Synthesis, X-ray crystal structure, and solution properties of nickel(II) complexes of new 16-membered mixed-donor-macrocyclic Schiff base ligand incorporating a pendant alcohol function

Khandar AA.; Hosseini-Yazdi SA.

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Synthesis, X-ray crystal structure, and solution properties of nickel(II) complexes of new 16-membered mixed-donor-macrocyclic Schiff base ligand incorporating a pendant alcohol function

机译：带有侧链醇官能团的新型16元混合供体-大环席夫碱配体的镍（II）配合物的合成，X射线晶体结构和溶液性质

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The synthesis of N2O3 macrocyclic ligand 8,9,18,19-tetrahydro-7H,17H-dibenzo[fo][1,5,9,13] dioxadiazacyclohexadecin-18-ol (L = 2) and preparation of complexes NiLX2 (X = Cl, Br, 1, ClO4) and NiLXY (X = Cl, Br, I and Y = ClO4) are reported. NiLX2 complexes were prepared by facile template reactions of appropriate dialdehyde 2-[3-(2-formylphenoxy)-2-hydroxypropoxy]bezaldehyde (1) and 1,3-diaminopropane in the presence of Ni(II) salts. Reactions of NiL(ClO4)(2) (2d) with lithium halides resulted in NiLXY complexes. From spectroscopic measurements and conductivity studies of the complexes it is followed that the six-coordinate species NiLX+ are formed in solution except 2d. In all complexes the ligand behaves as a pentadentate ligand. Complexes 2b . CH3CN and 2b . 1.75CH(3)CN (2b = NiLBr2) contain nickel in a distorted octahedral environment of N2O3Br donors. (C) 2003 Elsevier Science Ltd. All rights reserved. [References: 32]

机译：N2O3大环配体8,9,18,19-四氢-7H，17H-二苯并[fo] [1,5,9,13]二氧杂氮杂环十六烷-18-ol（L = 2）的合成和配合物NiLX2（X报道了Cl ＝ Br，1，ClO 4）和NiLXY（X ＝ Cl，Br，I和Y ＝ ClO 4）。通过在Ni（II）盐存在下合适的二醛2- [3-（2-甲酰基苯氧基）-2-羟基丙氧基]苯甲醛（1）和1,3-二氨基丙烷的简便模板反应制备NiLX2复合物。 NiL（ClO4）（2）（2d）与卤化锂的反应生成NiLXY配合物。从配合物的光谱测量和电导率研究可以看出，除了2d外，六配位物种NiLX +在溶液中形成。在所有配合物中，配体均表现为五齿配体。配合物2b。 CH 3 CN和2b。 1.75CH（3）CN（2b = NiLBr2）在扭曲的N2O3Br供体的八面体环境中包含镍。（C）2003 Elsevier ScienceLtd。保留所有权利。 [参考：32]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2003年第11期|共7页
作者
Khandar AA.; Hosseini-Yazdi SA.;
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正文语种 eng
中图分类化学;
关键词
Macrocycle; Schiff base; Template; Nickel(ii) complexes; Mixed-donor macrocycles; Azacrown ethers; Metal-ion recognition; Copper(ii); Binding; Cadmium(ii); Zinc(ii); Series;

机译：大环;席夫碱;模板;镍（ii）配合物;混合施主大环;氮杂冠醚;金属离子识别;铜（ii）;结合;镉（ii）;锌（ii）;系列;

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1. Synthesis, X-ray crystal structure, and solution properties of nickel(II) complexes of new 16-membered mixed-donor-macrocyclic Schiff base ligand incorporating a pendant alcohol function [J] . Khandar AA., Hosseini-Yazdi SA. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2003,第11期

机译：带有侧链醇官能团的新型16元混合供体-大环席夫碱配体的镍（II）配合物的合成，X射线晶体结构和溶液性质
2. Synthesis, characterization and structure of nickel(II) complexes of a 16-membered mixed-donor macrocyclic Schiff base ligand, potentially hexadentate, bearing two pendant alcohol functions [J] . Khandar AA, Hosseini-Yazdi SA, Khatamian M, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2007,第26期

机译：带有两个侧链醇官能团的16元混合供体大环席夫碱配体（可能为六齿）镍（II）配合物的合成，表征和结构
3. Template synthesis, and X-ray crystal structures of copper(II) and nickel(II) complexes of new unsymmetrical tetradentate Schiff base ligands. Electrochemistry, antibacterial properties, and metal ion effect on hydrolysis-recondensation of the ligand [J] . Meghdadi Soraia, Amirnasr Mehdi, Majedi Mona, Inorganica Chimica Acta . 2015,第Null期

机译：新的不对称四齿席夫碱配体的铜（II）和镍（II）配合物的模板合成和X射线晶体结构。电化学，抗菌性能和金属离子对配体水解-缩合的影响
4. Dependence of Stability of the Polymerizesd Nickel Complexes with Schiff Bases on the Structure of the Ligand Diimine Bridge [C] . E. V. Alekseeva, V. A. Ershov, A. S. Konev, International Conference on Advanced Batteries, Accumulators and Fuel Cells . 2018

机译：聚合镍复合物与席夫碱对配体二亚胺桥结构的依赖性依赖性
5. (1,3-Bis(2'-pyridylimino)isoindolinato)nickel(II) complexes of phenylcyanamido ligands: Crystal structure, solution and spectroscopic properties [D] . Letcher, Robert J. 1991

机译：苯基氰酰胺基配体的（1,3-双（2'-吡啶基氨基）异吲哚并合）镍（II）配合物：晶体结构，溶液和光谱性质
6. Trinuclear NiII-LnIII-NiII Complexes with Schiff Base Ligands: Synthesis Structure and Magnetic Properties [O] . Anastasia N. Georgopoulou, Michael Pissas, Vassilis Psycharis, 2020

机译：含席夫碱配体的三核NiII-LnIII-NiII配合物：合成结构和磁性
7. Synthesis and X-Ray Crystal Structures of Trinuclear Nickel(II) Complexes Derived from Schiff Bases and Acetate Ligands with Biological Activity [O] . Jin-Long Hou, Hong-Yuan Wu, Cheng-Bin Sun, 2020

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机译：（au（CH2）2pph2）2（CF3）2，（au（CH2）2pph2）2（C6F5）2和（ppN）（au（C6F5）4）的合成和X射线晶体结构：两个双核金（ II）含有烷基和芳基配体的Ylide配合物和四（五氟苯基）丙酸酯（III）

Synthesis, X-ray crystal structure, and solution properties of nickel(II) complexes of new 16-membered mixed-donor-macrocyclic Schiff base ligand incorporating a pendant alcohol function

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