One-dimensional co-ordination polymers formed by crown ether metal cation bridges: synthesis and crystal structure of nickel(II) dithiolene complexes [{Na(benzo-15-crown-5)}(2) Ni(i-mnt)(2)](n)center dot nCH(2)Cl(2) and [{Na(benzo-15-crown-5)}(2)Ni(m

Long DL.; Chen JT.; Cheng WD.; Huang JS.; Cui Y.

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One-dimensional co-ordination polymers formed by crown ether metal cation bridges: synthesis and crystal structure of nickel(II) dithiolene complexes [{Na(benzo-15-crown-5)}(2) Ni(i-mnt)(2)](n)center dot nCH(2)Cl(2) and [{Na(benzo-15-crown-5)}(2)Ni(m

机译：由冠醚金属阳离子桥形成的一维配位聚合物：二硫代镍镍（II）配合物[{Na（benzo-15-crown-5）}（2）Ni（i-mnt）（2）的合成和晶体结构）]（n）中心点nCH（2）Cl（2）和[{Na（benzo-15-crown-5）}（2）Ni（m

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Reaction of NiCl2. 6H(2)O, Na-2[i-mnt] and benzo-15-crown-5 in CH3OH/CH2Cl2 at room temperature leads to [{Na(benzo-15-crown-5)}(2)Ni(mnt)(2)](n) . nCH(2)Cl(2) (1). The same reaction with Na-2[mnt] instead of Na-2[i-mnt] affords [{Na(benzo-15-crown-5)}(2)Ni(mnt)(2)](n) (2). Both complexes were isolated as crystalline products. X-ray diffraction analyses reveal that the main segments of 1 and 2 are infinite "train" structures, in which the building blocks Ni(i-mnt), or Ni(mnt), in end-to-end arrangements act as "body frames" and crown cycles standing by the body frames play the role of "cartwheel". They are joined with each other through sodium ions. (C) 1998 Elsevier Science Ltd. All rights reserved. [References: 36]

机译：NiCl2的反应。室温下在CH3OH / CH2Cl2中的6H（2）O，Na-2 [i-mnt]和苯并15-冠5生成[{Na（苯并15-冠-5）}（2）Ni（mnt ）（2）]（n）。 nCH（2）Cl（2）（1）。用Na-2 [mnt]代替Na-2 [i-mnt]进行相同的反应可得到[{Na（苯并15-冠-5）}（2）Ni（mnt）（2）]（n）（2 ）。两种配合物均被分离为结晶产物。 X射线衍射分析显示1和2的主要部分是无限的“火车”结构，其中Ni（i-mnt）或Ni（mnt）的结构单元以端到端的方式充当“物体”车架”和站立在车架上的冠轮起“车轮”的作用。它们通过钠离子彼此结合。（C）1998 Elsevier ScienceLtd。保留所有权利。 [参考：36]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1998年第22期|共7页
作者
Long DL.; Chen JT.; Cheng WD.; Huang JS.; Cui Y.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Crown ether; Nickel(ii) dithiolate; Crystal structure; Co-ordination polymer; Sodium; Benzo-15-crown-5; Chemistry; Palladium; Ligands; Alkali; Bases;

机译：冠醚;二硫代镍（Ni）;晶体结构;配位聚合物;钠;Benzo-15-crown-5;化学;钯;配体;碱;碱;

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1. One-dimensional co-ordination polymers formed by crown ether metal cation bridges: synthesis and crystal structure of nickel(II) dithiolene complexes [{Na(benzo-15-crown-5)}(2) Ni(i-mnt)(2)](n)center dot nCH(2)Cl(2) and [{Na(benzo-15-crown-5)}(2)Ni(m [J] . Long DL., Chen JT., Cheng WD., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第22期

