TRIAZENIDO-BRIDGED BINUCLEAR PALLADIUM(II) AND PLATINUM(II) COMPLEXES

Singhal A.; Jain VK.

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TRIAZENIDO-BRIDGED BINUCLEAR PALLADIUM(II) AND PLATINUM(II) COMPLEXES

机译：三氮烯桥双核钯和铂络合物

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Triazenido-bridged binuclear palladium(II) and platinum(II) complexes of the type [M(2)X(2)(mu-ArNNNAr)(2)(PR(3))(2)] (where M = Pd or Pt; X = Cl, Me, p-tol; Ar = Ph, p-tol or p-C6H4F; PR(3) = PEt(3), PBu(3), PMe(2)Ph or PMePh(2)) have been prepared by the reaction of [M(2)X(2)(mu-Cl)(2)(PR(3))(2)] with free triazene in the presence of NaOH. These complexes were characterised by elemental analyses, IR and NMR (H-1, P-31, Pt-195) spectrpscopy. Variable temperature NMR data reveal that the eight-membered metallocyclic ring has a rigid conformation. Pt-195 NMR data showed the existence of significant metal-metal interaction. A few reactions of these complexes have also been investigated by NMR spectroscopy. [References: 39]

机译：类型为[M（2）X（2）（mu-ArNNNAr）（2）（PR（3））（2）]的Triazenido桥联双核钯（II）和铂（II）络合物（其中M = Pd或Pt; X = Cl，Me，对甲苯; Ar = Ph，对甲苯或p-C6H4F; PR（3）= PEt（3），PBu（3），PMe（2）Ph或PMePh（2））通过[M（2）X（2）（mu-Cl）（2）（PR（3））（2）]与游离三氮烯在NaOH存在下的反应制备。通过元素分析，IR和NMR（H-1，P-31，Pt-195）光谱对这些复合物进行表征。可变温度NMR数据显示八元金属环具有刚性构象。 Pt-195 NMR数据表明存在明显的金属-金属相互作用。这些配合物的一些反应也已经通过NMR光谱研究。 [参考：39]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1995年第2期|共7页
作者
Singhal A.; Jain VK.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Ray crystal-structure; Mercapto group; Dinuclear; Ligands; Chloro; Carbonylation; Derivatives; Dimer;

机译：射线晶体结构;巯基;双核;配体;氯;羰基化;衍生物;二聚体;

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1. TRIAZENIDO-BRIDGED BINUCLEAR PALLADIUM(II) AND PLATINUM(II) COMPLEXES [J] . Singhal A., Jain VK. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1995,第2期

机译：三氮烯桥双核钯和铂络合物
2. Palladium(II), platinum(II), and platinum(IV) complexes containing trans-1,2-bis( diphenylphosphino) ethene or cis,trans,cis-1,2,3,4-tetrakis( diphenylphosphino) cyclobutane: complete X-ray structural characterization of binuclear compounds [J] . Oberhauser W., Bachmann C., Haid R., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2000,第8期

机译：含有反式1,2-双（二苯基膦基）乙烯或顺式，反式，顺式，1,2,3,4-四（二苯基膦基）环丁烷的钯（II），铂（II）和铂（IV）配合物：完全双核化合物的X射线结构表征
3. BINUCLEAR PALLADIUM(II), PLATINUM(II) AND PLATINUM(IV) COMPLEXES CONTAINING 1,2-BIS(DIPBENYLPHOSPHINO)ACETYLENE - DIFFERENT ORIENTATIONS OF THE DIPHOSPHINE-BRIDGES DUE TO METAL-PHOSPHORUS D-PI-D-PI BACK BONDING [J] . Oberhauser W., Stampfl T., Bruggeller P., Inorganica Chimica Acta . 1997,第2期

机译：含1,2-双（二苯膦基）乙炔的双核钯（II），铂（II）和铂（IV）络合物-由于金属磷D-PI-D-PI的键合，二膦膦桥的取向不同
4. Heterometallic Aggregations in Ultrasound-Induced Gelation with Mixed System of Binuclear Palladium and Platinum Complexes [C] . Yuuki Kuwaiima, Takako Muraoka, Masayuki Iida Symposium on Organometallic Chemistry . 2008

机译：超声诱导凝胶化与二核钯和铂复合物混合系统的杂动机聚集
5. iClick Reactions as a Modular Access to Palladium(II) and Platinum(II) Triazolato Complexes: Trends in Kinetics and Biological Activity =iClick-Reaktionen als modularer Zugang zu Palladium (II)- und Platin (II)-Triazolato-Komplexen: Trends in der Kinetik [D] . Peng, Kun. 2020

机译：Iclick反应作为对钯（II）和铂（II）三唑酸盐复合物的模块化进入：动力学和生物活性的趋势= Iclick反应作为钯（II）和铂（II） - 三唑络合物的模块化进入：动力学趋势
6. Binuclear Palladium(I) and Palladium(II) Complexes of ortho-Functionalized 13-Bis(aryl)triazenido Ligands [O] . Juan José Nuricumbo-Escobar, Carlos Campos-Alvarado, Gustavo Ríos-Moreno, -1

机译：邻官能化的13-双（芳基）三氮杂多配体的双核钯（I）和钯（II）配合物
7. A Transition State Analogue for the Oxidation of Binuclear Palladium(II) to Binuclear Palladium(III) Complexes [O] . Powers, D., Ritter, T. 2013

机译：用于将双核钯（II）氧化成双核钯（III）配合物的过渡态类似物

TRIAZENIDO-BRIDGED BINUCLEAR PALLADIUM(II) AND PLATINUM(II) COMPLEXES

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