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首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Structure of Fe3O complexes with long alkyl chain fatty acid, [Fe3O(O2CCnH2n+1)(6)L-3]NO3 (L = H2O, n = 11, 13, 15, 17; L = py, n = 13, 15, 17); crystal structure of [Fe3O(O2CC13H27)(6)(py)(3)]NO3
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Structure of Fe3O complexes with long alkyl chain fatty acid, [Fe3O(O2CCnH2n+1)(6)L-3]NO3 (L = H2O, n = 11, 13, 15, 17; L = py, n = 13, 15, 17); crystal structure of [Fe3O(O2CC13H27)(6)(py)(3)]NO3

机译:具有长烷基链脂肪酸[[Fe3O(O2CCnH2n + 1)(6)L-3] NO3的Fe3O络合物的结构(L = H2O,n = 11,13,15,17; L = py,n = 13,15 ,17); [Fe3O(O2CC13H27)(6)(py)(3)] NO3的晶体结构

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摘要

Two series of trinuclear iron(III) carboxylate complexes with long alkyl chains, [Fe3O(O2CR)(6)L-3]NO3 where L=H2O or py (pyridine), were prepared. Powder X-ray diffraction patterns of each series suggested that the aqua series has a double-layer structure and the pyridine series has a single-layer structure. The single crystal X-ray structure determination of [Fe3O(O2CC13H27)(6)(py)(3)]NO3 revealed that the compound forms a single-layer structure with the interlamellar orientation of alkyl chains being arranged alternately to those of adjacent layers. (C) 1998 Elsevier Science Ltd. All rights reserved. [References: 15]
机译:制备了两个具有长烷基链的三核三羧酸铁(III)配合物,[L3O(O2CR)(6)L-3] NO3,其中L = H2O或py(吡啶)。每个系列的粉末X射线衍射图表明,aqua系列具有双层结构,而吡啶系列具有单层结构。 [Fe3O(O2CC13H27)(6)(py)(3)] NO3的单晶X射线结构测定表明,该化合物形成单层结构,烷基链的层间取向与相邻层的交替排列。 (C)1998 Elsevier ScienceLtd。保留所有权利。 [参考:15]

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