Addition compounds of MoO2Br2 from MoO2Br2(H2O)2. Molecular structure of MoO2Br2{OP[N(CH3)(2)](3)}(2) and MoO2Br2{CH2[P(O)(C6H5)(2)](2)}

Arnaiz FJ.; Aguado R.; Pedrosa MR.; Mahia J.; Maestro MA.

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Addition compounds of MoO2Br2 from MoO2Br2(H2O)2. Molecular structure of MoO2Br2{OP[N(CH3)(2)](3)}(2) and MoO2Br2{CH2[P(O)(C6H5)(2)](2)}

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Addition compounds of MoO2Br2 from MoO2Br2(H2O)2. Molecular structure of MoO2Br2{OP[N(CH3)(2)](3)}(2) and MoO2Br2{CH2[P(O)(C6H5)(2)](2)}

机译：从MoO2Br2（H2O）2中添加MoO2Br2。 MoO2Br2 {OP [N（CH3）（2）]（3）}（2）和MoO2Br2 {CH2 [P（O）（C6H5）（2）]（2）}的分子结构

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MoO2Br2L2 (L=dimethyl formamide (DMF), N-methyl pirrolidone (NMP), dimethyl sulfoxide (DMSO), methyl phenyl sulfoxide (MePhSO), diphenyl sulfoxide (Ph-2,SO), hexamethyl phosphorotriamide (HMPA), triphenyl phosphine oxide (OPPh3), tributhyl phosphine oxide (OPBu3), triocthyl phosphine oxide (OPOct(3), methyl diphenyl phosphine oxide (OPMePh2), and 1/2 methylene bis(diphenyl phosphine) dioxide (dppmO(2))) have been prepared by reacting, a solution of MoO2Br2(H2O2), in diethyl ether with the corresponding ligand. The molecular structures of MoO2,Br-2(HMPA)(2) and MoO2Br2(dppmO(2),) have beeii established by X-ray diffraction analysis. The ability of MoO2Br2L2 to oxidize (CH3)(3)CSH to (CH3)CS-SC(CH3)(3) has been dctermined by H-1 NMR spectroscopy. (C) 2002 Elsevier Science Ltd. All rights reserved. [References: 24]

机译：MoO2Br2L2（L =二甲基甲酰胺（DMF），N-甲基吡咯烷酮（NMP），二甲基亚砜（DMSO），甲基苯基亚砜（MePhSO），二苯基亚砜（Ph-2，SO），六甲基磷三酰胺（HMPA），三苯基氧化膦（OPPh3），三丁基氧化膦（OPOct（3），甲基二苯基氧化膦（OPMePh2）和1/2亚甲基双（二苯基膦）二氧化二膦（dppmO（2）））已制备成反应后，MoO2Br2（H2O2）在乙醚中的溶液与相应的配体反应，通过X射线衍射确定了MoO2，Br-2（HMPA）（2）和MoO2Br2（dppmO（2），）的分子结构H-1 NMR光谱测定了MoO2Br2L2将（CH3）（3）CSH氧化为（CH3）CS-SC（CH3）（3）的能力（C）2002 Elsevier Science Ltd.保留所有权利。 [参考：24]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2002年第16期|共8页
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Arnaiz FJ.; Aguado R.; Pedrosa MR.; Mahia J.; Maestro MA.;
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1. Addition compounds of MoO2Br2 from MoO2Br2(H2O)2. Molecular structure of MoO2Br2{OP[N(CH3)(2)](3)}(2) and MoO2Br2{CH2[P(O)(C6H5)(2)](2)} [J] . Arnaiz FJ., Aguado R., Pedrosa MR., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2002,第16期

机译：从MoO2Br2（H2O）2中添加MoO2Br2。 MoO2Br2 {OP [N（CH3）（2）]（3）}（2）和MoO2Br2 {CH2 [P（O）（C6H5）（2）]（2）}的分子结构
2. Synthesis and spectroscopic properties of Mo(VI) complexes with phosphine oxide ligands and the crystal structures of [MoO2X2(OPMe3)(2)] (X=Cl or Br) and [MoO2Br2{0-C6H4(P(O)Ph-2)(2)}center dot 2CH(2)Cl(2) [J] . Hursthouse MB, Levason W, Ratnani R, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2004,第11期

