Zn (Ce,Mn)-MOFs with (3,4,5)-connected 3-D topology network and test of photocatalysis on the reduction of Cr6+ by Zn (Ce)-MOFs

Xu Qian-Qian; Fan Hong-Jie; Li Yin-Tao; Christensen Kirsten E.; Ren Tie-zhen

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Zn (Ce,Mn)-MOFs with (3,4,5)-connected 3-D topology network and test of photocatalysis on the reduction of Cr6+ by Zn (Ce)-MOFs

【24h】

Zn (Ce,Mn)-MOFs with (3,4,5)-connected 3-D topology network and test of photocatalysis on the reduction of Cr6+ by Zn (Ce)-MOFs

机译：具有（3,4,5）连接的3-D拓扑网络的Zn（Ce，Mn）-MOFs以及光催化测试Zn（Ce）-MOFs还原Cr6 +的实验

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Three metal-organic frameworks Zn-5(mu-OH)(BTC)(3)(phen)(4)center dot 5H(2)O (HUT-11), Ce-5(mu-OH)(BTC)(3) (Phen)(4) (HUT-091) and Mn-5(mu-OH)(BTC)(3)(phen)(4)center dot 5H(2)O (HUT-101) have been synthesized, based on the ligands of 1,3,5-benzenetricarboxylic acid (H3BTC) and phenanthroline (phen) in the presence of Zn, Ce and Mn metal ions. The flexible ligand of BTC gives the remarkable properties of the microporous coordination polymers, that exhibits infrequent (3,4,5)-connected (4 center dot 6 center dot 8)(2)(4 center dot 8(2))(4(2)center dot 6(2)center dot 8(2))(4(2)center dot 8(2)center dot 10(2))(4 center dot 6(4)center dot 8(5)) topology by using Zn, Ce or Mn metal clusters and H3BTC as nodes. The thermal stability of each compounds relies on the atmosphere and Ce-MOFs stabilize till 600 degrees C in N-2. The photocatalytic properties of Zn-MOFs and Ce-MOFs on reduction of Cr6+ have also been studied and Ce-MOFs are more active and can be recycled at least in three times. (C) 2015 Elsevier Ltd. All rights reserved.

机译：三种金属有机骨架Zn-5（mu-OH）（BTC）（3）（phen）（4）中心点5H（2）O（HUT-11），Ce-5（mu-OH）（BTC）（ 3）已合成（Phen）（4）（HUT-091）和Mn-5（mu-OH）（BTC）（3）（phen）（4）中心点5H（2）O（HUT-101）， Zn，Ce和Mn金属离子存在下，基于1,3,5-苯三甲酸（H3BTC）和菲咯啉（phen）的配体。 BTC的柔性配体赋予了微孔配位聚合物非凡的性能，这种聚合物不频繁（3,4,5）连接（4个中心点6个中心点8）（2）（4个中心点8（2））（4 （2）中心点6（2）中心点8（2））（4（2）中心点8（2）中心点10（2））（4中心点6（4）中心点8（5））拓扑通过使用Zn，Ce或Mn金属簇和H3BTC作为节点。每种化合物的热稳定性取决于大气，并且Ce-MOF在N-2中稳定到600摄氏度。还研究了Zn-MOF和Ce-MOF对Cr6 +还原的光催化性能，并且Ce-MOF更具活性，至少可以循环使用三次。（C）2015 Elsevier Ltd.保留所有权利。

著录项

来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2015年第null期|共8页
作者
Xu Qian-Qian; Fan Hong-Jie; Li Yin-Tao; Christensen Kirsten E.; Ren Tie-zhen;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Coordination polymer; Hydrothermal synthesis; (3; 4; 5)-connected metal organic framework; Topology; Photocatalysis;

机译：配位聚合物;水热合成;（3;4;5）-连接的金属有机骨架;拓扑结构;光催化;

相似文献

外文文献
中文文献
专利

1. Simultaneously Regulating Uniform Zn^(2+) Flux and Electron Conduction by MOF/rGO Interlayers for High‑Performance Zn Anodes [J] . Ziqi Wang, Liubing Dong, Weiyuan Huang, 纳微快报：英文版 . 2021,第005期
2. MOF-Derived ZnS Nanodots/Ti_(3)C_(2)T_(x) MXene Hybrids Boosting Superior Lithium Storage Performance [J] . Bin Cao, Huan Liu, Xin Zhang, 纳微快报：英文版 . 2021,第012期
3. Influence of Additives on the Solvothermal Synthesis in the Formation of Zn-MOF5 [J] . LIN Xiaoying, SU Ting, ZHONG Qinhua, 东华大学学报（英文版） . 2018,第006期
4. Zn (Ce,Mn)-MOFs with (3,4,5)-connected 3-D topology network and test of photocatalysis on the reduction of Cr6+ by Zn (Ce)-MOFs [J] . Xu Qian-Qian, Fan Hong-Jie, Li Yin-Tao, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2015,第Null期

机译：具有（3,4,5）连接的3-D拓扑网络的Zn（Ce，Mn）-MOFs以及光催化测试Zn（Ce）-MOFs还原Cr6 +的实验
5. Advances in transition-metal (Zn, Mn, Cu)-based MOFs and their derivatives for anode of lithium-ion batteries [J] . Li Ting, Bai Yilu, Wang Yong, Coordination chemistry reviews . 2020,第May期

机译：转发 - 金属（Zn，Mn，Cu）的进展 - 基于锂离子电池阳极的MOF和它们的衍生物
6. Structure and photoluminescence tuning features of Mn~(2+)- and Ln~(3+)-activated Zn-based heterometal-organic frameworks (MOFs) with a single 5-methylisophthalic acid ligand [J] . Bo Q.-B., Wang H.-Y., Wang D.-Q., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2011,第20期

机译：具有单个5-甲基间苯二甲酸配体的Mn〜（2+）和Ln〜（3+）活化的Zn基杂金属有机骨架（MOF）的结构和光致发光调谐特性
7. How does the pore morphology influence the adsorption performance of metal-organic frameworks? A molecular simulation study of methane and ethane adsorption in Zn-MOFs [C] . F.E.P.Fernandes, R.Garcia, A.J.V.Pires, 40th Anniversary of International Zeolite Conference;International Zeolite Conference . 2007

机译：孔的形态如何影响金属有机骨架的吸附性能？ Zn-MOFs中甲烷和乙烷吸附的分子模拟研究
8. Physicochemical, Spectroscopic Properties, and Diffusion Mechanisms of Small Hydrocarbon Molecules in MOF-74-Mg/Zn: A Quantum Chemical Investigation [D] . Degaga, Gemechis D. 2018

机译：MOF-74-Mg / Zn中小烃分子的理化性质，光谱性质和扩散机理：量子化学研究
9. Unravelling Why and to What Extent the Topology of Similar Ce‐Based MOFs Conditions their Photodynamic: Relevance to Photocatalysis and Photonics [O] . Elena Caballero‐Mancebo, Boiko Cohen, Simon Smolders, 2019

机译：阐明类似的基于Ce的MOF的拓扑为何以及在多大程度上限制了它们的光动力：与光催化和光子学的相关性
10. Characterization of Zn-containing MOFs by Solid-state 67Zn NMR and Computational Modeling [O] . Sutrisno, Andre, Terskikh, Victor V., Shi, Qi, 2012

机译：固态67Zn NMR和计算模型表征含锌的MOF

Zn (Ce,Mn)-MOFs with (3,4,5)-connected 3-D topology network and test of photocatalysis on the reduction of Cr6+ by Zn (Ce)-MOFs

摘要

著录项

相似文献

相关主题

期刊订阅