X-ray structural determination of a bulky phosphine complex: chloro{tris(2,4,6-trimethoxyphenyl)phosphine}gold(I), {AuCl[P(C_9H_11O_3)_3]}

Elmer C.Alyea; George Ferguson; Shanmugaperumal Kannan

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X-ray structural determination of a bulky phosphine complex: chloro{tris(2,4,6-trimethoxyphenyl)phosphine}gold(I), {AuCl[P(C_9H_11O_3)_3]}

机译：庞大的膦配合物的X射线结构测定：氯{tris（2,4,6-三甲氧基苯基）膦}金（I），{AuCl [P（C_9H_11O_3）_3]}

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The title comp.ound, {AuCI[P(C9H11OJ)3]}' has three fold symmetry in the solid state. The Au-.CI and Au-F bond lengths are !.294 and 2.255 A, respectively, and the Au atom has nearly linear coordination geometry, with P-Au~CI 176.03(9)0. The extreme ,ulkiness of the phosphine ligand is shown by the mean cone angle of 188° (based on O atoms defining the cone), though the cone Ingle is considerably smaller than 214° for trimesitylphosphine in the known analogous complex. The shorter Au-F bond distance ban for Ag-F (2.379(1) A) in the corresponding known silver chlorideconclusion that gold is smaller than silver.

机译：标题化合物{AuCI [P（C9H11OJ）3]}'在固态时具有三重对称性。 Au-.CI和Au-F键长分别为！.294和2.255 A，Au原子具有近乎线性的配位几何，P-Au〜CI 176.03（9）0。膦配体的极高烷基度由188°的平均锥角显示（基于定义锥的O原子），尽管在已知的类似化合物中，三苯甲基膦的锥Ingle显着小于214°。在相应的已知氯化银结论（金小于银）中，Ag-F的较短Au-F键距被禁止（2.379（1）A）。

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来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2000年第21期|共3页
作者
Elmer C.Alyea; George Ferguson; Shanmugaperumal Kannan;
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正文语种 eng
中图分类化学;无机化学;
关键词
bulky phosphine; X-ray structure; cone angle; two-coordinate gold complex;

机译：大块膦;X射线结构;锥角;二配位金络合物;

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1. X-ray structural determination of a bulky phosphine complex: chloro{tris(2,4,6-trimethoxyphenyl)phosphine}gold(I), {AuCl[P(C_9H_11O_3)_3]} [J] . Elmer C.Alyea, George Ferguson, Shanmugaperumal Kannan Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2000,第20a21期

机译：庞大的膦配合物的X射线结构测定：氯{tris（2,4,6-三甲氧基苯基）膦}金（I），{AuCl [P（C_9H_11O_3）_3]}
2. Synthesis and chemistry of tris(2-pyridyl)phosphine and bis(2-pyridyl)phenylphosphine complexes of mercury(II) X (X=Br, Cl) and X-ray crystal structural determination of [HgBr_2(PPh(2-py)_2)_2] [J] . ALI NEMATI KHARAT, BAHAREH TAMADDONI JAHROMI, ABOLGHASEM BAKHODA, Journal of Coordination Chemistry . 2010,第21期

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3. Synthesis and chemistry of tris(2-pyridyl)phosphine and bis(2-pyridyl)phenylphosphine complexes of mercury(II) X (Xâ=âBr, Cl) and X-ray crystal structural determination of [HgBr₂(PPh(2-py)₂)₂] [J] . Ali Nemati Kharat Journal of Coordination Chemistry . 2010,第21期

机译：合成和化学的三（2-吡啶基）膦和双（2-吡啶基）苯基膦配合物的汞（II）X（X = = Br，Cl）和X射线晶体结构测定[HgBr _{2 （PPh（2-py）_{2 ）_{2 ]}}}
4. Synthesis and X-ray Structural Study on the Complexes of Silver(I) Halide with Tricyclohexylephosphine, Diphenyl-(2,4,6-trimethoxy)phenylphosphine, Phenyl-2,4,6-trimethoxyphenyl phosphine, and Tris(2,4,6-trimethoxy)phenylphosphine [C] . Effendya, A. H. White International Conference on Neutron and X-Ray Scattering . 2008

机译：用三环己磷，二苯基 - （2,4,4,4,6-三甲氧基）苯基膦，苯基-2,4,6-三甲氧基苯基膦，以及三（2,4，）银（I）卤化物的合成和X射线结构研究6-三甲氧基）苯基膦
5. THE X-RAY CRYSTAL STRUCTURE DETERMINATION OF TRI-IRON-UNDECACARBONYL - TRIPHENYL PHOSPHINE COMPLEX AND THE DESIGN, INSTALLATION, AND AUTOMATION OF A NEUTRON DIFFRACTION SYSTEM. [D] . DAHM, DONALD JAMES. 1968

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6. Structural Properties Cytotoxicity and Anti-Inflammatory Activity of Silver(I) Complexes with tris(p-tolyl)Phosphine and 5-Chloro-2-Mercaptobenzothiazole [O] . L. Kyros, N. Kourkoumelis, M. Kubicki, 2010

机译：三（对甲苯基）膦和5-氯-2-巯基苯并噻唑的银（I）配合物的结构性质细胞毒性和抗炎活性
7. Structural studies of two-coordinate complexes of tris(2-methoxyphenyl)phosphine and tris(4-methoxyphenyl)phosphine with gold(I) halides [O] . Bott Raymond C., Healy Peter C., Smith Graham 2007

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8. Poly(Tertiary Phosphines and Arsines)- XII. Some Metal Complexes of Methylated DI- and Tri (Tertiary Phosphines). [R] . King, R. B., Zinich, J. A., Cloyd, J. C. 1974

机译：聚（叔膦和胂） - XII。一些甲基化DI-和三（叔膦）金属配合物。

X-ray structural determination of a bulky phosphine complex: chloro{tris(2,4,6-trimethoxyphenyl)phosphine}gold(I), {AuCl[P(C_9H_11O_3)_3]}

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