Synthesis, structure and anti-fungal activity of dimeric Ag(I) complexes containing bis-imidazole ligands

Abuskhuna S; Briody J; McCann M; Devereux M; Kavanagh K; Fontecha JB; McKee V

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Synthesis, structure and anti-fungal activity of dimeric Ag(I) complexes containing bis-imidazole ligands

机译：含双咪唑配体的二聚Ag（I）配合物的合成，结构和抗真菌活性

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;ive Ag(I) complexes containing the ligands bis(imidazol-2-yl)methane (2-BIM) and its derivatives were prepared and [Ag-2(2-BIM)(2)](ClO4)(2) and [Ag-2(2-BIM(Bz)OH)(2)](ClO4)(2) . EtOH were characterised using X-ray crystallography. In each dimer the two Ag(I) ions are two-coordinate and there are small but definite argentophilic Ag-Ag (d(10)-d(10)) interactions. All of the complexes display anti-fungal activity when tested in vitro against the fungal pathogen Candida albicans. (C) 2004 Elsevier Ltd. All rights reserved.

机译：制备含有配体双（咪唑-2-基）甲烷（2-BIM）及其衍生物的Ag（I）配合物，并制备[Ag-2（2-BIM）（2）]（ClO4）（2）和[Ag-2（2-BIM（Bz）OH）（2）]（ClO4）（2）。使用X射线晶体学表征EtOH。在每个二聚体中，两个Ag（I）离子是两个坐标的，并且存在很小但确定的纯银Ag-Ag（d（10）-d（10））相互作用。当针对真菌病原体白色念珠菌进行体外测试时，所有复合物均显示出抗真菌活性。（C）2004 Elsevier Ltd.保留所有权利。

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来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2004年第7期|共7页
作者
Abuskhuna S; Briody J; McCann M; Devereux M; Kavanagh K; Fontecha JB; McKee V;
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正文语种 eng
中图分类化学;
关键词
bis-imidazole; bis(imidazol-2-yl)methane; X-ray structures; silver(I); argentophilicity; anti-fungal; Candida albicans; ANTIMICROBIAL ACTIVITY; CRYSTAL-STRUCTURE; METAL-COMPLEXES; 1; 10-PHENANTHROLINE; COPPER(II);

机译：双咪唑;双（咪唑-2-基）甲烷;X射线结构;银（I）;嗜酸性;抗真菌;白色念珠菌;抗菌活性;晶体结构;金属络合物;1;10-苯酚;铜（II）;

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1. Synthesis, structure and anti-fungal activity of dimeric Ag(I) complexes containing bis-imidazole ligands [J] . Abuskhuna S, Briody J, McCann M, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2004,第7期

机译：含双咪唑配体的二聚Ag（I）配合物的合成，结构和抗真菌活性
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7. Synthesis, structure and anti-fungal activity of dimeric Ag(I) complexes containing bis-imidazole ligands [O] . Abuskhuna, A., Briody, J.M., McCann, M., 2004

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Synthesis, structure and anti-fungal activity of dimeric Ag(I) complexes containing bis-imidazole ligands

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