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首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Backscatter Fe-57 Mossbauer studies of iron(II) phthalocyanine
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Backscatter Fe-57 Mossbauer studies of iron(II) phthalocyanine

机译:Fe-57 Mossbauer的反向散射研究酞菁铁(II)

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摘要

Phthalocyanines are established gas sensitive materials. We have successfully recorded backscatter conversion electron Mossbauer spectra (CEMS) of iron(ll) phthalocyanine. Further, we have shown that the introduction of nitrogen dioxide, a typical analyte for these materials, into the detector system can be achieved without deleterious effects. The method allows surface sensitive spectra of these materials to be recorded under normal sensor operating conditions of temperature and pressure. The high vacuum conditions of other surface sensitive techniques used to study materials of this type are not required by this method. (C) 2002 Elsevier Science Ltd. All rights reserved. [References: 14]
机译:酞菁是公认的气体敏感材料。我们已经成功地记录了铁(II)酞菁的背散射转换电子Mossbauer光谱(CEMS)。此外,我们已经表明,可以将二氧化氮(这些材料的典型分析物)引入检测器系统,而不会造成有害影响。该方法允许在温度和压力的正常传感器工作条件下记录这些材料的表面敏感光谱。该方法不需要用于研究此类材料的其他表面敏感技术的高真空条件。 (C)2002 Elsevier ScienceLtd。保留所有权利。 [参考:14]

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