Synthesis, binding properties and electrochemistry of nickel(II) macrocyclic complexes containing crown ethers

Chee-Hun Kwak; Hyejin Nam; Jeong-Mi Moon; Il Cheol Jeon; Yong Kook Choi

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Synthesis, binding properties and electrochemistry of nickel(II) macrocyclic complexes containing crown ethers

机译：含冠醚的镍（II）大环配合物的合成，结合性能和电化学

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Macrotetracyclic complexes of nickel(II) containing crown ethers as pendant arms. [Ni(B)](ClO_4)_2, were prepared and characterized. The binding constants of the complexes toward alkali metal ions are relatively small compared with those of free 15-crown-5 or 18-crown-6 and the reduction potentials of the [Ni(B)](ClO_4)_2 in the presence of alkali metal ions shift to the positive direction in the order Li~+> Na~+>K~+>Na~+>Li~+, respectively.

机译：含冠醚作为侧链的镍（II）的大四环配合物。制备并表征了[Ni（B）]（ClO_4）_2。与游离的15冠5或18冠6相比，络合物对碱金属离子的结合常数较小，并且在碱存在下[Ni（B）]（ClO_4）_2的还原电位金属离子分别以Li〜+> Na〜+> K〜+> Na〜+> Li〜+的顺序向正方向移动。

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1999年第20期|共7页
作者
Chee-Hun Kwak; Hyejin Nam; Jeong-Mi Moon; Il Cheol Jeon; Yong Kook Choi;
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正文语种 eng
中图分类化学;无机化学;
关键词
macrotetracyclic complexes of nickel(II); crown ether; pendant arm; binding properties; electrochemical behavior;

机译：镍（II）的大四环配合物;冠醚;悬臂;结合性能;电化学行为;

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1. Synthesis, binding properties and electrochemistry of nickel(II) macrocyclic complexes containing crown ethers [J] . Chee-Hun Kwak, Hyejin Nam, Jeong-Mi Moon, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1999,第20期

机译：含冠醚的镍（II）大环配合物的合成，结合性能和电化学
2. Binding property and redox behaviour of nickel(II)macrocyclic complex containing crown ether toward alkaline earth metal ions [J] . Joo-Eun Jee, Man Chai Chang, Chee-Hun kwak Inorganic Chemistry Communications . 2004,第5期

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3. Binding property and redox behaviour of nickel(II)macrocyclic complex containing crown ether toward alkaline earth metal ions [J] . Joo-Eun Jee, Man Chai Chang, Chee-Hun kwak Inorganic Chemistry Communications . 2004,第5期

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Synthesis, binding properties and electrochemistry of nickel(II) macrocyclic complexes containing crown ethers

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