Bismuth(III) thioether chemistry: synthesis and structure of a coordination polymer derived from BiCl3 and MeSi(CH2SMe)(3)

Yim HW.; Rheingold AL.; Rabinovich D.; Lam KC.

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Bismuth(III) thioether chemistry: synthesis and structure of a coordination polymer derived from BiCl3 and MeSi(CH2SMe)(3)

机译：铋（III）硫醚化学：BiCl3和MeSi（CH2SMe）（3）衍生的配位聚合物的合成与结构

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The bismuth(III) halides BiX3 (X = Cl, Br) react readily with the tridentate thioether MeSi(CH2SMe)(3) to give complexes of composition Bi-2{MeSi( CH2SMe)(3)}(2)X-6, which have been characterized analytically, spectroscopically and, for the chloro derivative. by single-crystal X-ray diffraction. In contrast to the mononuclear derivatives formed in the reactions of BiCl3 with crown thioethers, Bi-2{MeSi(CH2SMe)(3)}(2)Cl-6 exhibits in the solid state an extended chain structure with bridging unidentate/bidentate thioether ligands. (C) 2000 Elsevier Science Ltd All rights reserved. [References: 34]

机译：卤化铋（III）BiX3（X = Cl，Br）与三齿硫醚MeSi（CH2SMe）（3）容易反应，生成成分Bi-2 {MeSi（CH2SMe）（3）}（2）X-6的配合物，已通过分析，分光镜和氯代衍生物表征。通过单晶X射线衍射。与BiCl3与冠状硫醚的反应中形成的单核衍生物相反，Bi-2 {MeSi（CH2SMe）（3）}（2）Cl-6在固态下表现出延伸的链结构，带有桥接的相同/不对称的硫醚配体。（C）2000 Elsevier Science Ltd保留所有权利。 [参考：34]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2000年第7期|共5页
作者
Yim HW.; Rheingold AL.; Rabinovich D.; Lam KC.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Bismuth; Thioether; Coordination polymers; Crystal structures; Electrospray; Crystal-structures; Complexes;

机译：铋;硫醚;配位聚合物;晶体结构;电喷涂;晶体结构;络合物;

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1. Bismuth(III) thioether chemistry: synthesis and structure of a coordination polymer derived from BiCl3 and MeSi(CH2SMe)(3) [J] . Yim HW., Rheingold AL., Rabinovich D., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2000,第7期

机译：铋（III）硫醚化学：BiCl3和MeSi（CH2SMe）（3）衍生的配位聚合物的合成与结构
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Bismuth(III) thioether chemistry: synthesis and structure of a coordination polymer derived from BiCl3 and MeSi(CH2SMe)(3)

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