COPPER(II) COMPLEXES OF HEPTANEDIOIC ACID (HDAH(2)) AND OCTANEDIOIC ACID (ODAH(2)) - X-RAY CRYSTAL STRUCTURES OF [CU(ETA(2)-HDA)(PHEN)(2)]CENTER-DOT-11.73H(2)O AND [CU(ETA(2)-ODA)(PHEN)2]CENTER-DOT-12H(2)O (PHEN=1,10-PHENANTHROLINE)

Mccann M.; Devereux M.; Ferguson G.; Cronin JF.

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >COPPER(II) COMPLEXES OF HEPTANEDIOIC ACID (HDAH(2)) AND OCTANEDIOIC ACID (ODAH(2)) - X-RAY CRYSTAL STRUCTURES OF [CU(ETA(2)-HDA)(PHEN)(2)]CENTER-DOT-11.73H(2)O AND [CU(ETA(2)-ODA)(PHEN)2]CENTER-DOT-12H(2)O (PHEN=1,10-PHENANTHROLINE)

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COPPER(II) COMPLEXES OF HEPTANEDIOIC ACID (HDAH(2)) AND OCTANEDIOIC ACID (ODAH(2)) - X-RAY CRYSTAL STRUCTURES OF [CU(ETA(2)-HDA)(PHEN)(2)]CENTER-DOT-11.73H(2)O AND [CU(ETA(2)-ODA)(PHEN)2]CENTER-DOT-12H(2)O (PHEN=1,10-PHENANTHROLINE)

机译：庚二酸（HDAH（2））和辛二酸（ODAH（2））的铜（II）络合物-[CU（ETA（2）-HDA）（PHEN）（2）] CENTER-DOT的X射线晶体结构-11.73H（2）O和[CU（ETA（2）-ODA）（PHEN）2] CENTER-DOT-12H（2）O（PHEN = 1,10-菲咯啉）

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The alpha,omega-dicarboxylic acids heptanedioic acid (hdaH(2)) and octanedioic acid (odaH(2)) reacted smoothly with [Cu-2(mu-O2CCH3)(4)(H2O)(2)] in water giving the insoluble copper(II) complexes [Cu(hda)] (1) and [Cu(oda)] (2). Complexes 1 and 2 reacted further with 1,10-phenanthroline (phen) giving [Cu(eta(2)-hda)(phen)(2)].chi H2O and [Cu(eta(2)-oda) (phen)(2)].chi H2O (chi approximate to 8), respectively. The X-ray crystal structures of [Cu(eta(2)-hda) (phen)(2)]. 11.73H(2)O (3) and [Cu(eta(2)-oda)(phen)(2)]. 12H(2)O (4) (i.e. chi = 11.73 and 12, respectively) reveal that, for each complex, the copper(II) atom is at the centre of a distorted octahedron comprising four nitrogen atoms from two chelating phen ligands and two oxygen atoms from a single asymmetric chelating carboxylate function, with the remaining carboxylate group of the diacid uncoordinated. [References: 23]

机译：α，ω-二羧酸庚二酸（hdaH（2））和辛二酸（odaH（2））在水中与[Cu-2（mu-O2CCH3）（4）（H2O）（2）]平稳反应，得到不溶性铜（II）配合物[Cu（hda）]（1）和[Cu（oda）]（2）。配合物1和2与1,10-菲咯啉（phen）进一步反应，得到[Cu（eta（2）-hda）（phen）（2）]。chi H2O和[Cu（eta（2）-oda）（phen）（2）.chi H 2 O（chi大约为8）。 [Cu（eta（2）-hda）（phen）（2）]的X射线晶体结构。 11.73H（2）O（3）和[Cu（eta（2）-oda）（phen）（2）]。 12H（2）O（4）（即chi分别为11.73和12）表明，对于每种络合物，铜（II）原子位于一个扭曲的八面体的中心，该八面体包含来自两个螯合酚配体和两个螯合苯基的四个氮原子来自单个不对称螯合羧酸盐的氧原子起作用，而二酸的其余羧酸盐基团未配位。 [参考：23]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1995年第18期|共9页
作者
Mccann M.; Devereux M.; Ferguson G.; Cronin JF.;
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正文语种 eng
中图分类化学;无机化学;
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Perchlorate;

机译：高氯酸盐;

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1. COPPER(II) COMPLEXES OF HEPTANEDIOIC ACID (HDAH(2)) AND OCTANEDIOIC ACID (ODAH(2)) - X-RAY CRYSTAL STRUCTURES OF [CU(ETA(2)-HDA)(PHEN)(2)]CENTER-DOT-11.73H(2)O AND [CU(ETA(2)-ODA)(PHEN)2]CENTER-DOT-12H(2)O (PHEN=1,10-PHENANTHROLINE) [J] . Mccann M., Devereux M., Ferguson G., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1995,第17a18期

机译：庚二酸（HDAH（2））和辛二酸（ODAH（2））的铜（II）络合物-[CU（ETA（2）-HDA）（PHEN）（2）] CENTER-DOT的X射线晶体结构-11.73H（2）O和[CU（ETA（2）-ODA）（PHEN）2] CENTER-DOT-12H（2）O（PHEN = 1,10-菲咯啉）
2. Sebacato-bridged Cu(II) phen complexes: syntheses and crystal structures of (2)(infinity)[Cu-2(phen)(2)L-4/2](H2O)(6) and [(phen)(2)Cu(mu-L)Cu(phen)(2)](HL)(2)(H2L)(H2O)(4) (H2L = sebacic acid; phen = 1,10-phenanthroline) [J] . Wei DY., Kong ZP., Zheng YQ. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2002,第16期

