SOLID STATE STRUCTURES AND C-13 NMR SPECTRA OF THE SEVEN-COORDINATE COMPLEXES [WI2(CO)(3)(NCR)(2)] (R=ME OR ET)

Drew MGB.; Armstrong EM.; Fraser SG.; Muldoon DJ.; Lavery AJ. Shawcross A.; Baker PK.

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SOLID STATE STRUCTURES AND C-13 NMR SPECTRA OF THE SEVEN-COORDINATE COMPLEXES [WI2(CO)(3)(NCR)(2)] (R=ME OR ET)

机译：七配位化合物[WI2（CO）（3）（NCR）（2）]的固态结构和C-13 NMR光谱（R = ME或ET）

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The X-ray crystal structures of the two seven-coordinate complexes [WI2(CO)(3)(NCR)(2)] {R = Me (1) or Et (2)} have been determined. In both structures, the molecules have crystallographic m symmetry. The geometries of the metal coordination spheres are very similar, conforming reasonably well to distorted capped octahedra. The C-13 NMR spectra of 1 and 2 are also described, and for the case of complex 1 can be correlated with the crystallographically observed geometry. [References: 22]

机译：已经确定了两个七坐标配合物[WI2（CO）（3）（NCR）（2）]的X射线晶体结构{R ＝ Me（1）或Et（2）}。在两种结构中，分子均具有晶体学对称性。金属配位球的几何形状非常相似，与扭曲的带帽八面体相当吻合。还描述了1和2的C-13 NMR光谱，对于配合物1，可以与晶体学观察到的几何形状相关。 [参考：22]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1995年第5期|共4页
作者
Drew MGB.; Armstrong EM.; Fraser SG.; Muldoon DJ.; Lavery AJ. Shawcross A.; Baker PK.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Ray crystal-structure; Carbonyl halides; Molybdenum(ii); Tungsten(ii); Ligands;

机译：射线晶体结构;卤化碳;钼（ii）;钨（ii）;配体;

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1. SOLID STATE STRUCTURES AND C-13 NMR SPECTRA OF THE SEVEN-COORDINATE COMPLEXES [WI2(CO)(3)(NCR)(2)] (R=ME OR ET) [J] . Drew MGB., Armstrong EM., Fraser SG., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1995,第5期

机译：七配位化合物[WI2（CO）（3）（NCR）（2）]的固态结构和C-13 NMR光谱（R = ME或ET）
2. Seven-coordinate thiophene-3-acetonitrile complexes of tungsten(II). Crystal structures of [WI2(CO)(3){NCCH2(3-C4H3S)}(2)] and[WI2(CO)(3){NCCH2(3-C4H3S)}(AsPh3)] [J] . Baker PK., Meehan MM., Parker EE., Journal of Organometallic Chemistry . 1998,第1a2期

机译：钨（II）的七配位噻吩-3-乙腈配合物。 [WI2（CO）（3）{NCCH2（3-C4H3S）}（2）]和[WI2（CO）（3）{NCCH2（3-C4H3S）}（AsPh3）的晶体结构]
3. NITRILE EXCHANGE REACTIONS OF [MI(2)(CO)(3)(NCME)(2)] (M=MO OR W) - X-RAY CRYSTAL STRUCTURES OF THE MIXED-LIGAND SEVEN-COORDINATE COMPLEXES [WI2(CO)(3)(NCR)(ASPH(3))] (R=ET OR PH) [J] . Baker PK., Hursthouse MB., Karaulov AI., Journal of Organometallic Chemistry . 1995,第1a2期

机译：[MI（2）（CO）（3）（NCME）（2）]的腈交换反应（M = MO或W）-混合配体七坐标络合物[WI2（CO）（ 3）（NCR）（ASPH（3））]（R = ET或PH）
4. The comparative analysis of the solid-state ~(31)P NMR spectra of Re-Pt vinylidene complexes [C] . K T Smolyarov, N V Volkov, A N Matsulev, International Conference on Applied Physics, Information Technologies and Engineering . 2020

机译：Re-Pt亚乙烯基复合物的固态〜（31）P NMR光谱的对比分析
5. Membrane protein secondary structure and spectral assignments by solid state NMR: Streptomyces lividans KcsA potassium channel and Escherichia coli ATP synthase subunit c. [D] . Varga, Krisztina. 2005

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6. Spectral editing of two-dimensional magic-angle-spinning solid-state NMR spectra for protein resonance assignment and structure determination [O] . K. Schmidt-Rohr, K. J. Fritzsching, S. Y. Liao, -1

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7. Investigation of chloromethane complexes of cryptophane-A analogue with butoxy groups using C-13 NMR in the solid state and solution along with single crystal X-ray diffraction [O] . Steiner, Emilie, Mathew, Renny, Zimmermann, Iwan, 2015

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SOLID STATE STRUCTURES AND C-13 NMR SPECTRA OF THE SEVEN-COORDINATE COMPLEXES [WI2(CO)(3)(NCR)(2)] (R=ME OR ET)

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