Sol-gel entrapped heteronuclear transition metal catalysts

Blum J.; Abu-Reziq R.; Miloslavski I.; Schumann H.; Avnir D.; Gelman F.

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Sol-gel entrapped heteronuclear transition metal catalysts

机译：溶胶凝胶包裹的异核过渡金属催化剂

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The heteronuclear complexes [(CO)(4)Fe(mu-PPh2)Pd(mu-Cl)(2)](2), [Et4N] [FeCo3(CO)(12)] and Rh2Co2(CO)(12) were physically entrapped in SiO2-sol-gel matrices. The doped materials, so formed, were utilized as recyclable catalysts for(a) selective isomerization of 1-octene, (b) selective dimerization of norbornadiene to 'binor-S', and (c) hydrogenation and hydrogenolysis of styrene, nitrobenzene and 1-chloronaphthalene, respectively. During the hydrogenation of the nitrobenzene and of chloronaphthalene, the dodecacarbonylbis(cobalt) dirhodium was converted into sol-gel entrapped carbonyl-free nanoparticles that efficiently catalyze the reduction of the aromatic C-C bonds. (C) 2000 Elsevier Science Ltd All rights reserved. [References: 14]

机译：杂核络合物[（CO）（4）Fe（mu-PPh2）Pd（mu-Cl）（2）]（2），[Et4N] [FeCo3（CO）（12）]和Rh2Co2（CO）（12）被物理包裹在SiO2-溶胶-凝胶基质中。如此形成的掺杂材料可用作（a）1-辛烯的选择性异构化，（b）降冰片二烯选择性二聚为'binor-S'以及（c）苯乙烯，硝基苯和1的加氢和氢解的可循环使用的催化剂。 -氯萘。在硝基苯和氯萘的氢化过程中，十二羰基双（钴）dirhodium被转化为溶胶-凝胶包裹的无羰基纳米颗粒，可有效催化芳族C-C键的还原。（C）2000 Elsevier Science Ltd保留所有权利。 [参考：14]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2000年第5期|共4页
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Blum J.; Abu-Reziq R.; Miloslavski I.; Schumann H.; Avnir D.; Gelman F.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Heteronuclear catalysts; Immobilization; Nanoparticles; Sol-gel matrices;

机译：异核催化剂;固定化;纳米颗粒;溶胶凝胶基质;

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1. Sol-gel entrapped heteronuclear transition metal catalysts [J] . Blum J., Abu-Reziq R., Miloslavski I., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2000,第5期

机译：溶胶凝胶包裹的异核过渡金属催化剂
2. Polyoxometalates entrapped in sol-gel matrices as electron exchange columns and catalysts for the reductive de-halogenation of halo-organic acids in water [J] . Neelam, Meyerstein Dan, Burg Ariela, Journal of Coordination Chemistry . 2018,第19a20期

机译：以溶胶 - 凝胶基质捕获的多血清液作为电子交换柱和催化剂，用于水中卤素 - 有机酸的还原脱卤
3. Sol-gel synthesis and characterization of transition metal based mixed oxides and their application as catalysts in selective oxidation of propane [J] . Carlo Lucarelli, Pietro Moggi, Fabrizio Cavani Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2007,第2期

机译：过渡金属基混合氧化物的溶胶-凝胶合成，表征及其在丙烷选择性氧化中的催化剂应用
4. HMS Catalysts Containing Transition Metals or Transition Metal Complexes [C] . Zaihui Fu, Dulin Yin, Wei Zhao, 13th International Zeolite Conference, 13th, Jul 8-13, 2001, Montpellier, France . 2001

机译：含过渡金属或过渡金属配合物的HMS催化剂
5. Hydroboration studies on transition metal carbonyl anions and chemical vapor deposition of metallic thin films using homonuclear and heteronuclear metal carbonyls [D] . Boyd, Edwin Pressley 1995

机译：使用同核和异核金属羰基化合物对过渡金属羰基阴离子进行硼氢化研究和金属薄膜的化学气相沉积
6. Traditional Sol-Gel Chemistry as a Powerful Tool for the Preparation of Supported Metal and Metal Oxide Catalysts [O] . Serena Esposito 2019

机译：传统溶胶-凝胶化学是制备负载型金属和金属氧化物催化剂的有力工具
7. Role of Heteronuclear Interactions in Selective H2 Formation from HCOOH Decomposition on Bimetallic Pd/M (M = Late Transition FCC Metal) Catalysts [O] . -1

机译：异核相互作用在双金属Pd / m（m =晚期过渡FCC金属）催化剂上的HCOOH分解中的选择性H2中的作用

Sol-gel entrapped heteronuclear transition metal catalysts

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