机译：癸二酸桥接的Cu（II）phen配合物：（2）（无穷大）[Cu-2（phen）（2）L-4 / 2]（H2O）（6）和[（phen）（2）的合成和晶体结构）Cu（mu-L）Cu（phen）（2）]（HL）（2）（H2L）（H2O）（4）（H2L =癸二酸; phen = 1,10-菲咯啉）
3. Dihydroxo-bridged dimeric Cu(II) system containing sandwiched non-coordinating phenylacetate anion: Crystal structure, spectroscopic, anti-bacterial, anti-fungal and DNA-binding studies of [(Phen)(H2O)Cu(OH)(2)Cu(H2O)(phen)2L center dot 6H(2)O: (HL = phenylacetic acid; phen=1,10-phenanthroline) [J] . Iqbal Muhammad, Ali Saqib, Tahir Muhammad Nawaz, Journal of Molecular Structure . 2017,第期

机译：二羟基桥接二聚体Cu（II）体系含有夹层的非协调苯乙酸阴离子：晶体结构，光谱，抗菌，抗真菌和抗真菌和DNA结合研究[（Phen）（H 2 O）Cu（OH）（2）Cu （H 2 O）（Phen）2L中心点6H（2）O :( HL =苯乙酸; Phen = 1,10菲咯啉）
4. Hydrothermal Synthesis and Characterization of the Coordination Polymers with bta =Benzene-1,2,4,5- tetracarboxylate as Bridging Ligand: {Cu(phen)(μ4-bta)1/2· (H2O)}n(phen= 1,10-phenanthroline) [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：以bta =苯-1,2,4,5-四羧酸苯酯为桥联配体的水热合成和表征：{Cu（phen）（μ4-bta）1/2·（H2O）} n（phen = 1,10-菲咯啉
5. Organometallic photonucleases. I. DNA cleavage by the photolysis of cyclopentadienyl metal complexes: Mechanistic studies and sequence selectivity of strand scission by CpW(CO)3CH3. II. Footprinting of chromatin structure and chromatin remodeling by SWI/SNF utilizing CpW(CO)3CH3. III. Dual mechanisms of DNA damage by MoX(eta3-allyl)(CO)3(phen) complexes. [D] . Downs, Jennifer. 2005

机译：有机金属光核酸酶。 I.通过环戊二烯基金属配合物的光解来切割DNA：通过CpW（CO）3CH3进行断裂的机理研究和序列选择性。二。 SWI / SNF利用CpW（CO）3CH3进行染色质结构足迹测定和染色质重塑。三， MoX（eta3-烯丙基）（CO）3（phen）复合物对DNA的双重破坏机制。
6. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of Mn(ph)(Phen)2(H2O)· 4H2O Mn(Phen)2(H2O)22(Isoph)2(Phen)· 12H2O and {Mn(Isoph)(bipy)4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 110-Phenanthroline; bipy = 22-Bipyridine) [O] . Michael Devereux, Malachy McCann, Vanessa Leon, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：Mn（ph）（Phen）2（H2O）·4H2OMn（Phen）2（H2O）2 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{Mn（Isoph）（bipy） 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 110-邻菲咯啉; bipy = 22 -联吡啶）
7. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of [Mn(ph)(Phen)2(H2O)]· 4H2O, [Mn(Phen)2(H2O)2]2(Isoph)2(Phen)· 12H2O and {[Mn(Isoph)(bipy)]4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 1,10-Phenanthroline; bipy = 2,2-Bipyridine) [O] . Devereux, Michael, McCann, Malachy, Leon, Vanessa, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：[Mn（ph）（Phen）2（H2O）]·4H2O，[Mn（Phen）2（H2O）2] 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{[Mn（Isoph）（bipy）] 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 1,10-邻菲咯啉; bipy = 2,2 -联吡啶）
8. Novel Square Pyramidal Copper(II) Complexes of the Stereospecific Linear NSNNTetradentate Ligand N-((2-Pyridyl)methyl)-2-((2-Aminoethyl)thio) Acetamide (pygeH). The Crystal Structures of (Cu(pyge)X) (X = Br, N3) [R] . Toscano, P. J., Fordon, K. J., Macherone, D., 1990

机译：新型方形金字塔形铜（II）配合物的立体特异性线性NsNN四齿配体N - （（2-吡啶基）甲基）-2 - （（2-氨基乙基）硫代）乙酰胺（pygeH）。（Cu（pyge）X）（X = Br，N3）的晶体结构

COPPER(II) COMPLEXES OF HEPTANEDIOIC ACID (HDAH(2)) AND OCTANEDIOIC ACID (ODAH(2)) - X-RAY CRYSTAL STRUCTURES OF [CU(ETA(2)-HDA)(PHEN)(2)]CENTER-DOT-11.73H(2)O AND [CU(ETA(2)-ODA)(PHEN)2]CENTER-DOT-12H(2)O (PHEN=1,10-PHENANTHROLINE)

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