Synthesis, structural investigations and magnetic properties of dipyridinated manganese phthalocyanine, MnPc(py)(2)

Janczak J.; Kubiak R.; Sledz M.; Borrmann H.; Grin Y.

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Synthesis, structural investigations and magnetic properties of dipyridinated manganese phthalocyanine, MnPc(py)(2)

机译：二吡啶锰酞菁MnPc（py）（2）的合成，结构研究和磁性

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The MnPc(py)(2) complex was obtained in the reaction of MnPc with purified and dry pyridine under non-oxidation conditions. It crystallises in the centrosymmetric space group P2(1)/c of the monoclinic system with two molecules per unit cell. The Mn2+ cation is coordinated by four N-isoindole atoms of phthalocyaninato(2-) macrocycle and axially by two nitrogen atoms of pyridine molecules into a tetragonal bipyramid. The MnPC(py)(2) crystals are moderately stable under air, but in pyridine solution the MnPC(py)2 complex undergoes oxidation by O-2 Yieldings the binuclear manganese(III) mu-oxo complex (MnPcpy)(2)O as evidenced by the UV-Vis spectroscopy. The magnetic susceptibility measurement performed on solid sample of MnPC(py)(2) shows the Curie-Weiss behaviour in the temperature region of 300-15 K. The calculated magnetic moment mu(eff) indicates three impaired electrons (S = 3/2), thus the ground state configuration of Mn ion is (a(Ig))(2)(e(g))(2)(b(2g))(1), and the MnPc(py)(2) complex is the intermediate spin complex. Below 5.5 K (T-N) the magnetic susceptibility sharply decreases due to the cooperative intermolecular antiferromagnetic interactions. (C) 2003 Elsevier Ltd. All rights reserved. [References: 68]

机译：MnPc（py）（2）配合物是在非氧化条件下，将MnPc与纯化和干燥的吡啶反应制得的。它在单斜晶系的中心对称空间群P2（1）/ c中结晶，每个单元格有两个分子。 Mn2 +阳离子由酞菁基（2-）大环的四个N-异吲哚原子配位，并由吡啶分子的两个氮原子轴向配位成四方双锥体。 MnPC（py）（2）晶体在空气中中等稳定，但在吡啶溶液中，MnPC（py）2络合物通过O-2氧化，生成双核锰（III）mu-oxo络合物（MnPcpy）（2）O如紫外-可见光谱所证明的。对MnPC（py）（2）固体样品进行的磁化率测量显示，在300-15 K的温度范围内，居里-魏斯行为。计算出的磁矩mu（eff）表示三个受损的电子（S = 3/2）），因此Mn离子的基态构型为（a（Ig））（2）（e（g））（2）（b（2g））（1），而MnPc（py）（2）络合物为中间自旋复合体。低于5.5 K（T-N），由于协同分子间反铁磁相互作用，磁化率急剧下降。（C）2003 Elsevier Ltd.保留所有权利。 [参考：68]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2003年第19期|共9页
作者
Janczak J.; Kubiak R.; Sledz M.; Borrmann H.; Grin Y.;
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正文语种 eng
中图分类化学;
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Dipyridinated manganese(ii) phthalocyanine; Crystal structures; Magnetic properties; Antiferromagnetic interactions; Oxidation; Uv-vis spectroscopy; Magnesium tetraphenylporphyrin complexes; Extended huckel calculations; Electronic ground-state; X-ray crystal; Iron(ii) phthalocyanine; Metal phthalocyanines; Molecular structure; Paramagnetic anisotropy; Zinc phthalocyanine; Circular-dichroism;

机译：二吡啶化酞菁锰;晶体结构;磁性;反铁磁相互作用;氧化;紫外可见光谱;四苯基卟啉镁配合物;扩展的huckel计算;电子基态;X射线晶体;铁（ii）酞菁;金属酞菁分子结构;磁各向异性;锌酞菁;圆二色性;

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1. Synthesis, structural investigations and magnetic properties of dipyridinated manganese phthalocyanine, MnPc(py)(2) [J] . Janczak J., Kubiak R., Sledz M., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2003,第19期

机译：二吡啶锰酞菁MnPc（py）（2）的合成，结构研究和磁性
2. Synthesis, crystal structure, and high-precision high-frequency and -field electron paramagnetic resonance investigation of a manganese(III) complex: [Mn(dbm)(2)(py)(2)](ClO4) [J] . Aromi G, Telser J, Ozarowski A, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2005,第2期

机译：锰（III）配合物[Mn（dbm）（2）（py）（2）]（ClO4）的合成，晶体结构以及高精度的高频和场电子顺磁共振研究
3. Synthesis, structural and magnetic properties of ternary complexes of (Me_4P~+)·{[Fe(I)Pc(-2)]~-} ·triptycene and (Me_4P~+)·{[Fe(I)Pc(-2)] ~-}·(N, N, N ', N '-tetrabenzyl- p -phenylenediamine)_(0.5) with iron(I) phthalocyanine anions [J] . Konarev D.V., Ishikawa M., Khasanov S.S., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2013,第7期

机译：（Me_4P〜+）·{[Fe（I）Pc（-2）]〜-}·三萜和（Me_4P〜+）·{{Fe（I）Pc（-2）的三元配合物的合成，结构和磁性）]〜-}·（N，N，N'，N'-四苄基-对苯二胺）_（0.5）含铁（I）酞菁阴离子
4. Contrasting agent for magnetic resonance imaging based on nanostructural dispersion of Manganese derivative of phthalocyanine: preliminary investigation results [C] . I.G. Meerovich, G.A. Meerovich, O.V. Dolotova, Nanotechnology 2009 : Technical proceedings . 2009

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机译：具有结构，光学，电子和磁性特性的定义明确的聚合物/无机核-壳纳米材料的合成和性能研究。
6. Synthesis and electrochemical properties of copper(II) manganese(III) phthalocyanines bearing chalcone groups at peripheral or nonperipheral positions [O] . Hüseyin BAŞ, Nuran KAHRİMAN, Zekeriya BIYIKLIOĞLU* 2020

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7. Synthesis, Crystal Structure, and High-Precision High-Frequency and -Field Electron Paramagnetic Resonance Investigation of a Manganese(III) Complex: Mn(dbm)2(py)2(ClO4) [O] . -1

机译：锰（III）复合物的合成，晶体结构和高精度高频和菲尔德电子顺磁共振调查：Mn（DBM）2（PY）2（CLO4）
8. Polymers with Conjugation System. Part 50. Synthesis and Investigation of Electrophysical Properties of Phthalocyanine Polymers (Polymeric Phthalocyanines) [R] . Berlin, A. A., Cherkashina, L. G. 1965

机译：具有共轭体系的聚合物。第50部分。酞菁聚合物（聚合酞菁）的电子物理性质的合成和研究

Synthesis, structural investigations and magnetic properties of dipyridinated manganese phthalocyanine, MnPc(py)(2)

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