机译：由冠醚金属阳离子桥形成的一维配位聚合物：二硫代镍镍（II）配合物[{Na（benzo-15-crown-5）}（2）Ni（i-mnt）（2）的合成和晶体结构）]（n）中心点nCH（2）Cl（2）和[{Na（benzo-15-crown-5）}（2）Ni（m
2. Nickel(II)center dot center dot center dot pi interaction in [M(ampy)(2)Ni(mu-CN)(2)(CN)(2)](n) (M = Zn(II) and Cd(II), ampy=2-aminomethylpyridine): Syntheses, vibrational spectroscopy, thermal analyses and crystal structures of cyano-bridged heteronuclear polymeric complexes [J] . Kuerkcueoglu Guenes Sueheyla, Yesilel Okan Zafer, Kavlak Ilkan, Journal of Molecular Structure . 2009,第1a3期

机译：[M（ampy）（2）Ni（mu-CN）（2）（CN）（2）]（n）中的镍（II）中心点中心点中心点pi相互作用（M = Zn（II）和Cd（ II），ampy = 2-氨基甲基吡啶）：氰基桥杂核聚合物配合物的合成，振动光谱，热分析和晶体结构
3. Synthesis and spectroscopic characterisation of new nickel(II) complexes with 5-methyl-3-formylpyrazole-3-piperidinylthiosemicarbazone (HMP(z)3Pi): X-ray structures of HMP(z)3Pi and [Ni(HMP(z)3Pi)(2)]Cl-2 center dot 2H(2)O with indication for unusual [J] . Saha NC, Butcher RJ, Chaudhuri S, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2005,第9期

机译：新型镍（II）与5-甲基-3-甲酰基吡唑-3-哌啶基硫代半碳酮（HMP（z）3Pi）的合成和光谱表征：HMP（z）3Pi和[Ni（HMP（z）3Pi）的X射线结构）（2）] Cl-2中心点2H（2）O，表示异常
4. Ni-S(uper)O(xide)D(ismutase) Inspired Ni(II)-Amino Acid Complexes Covalently Grafted onto Merrifield's Resin - Synthesis, Structure and Catalytic Activity [C] . Z. Csendes, B. Kutus, P. Sipos, Encontro da Sociedade Portuguesa de Materials SPM . 2013

机译：Ni-s（Uper）O（XIESE）D（Ismutase）的灵感Ni（II） - 氨基酸配合物共价接枝到Merrifield的树脂合成，结构和催化活性上
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机译：镍二膦醚配合物和金属大环作为配体中碳氧键活化的基础研究：铁和钴的铝桥联双乙氧肟酸酯配合物的合成和表征。
6. Syntheses and crystal structures of the one-dimensional coordination polymers formed by Ni(cyclam)2+ cations and 13-bis(3-carboxypropyl)tetramethyldisiloxane anions in different degrees of deprotonation [O] . Sergey P. Gavrish, Sergiu Shova, Maria Cazacu, 2020

机译：Ni（cyclam） 2+阳离子与13-双（3-carboxyoxypropyl）四甲基二硅氧烷阴离子形成的一维配位聚合物在不同质子化程度下的合成和晶体结构
7. Correction to “Synthesis of Mono- and Diiron Dithiolene Complexes as Hydrogenase Models by Dithiolene Transfer Reactions, Including the Crystal Structure of {Ni(S2C2Ph2)}6” [O] . Harry Adams, Michael J. Morris, Craig C. Robertson, 2019

机译：通过二苯二烯转移反应将“单 - 和二硫硅基络合物的合成作为氢化酶模型的校正，包括{ni（s2c2ph2）} 6的晶体结构”
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机译：通过d8-Closo-Bis（三芳基膦）Nickelacarboranes的热重排将Ni-pR3和B-H同时转化为Ni-H和B-pR3键。（Closo-3-mu-CO-8-pph3-3,1,2-NiC2B9H10）2的晶体和分子结构;含有金属 - 金属键的二聚体Nickelacarborane复合物。

One-dimensional co-ordination polymers formed by crown ether metal cation bridges: synthesis and crystal structure of nickel(II) dithiolene complexes [{Na(benzo-15-crown-5)}(2) Ni(i-mnt)(2)](n)center dot nCH(2)Cl(2) and [{Na(benzo-15-crown-5)}(2)Ni(m

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