz）〜2测得为149.8 pm V〜（-1），与DI大致相同。

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