Reaction of Ru(PPh_3)_3l_2 with 2-(arylazo)pyrimidines. Spectral and redox characterisation of the products. Part V. Single crystal X-ray structure of Ru(PPh_3)_2(papm)Cl_2 (papm = 2-(phenylazo)pyrimidine)

Prasanta Kumar Santra; Chittaranjan Sinha; Wen-Jyh Sheen; Fen-Ling Liao; Tian-Huey Lu

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Reaction of Ru(PPh_3)_3l_2 with 2-(arylazo)pyrimidines. Spectral and redox characterisation of the products. Part V. Single crystal X-ray structure of Ru(PPh_3)_2(papm)Cl_2 (papm = 2-(phenylazo)pyrimidine)

机译：Ru（PPh_3）_3l_2与2-（芳基偶氮）嘧啶的反应。产品的光谱和氧化还原特性。第五部分Ru（PPh_3）_2（papm）Cl_2（papm = 2-（苯基偶氮）嘧啶）的单晶X射线结构

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Reaction of 2-(arylazo)pyrimidine (aapm) with Ru(PPh_3)_3Cl_2 in CH_2Cl_2 solution affords [Ru(PPh_3)_2(aapm)Cl_2] (2) while the reaction under refluxing conditions in EtOH isolates [Ru(PPh_3)_2(aapm)_2](ClO_4)_2·H_2O (3/4). Single crystal X-ray diffraction study of dichloro-bis(triphenylphosphine){2-(phenylazo)pyrimidine}ruthenium(II) has assigned a cis-Ru(PPh_3)_2 motif to the complex. Isomers of [Ru(PPh_3)_2(aapm)_2](ClO_4)_2 have been characterised by ~1H NMR data and they exist in cis-trans-cis and cis-cis-cis configurations in which coordination is considered with reference to three pairs of sequence of P, P (PPh_3 abbreviated as P), N, N (N is N(pyrimidine)) and N', N' (N' is N(azo)). The complexes exhibit MLCT transitions in the visible region. Redox studies show the Ru(III)/Ru(II) couple is in the range 0.8-1.2 V vs. SCE and [Ru(PPh_3)_2(aapm)_2](ClO_4)_2 exhibits a higher potential value than that of [Ru(PPh_3)_2(aapm)Cl_2].

机译：2-（芳基偶氮）嘧啶（aapm）与Ru（PPh_3）_3Cl_2在CH_2Cl_2溶液中反应生成[Ru（PPh_3）_2（aapm）Cl_2]（2），而在回流条件下在EtOH中的反应分离出[Ru（PPh_3）_2 （aapm）_2]（ClO_4）_2·H_2O（3/4）。二氯-双（三苯基膦）{2-（苯基偶氮）嘧啶}钌（II）的单晶X射线衍射研究已将顺式（Ru）（PPh_3）_2图案赋予了配合物。 [Ru（PPh_3）_2（aapm）_2]（ClO_4）_2的异构体已通过〜1H NMR数据表征，并且以顺-反-顺式和顺-顺-顺-顺式构型存在，其中考虑了三个对P，P（PPh_3缩写为P），N，N（N为N（嘧啶））和N'，N'（N'为N（偶氮））的序列对。该复合物在可见光区域表现出MLCT转变。氧化还原研究表明，相对于SCE，Ru（III）/ Ru（II）对在0.8-1.2 V范围内，并且[Ru（PPh_3）_2（aapm）_2]（ClO_4）_2的电势值高于[[ Ru（PPh_3）_2（aapm）Cl_2]。

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来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2001年第8期|共8页
作者
Prasanta Kumar Santra; Chittaranjan Sinha; Wen-Jyh Sheen; Fen-Ling Liao; Tian-Huey Lu;
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正文语种 eng
中图分类化学;无机化学;
关键词
Azopyrimidines; high potential ru(ii) complexes; phosphine; isomer; structures;

机译：偶氮嘧啶;高电位钌（ii）配合物;膦;异构体;结构;

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1. Reaction of Ru(PPh_3)_3l_2 with 2-(arylazo)pyrimidines. Spectral and redox characterisation of the products. Part V. Single crystal X-ray structure of Ru(PPh_3)_2(papm)Cl_2 (papm = 2-(phenylazo)pyrimidine) [J] . Prasanta Kumar Santra, Chittaranjan Sinha, Wen-Jyh Sheen, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2001,第7a8期

机译：Ru（PPh_3）_3l_2与2-（芳基偶氮）嘧啶的反应。产品的光谱和氧化还原特性。第五部分Ru（PPh_3）_2（papm）Cl_2（papm = 2-（苯基偶氮）嘧啶）的单晶X射线结构
2. Reaction of Ru(PPh3)(3)Cl-2 with 2-(arylazo)pyrimidines. Spectral and redox characterisation of the products. Part V. Single crystal X-ray structure of Ru(PPh3)(2)(papm)Cl-2 (papm=2-(phenylazo)pyrimidine) [J] . Santra PK., Sheen WJ., Liao FL., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2001,第7a8期

机译：Ru（PPh3）（3）Cl-2与2-（芳基偶氮）嘧啶的反应。产品的光谱和氧化还原特性。第五部分Ru（PPh3）（2）（papm）Cl-2（papm = 2-（苯基偶氮）嘧啶）的单晶X射线结构
3. Synthesis, spectral and electrochemical studies of 2-(arylazo)heterocycle complexes of zinc(II). Single-crystal X-ray structure of [Zn(papm)Cl_2·CH_3OH] (papm = 2-(phenylazo)pyrimidine) [J] . Jiban Kumar Nag, Prasanta Kumar Santra, Chittaranjan Sinha, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2001,第17期

机译：锌（II）的2-（芳基偶氮）杂环配合物的合成，光谱和电化学研究。 [Zn（papm）Cl_2·CH_3OH]（papm = 2-（苯基偶氮）嘧啶）的单晶X射线结构
4. Complexes of 2-(Phenylazo)pyridine. Chemical Reactivity and Crystal and Molecular Structure of Conformers of Ru(azpy)2(N3)2. [O] . Kirsten Krause, R. A. Krause, Sine Larsen, 1985

机译：吡啶的2-（苯氮杂）的复合物。 Ru（AZPY）2（N3）2的化学反应性和晶体和分子结构。

Reaction of Ru(PPh_3)_3l_2 with 2-(arylazo)pyrimidines. Spectral and redox characterisation of the products. Part V. Single crystal X-ray structure of Ru(PPh_3)_2(papm)Cl_2 (papm = 2-(phenylazo)pyrimidine)

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