机译：具有氧化膦配体的Mo（VI）配合物的合成和光谱性质以及[MoO2X2（OPMe3）（2）]（X = Cl或Br）和[MoO2Br2 {0-C6H4（P（O）Ph-2））（2）}中心点2CH（2）Cl（2）
3. Trans-dibromodioxodimethylformamide molybdenum(VI) MoO2Br2(OCHNMe2)(2) [J] . Drake JE, Hursthouse MB, Light ME, Journal of chemical crystallography . 2007,第6期

机译：反二溴二氧代二甲基甲酰胺钼（VI）MoO2Br2（OCHNMe2）（2）
4. Synthesis, structure and photochromic properties of a novel supramolecular compound (HisH2)2SiW12O40·6H2O [C] . SUN Dehui, ZHANG Jilin, REN Huijuan, International Conference on Advanced Fibers and Polymer Materials;ICAFPM . 2009

机译：新型超分子化合物（HisH2）2SiW12O40·6H2O的合成，结构与光致变色性能
5. 1. Molecular structure, electronic properties and crystal packing of 6-arylfulvenes. 2. Charge transfer in biphenyl bridged dicyclooctatetraenes [D] . Peterson, Matthew Lynn 1999

机译：1. 6-芳基富烯的分子结构，电子性质和晶体堆积。 2.联苯桥联的二环辛酸酯中的电荷转移
6. The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)2P(=N-t-Bu)—C(=CH2)CH(p-CH3O—C6H4)-P(O)(OCH2C(CH3)2CH2O)} [O] . G. Gangadhararao, Srinivas Venu 2011

机译：磷-迈克尔加成产物{（t-BuNH）P（μ-Nt-Bu）2P（= Nt-Bu）-C（= CH2）CH（p-CH3O-C6H4）-P（O）（OCH2C（ CH3）2CH2O）}
7. Preparation and Characterization of Cobalt(III)-Dimethyldithiocarbamato Complexes Containing R2P(CH2)nPR2(R=CH3, C6H5;n=1,2,3,4) and PR3(R=C2H5, C6H5). Crystal Structure of Co{(CH3)2NCS2}{(CH3)2PCH2P(CH3)2}2(BF4)2 [O] . Masakazu Kita, Akiyoshi Okuyama, Kazuo Kashiwabara, 1990

机译：含有R2P（CH2）NPR2（R = CH3，C6H5; N = 1,2,3,4）和PR3（R = C2H5，C6H5）的含钴（III） - 二甲基二硫代氨基甲酰胺配合物的制备及表征。 Co {（CH3）2NCS2}晶体结构{（CH3）2PCH2P（CH3）2} 2（BF4）2
8. Boranametallacarboranes. 2. Crystal and Molecular Structures of (2, 3-(C2H5)2C2B4H4)-5-Co(B9H12-1-O(CH2)4), (2,3-(CH3)2C2B3H5)-5-Co(B9H12-1-O(CH2)4), and (1,2-(C2H5)2C2B7H7)-6-Co(B9H12-2-O(CH2)4) [R] . Borodinsky, L., Sinn, E., Grimes, R. N. 1981

机译：Boranametallacarboranes。 2.（2,3-（C2H5）2C2B4H4）-5-Co（B9H12-1-O（CH2）4），（2,3-（CH3）2C2B3H5）-5-Co（B9H12-）的晶体和分子结构1-O（CH2）4）和（1,2-（C2H5）2C2B7H7）-6-Co（B9H12-2-O（CH2）4）

Addition compounds of MoO2Br2 from MoO2Br2(H2O)2. Molecular structure of MoO2Br2{OP[N(CH3)(2)](3)}(2) and MoO2Br2{CH2[P(O)(C6H5)(2)](2)}

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