Synthesis and structure of a complex with the coordinated triaminoguanidinium(2+) ion, [Cu(TAGH(2))Cl-3]Cl center dot H2O

Saveleva ZA.; Sheludyakova LA.; Larionov SV.; Romanenko GV.

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Synthesis and structure of a complex with the coordinated triaminoguanidinium(2+) ion, [Cu(TAGH(2))Cl-3]Cl center dot H2O

机译：具有配位的三氨基胍（2+）离子，[Cu（TAGH（2））Cl-3] Cl中心点H2O的配合物的合成和结构

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The title compound has been isolated upon the reaction of copper(II) chloride and triaminoguanidine hydrochloride in concentrated HCl. An X-ray study has shown that the crystal structure of this complex is composed of [Cu(TAGH(2))Cl-3](+) cations, Cl- anions and water molecules. The complex cation involved the coordinated triaminoguanidinium(2+) cation bonded to the Cu(II) ion via N atoms of the amino group and the C=N moiety as a chelate bidentate ligand. The square-planar environment of the Cu atom is formed by two Cl atoms (2.2769(9) and 2.3002(9) Angstrom) and two N atoms (Cu-N 1.987(2) and 2.033(2) Angstrom). The long Cu-Cl bonds (2.728(1) and 2.941(1) Angstrom) which complement the environment to a distorted square bipyramid allow us to separate the staggered cation chains. mu(ef) values are 1.83 and 1.86 mu B at 78 and 300 K, respectively. (C) 2000 Elsevier Science Ltd. All rights reserved. [References: 15]

机译：在氯化铜（II）和三氨基胍盐酸盐在浓HCl中反应后，分离出标题化合物。 X射线研究表明，该络合物的晶体结构由[Cu（TAGH（2））Cl-3]（+）阳离子，Cl-阴离子和水分子组成。复杂阳离子涉及通过氨基的N个原子和C = N部分作为螯合双齿配体与Cu（II）离子键合的配位三氨基胍（2+）阳离子。 Cu原子的方形平面环境由两个Cl原子（2.2769（9）和2.3002（9）埃）和两个N原子（Cu-N 1.987（2）和2.033（2）埃）形成。较长的Cu-Cl键（2.728（1）和2.941（1）埃）为环境提供了变形的方形双锥体，使我们能够分离交错的阳离子链。在78 K和300 K时，mu（ef）值分别为1.83和1.86 muB。（C）2000 Elsevier ScienceLtd。保留所有权利。 [参考：15]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2000年第14期|共4页
作者
Saveleva ZA.; Sheludyakova LA.; Larionov SV.; Romanenko GV.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Cu(ii) complex; Structure; Triaminoguanidinium(2+) ion;

机译：铜（ii）配合物;结构;三氨基胍（2+）离子;

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1. Synthesis and structure of a complex with the coordinated triaminoguanidinium(2+) ion, [Cu(TAGH(2))Cl-3]Cl center dot H2O [J] . Saveleva ZA., Sheludyakova LA., Larionov SV., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2000,第14期

机译：具有配位的三氨基胍（2+）离子，[Cu（TAGH（2））Cl-3] Cl中心点H2O的配合物的合成和结构
2. Synthesis and characterization of some four- and five-coordinate copper(II) complexes of 6-methyl-2-formylpyridinethiosemicarbazone (HNNS) and the X-ray crystal structures of the [Cn(NNS)(CH3COO)(H2O)] and [Cu(HNNS)(H2O)(SO4)]center dot H2O complexes [J] . Ali MA., Butcher RJ., Jasinski JP., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第11a12期

机译：六甲基-2-甲酰基吡啶硫代半碳酮（HNNS）的四配位和五配位铜（II）配合物以及[Cn（NNS）（CH3COO）（H2O）]和[的X射线晶体结构的合成和表征Cu（HNNS）（H2O）（SO4）]中心点H2O络合物
3. [Cu(phdpa)Cl](+) (phdpa = bis(2-pyridylmethyl)aniline): a moiety of unusual stability in some 1 : 1 Cu(II) complexes of phdpa. Synthesis and X-ray crystal structures of [Cu(phdpa)Cl-2] and [Cu-2(phdpa)(2)Cl-3]PF6 center dot 0.5MeOH [J] . Ugozzoli F., Massera C., Lanfredi AMM., Inorganica Chimica Acta . 2002,第0期

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4. Syntheses and Crystal Structure of Nine-Coordinate Mononuclear Na EuⅢ (edta)(H2O)3 · 4H2O and Binuclear Na4Eu2Ⅲ(Httha)2·10H2O Complexes [C] . International Conference on Rare Earth Research and Application; 2004; . 2004

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5. Synthesis, structural and photophysical characterization of phosphorescent three-coordinate Cu(i)-N-heterocyclic carbene complexes [D] . Krylova, Valentina 2013

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6. Synthesis of Two Mononuclear SchiffBase Metal (M = Fe Cu) Complexes: MOF Structure Dye DegradationH2O2 Sensing and DNA Binding Property [O] . Mithun Kumar Ghosh, Sayantan Pathak, Tanmay Kumar Ghorai, 2019

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机译：铁（2+）和钌（2+）二亚氨基，二氨基和二氨基-二膦配合物的合成与表征X-射线反式RuCl2（P2N2C2H4）中心点CHCl3的晶体结构

Synthesis and structure of a complex with the coordinated triaminoguanidinium(2+) ion, [Cu(TAGH(2))Cl-3]Cl center dot H2O

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