CRYSTAL STRUCTURE OF BASE-FREE [MOOI4](-)

Gordon JC.; Poli R.; Fanwick PE.; Mattamana SP.

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CRYSTAL STRUCTURE OF BASE-FREE [MOOI4](-)

机译：无基[MOOI4]（-）的晶体结构

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Air oxidation of [PPh(4)](3)[Mo3I12] produces [PPh(4)][MoOI4], a rare example of an iodide-containing molybdenum(V) complex, whose structure has been determined by X-ray crystallography. This structural determination completes the [MoOX(4)](-) (X = Cl, Pr, I) series. The structural parameters are compared with those of the other halide analogues and with those of crystallographically characterized base adducts, [MoOI4(L)](-) (L = H2O, THF). Also, a comparison between the donor power of O2- vs the pentamethyl-cyclopentadienyl anion for molybdenum(V) is made possible by comparing [MoOI4](-) with the non-existent (eta-C(5)Me(5))MoI4. [References: 19]

机译：空气氧化[PPh（4）]（3）[Mo3I12]会产生[PPh（4）] [MoOI4]，这是一种含碘化物的钼（V）配合物的稀有例子，其结构已通过X射线晶体学确定。此结构确定完成[MoOX（4）]（-）（X = Cl，Pr，I）系列。将结构参数与其他卤化物类似物的参数以及晶体学表征的碱加合物[MoOI4（L）]（-）（L = H2O，THF）进行比较。此外，通过比较[MoOI4]（-）与不存在的（eta-C（5）Me（5）），可以比较O2-与五甲基-环戊二烯基阴离子对Mo（V）的供体功率MoI4。 [参考：19]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1995年第10期|共4页
作者
Gordon JC.; Poli R.; Fanwick PE.; Mattamana SP.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Dimolybdenum tetraacetate; = tetrahydrofuran; Iodide complexes; Molybdenum; Tungsten;

机译：四乙酸二钼;=四氢呋喃;碘化物络合物;钼;钨;

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1. CRYSTAL STRUCTURE OF BASE-FREE [MOOI4](-) [J] . Gordon JC., Poli R., Fanwick PE., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1995,第10期

机译：无基[MOOI4]（-）的晶体结构
2. Solvent-resistant structures of base-free lithium and potassium allylcomplexes, MI(SiMe_3)_nC_3H_(5-n)(M = Li,n=3; M = K,n =2) [J] . Cameron K. Gren, Timothy P. Hanusa, Arnold L. Rheingold Main group chemistry . 2009,第4期

机译：无碱锂和钾烯丙基复合物的耐溶剂结构MI（SiMe_3）_nC_3H_（5-n）（M = Li，n = 3; M = K，n = 2）
3. Solid-State Structures of Base-Free Rubidium and Cesium Pentamethylcyclopentadienides. Determination by High-Resolution Powder Diffraction [J] . Behrens U, Dinnebier RE, Neander S, Organometallics . 2008,第20期

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4. Crystal Structure, Phase Stability and Plastic Deformation Behavior of Ti-rich Ni_3(Ti,Nb) Single Crystals with Various Long-Period Ordered Structures [C] . Koji Hagihara, Tetsunori Tanaka, Takayoshi Nakano, Symposium on Integrative and Interdisciplinary Aspects of Intermetallics . 2005

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5. I. CRYSTAL AND MOLECULAR STRUCTURE OF ANTITUMOR AGENT JATROPHATRIONE; II. CRYSTAL AND MOLECULAR STRUCTURES OF TWO PYRIMIDONE DIMERS; III. CRYSTAL AND MOLECULAR STRUCTURE OF PHTHALIC ANHYDRIDE; IV. SYNTHETIC STUDIES ON THE SIDE CHAINS OF CEPHALOTAXINE ESTERS, POTENT ANTICANCER AGENTS. [D] . CUTLER, ROBERT STEVEN -1

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6. Crystal structures of hydrogen-bonded co-crystals as liquid crystal precursors: 4-(n-pentyloxy)benzoic acid–(E)-12-bis(pyridin-4-yl)ethene (2/1) and 4-(n-hexyloxy)benzoic acid–(E)-12-bis(pyridin-4-yl)ethene (2/1) [O] . Yohei Tabuchi, Kazuma Gotoh, Hiroyuki Ishida 2016

机译：作为液晶前体的氢键合共晶体的晶体结构：4-（正戊氧基）苯甲酸-（E）-12-双（吡啶-4-基）乙烯（2/1）和4-（正己氧基）苯甲酸-（E）-12-双（吡啶-4-基）乙烯（2/1）
7. Frontiers in Crystal Chemistry: Prediction of Structures and Properties. Part 2. Solid-State Properties and Reactions Predicted from Crystal Structures. Observation of Crystalline-State Reaction and Structure of Unstable Reaction-Intermediate in Crystals. [O] . Hidehiro UEKUSA 2002

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8. Synthesis and Structure of the First Base-Free Diphosphadigalletane [R] . Atwood, D. A., Cowley, A. H., Jones, R. A., 1991

机译：第一种无碱二磷杂环戊烷的合成和结构

CRYSTAL STRUCTURE OF BASE-FREE [MOOI4](-)

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