Three interpenetrated frameworks constructed by long flexible N,N '-bipyridyl and dicarboxylate ligands

Li XJ; Cao R; Bi WH; Wang YQ; Wang YL; Li X

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Three interpenetrated frameworks constructed by long flexible N,N '-bipyridyl and dicarboxylate ligands

机译：由长的柔性N，N'-联吡啶和二羧酸酯配体构建的三个互穿框架

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Three interpenetrated polymeric networks, {[Co(bpp)(OH-BDC)] (.) H2O}(n) (1) [Ni(bpp)(1.5)(H2O)(OH-BDC)](n) (2) and {[Cd(bpp)(H2O)(OH-BDC)](.)2H(2)O}(n) (3), have been prepared by hydrothermal reactions of 1,3-bis(4-pyridyl)propane (bpp), 5-hydroxyisophthalic acid (OH-H2BDC), with Co(NO3)(2) (.) 6H(2)O, Ni(NO3)(2) (.) 6H(2)O and Cd(NO3)(2) (.) 4H(2)O, respectively. Single-crystal X-ray diffraction analyses reveal that the three compounds all exhibit interpenetrated but entirely different structures. Compound 1 is a fourfold interpenetrated adamantanoid structure with water molecules as space fillers, in which bpp adopts a TG conformation (T = trans, G = gauche). Compound 2 is all interdigitated structure from the interpenetrated long arms of one-dimensional molecular ladders, while bpp in 2 adopts both TT and TG conformations. Compound 3 is a twofold interpenetrated three-dimensional network from a one-dimensional metal-carboxylate chain bridged by TG conformational bpp. The hydrogen bonding interactions in 1-3 further stabilize the whole structural frameworks and play critical roles in their Constructions. (c) 2005 Elsevier Ltd. All rights reserved.

机译：三个互穿的聚合物网络，{[Co（bpp）（OH-BDC）]（。）H2O}（n）（1）[Ni（bpp）（1.5）（H2O）（OH-BDC）]（n）（2 ）和{[Cd（bpp）（H2O）（OH-BDC）]（。）2H（2）O}（n）（3）已通过1,3-双（4-吡啶基）水热反应制备丙烷（bpp），5-羟基间苯二甲酸（OH-H2BDC）与Co（NO3）（2）（。）6H（2）O，Ni（NO3）（2）（。）6H（2）O和Cd（ NO3）（2）（。）4H（2）O。 X射线单晶衍射分析表明这三种化合物都具有互穿但完全不同的结构。化合物1是具有水分子作为空间填充物的四重互穿金刚烷类结构，其中bpp采用TG构象（T =反式，G =乳脂状）。化合物2都是一维分子梯的互穿长臂的互指结构，而bpp in 2则采用TT和TG构象。化合物3是由TG构象bpp桥接的一维金属羧酸盐链的两倍互穿的三维网络。 1-3中的氢键相互作用进一步稳定了整个结构框架，并在其结构中起关键作用。（c）2005 Elsevier Ltd.保留所有权利。

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2005年第18期|共8页
作者
Li XJ; Cao R; Bi WH; Wang YQ; Wang YL; Li X;
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正文语种 eng
中图分类化学;
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cobalt(II); nickel(II); cadmium(II); X-ray diffraction; interpenetrated; 2-D COORDINATION POLYMER; MOLECULAR LADDERS; CRYSTAL-STRUCTURE; NETWORKS; LAYERS; ARCHITECTURES; COMPLEXES;

机译：钴（II）;镍（II）;镉（II）;X射线衍射;互穿;二维配位聚合物;分子梯;晶体结构;网络;层;体系结构;复合物;

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1. Three interpenetrated frameworks constructed by long flexible N,N '-bipyridyl and dicarboxylate ligands [J] . Li XJ, Cao R, Bi WH, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2005,第18期

机译：由长的柔性N，N'-联吡啶和二羧酸酯配体构建的三个互穿框架
2. Polycatenated bilayer motif constructed from flexible N, N'-bipyridyl and aromatic dicarboxylate ligands [J] . Xin Zhang, Zhao-Ji Li, Ye-Yan Qin Inorganic Chemistry Communications . 2012,第Null期

机译：由柔性N，N'-联吡啶基和芳香族二羧酸酯配体构成的多链双层基序
3. Two novel interpenetrating MOFs constructed from a derivative of phenanthroline and a V-shaped flexible dicarboxylate ligand contains unique chiral structure [J] . Huang W.-H., Hou L., Liu B., Inorganica Chimica Acta . 2012,第Null期

机译：由菲咯啉衍生物和V形柔性二羧酸配体构成的两个新型互穿MOF包含独特的手性结构
4. A Mn(II) Metal-Organic Framework Constructed from a Tetrahedral Silicon-Cored Ligand [C] . Qing-Yu Ma, Rui-Fang Guan, Guo-Zhong Li, International Conference on Applied Mechanics and Materials . 2013

机译：由四面体硅芯配体构成的Mn（II）金属有机骨架
5. Synthesis of metal-organic frameworks containing perfluorinated dicarboxylates [D] . Hulvey, Zeric 2010

机译：含全氟二羧酸盐的金属有机骨架的合成
6. A Pair of CoII Supramolecular Isomers Based on Flexible Bis-Pyridyl-Bis-Amide and Angular Dicarboxylate Ligands [O] . Pradhumna Mahat Chhetri, Ming-Hao Wu, Chou-Ting Hsieh, 2020

机译：基于柔性双-吡啶基-双-酰胺和角二羧酸盐配体的一对CoII超分子异构体
7. One-dimensional and two-dimensional coordination polymers constructed from Cd2+ ions and flexible bipyridyl bridging ligands [O] . Plater, M. John, De Silva, Ben M., Foreman, Mark R. St J., 2015

机译：由Cd2 +离子和柔性联吡啶桥联配体构成的一维和二维配位聚合物

Three interpenetrated frameworks constructed by long flexible N,N '-bipyridyl and dicarboxylate ligands

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