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Dispersion of Multiwalled Carbon Nanotubes in Thermoplastic Elastomer Gels: Morphological, Rheological, and Electrical Properties

机译:碳纳米管在热塑性弹性体凝胶中的分散:形态,流变和电学性质

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摘要

An investigation was reported here with an aim to prepare nanocomposite thermoplastic elastomer gels by dissolving polystyrene-b-poly(ethylene/butylene)-b-pol-ystyrene (SEBS) triblock copolymer in selective hydrocarbon oils with the presence of multiwalled carbon nanotubes (MWCNTs). The properties related to morphology, viscoelasticity, electrical and mechanical properties, and thermal stability were explored and discussed. Dynamic rheological measurements of the resultant nanocomposite thermoplastic elastomer gels (NCTPEGs) confirmed that addition of MWCNTs affects the linear viscoelastic properties in which dynamic storage and loss moduli increase to some extent. At a temperature between 30 C and 40 C below the gel point the NCTPEGs have dynamic storage modulus greater than loss modulus (G' and G"), thereby indicating that at room temperature a physical network is still present despite the addition of MWCNTs. The morphological properties revealed that MWCNTs were dispersed and exfoliated within the swollen TPE. The incorporation of small quantity of MWCNTs improved the thermal stability and mechanical properties of NCTPEGs.
机译:本文报道了一项研究,目的是通过在多壁碳纳米管(MWCNTs)存在下,将聚苯乙烯-b-聚(乙烯/丁烯)-b-聚苯乙烯(SEBS)三嵌段共聚物溶于选择性烃油中来制备纳米复合热塑性弹性体凝胶。 )。探索和讨论了与形态,粘弹性,电和机械性能以及热稳定性有关的性能。所得纳米复合热塑性弹性体凝胶(NCTPEGs)的动态流变学测量结果证实,添加MWCNTs会影响线性粘弹性,动态储能和损耗模量在一定程度上增加。在低于胶凝点的30到40℃之间的温度下,NCTPEG的动态储能模量大于损耗模量(G'和G“),从而表明在室温下,尽管添加了MWCNT,物理网络仍然存在。形态学特征表明,MWCNTs在膨胀的TPE中分散和剥落,少量MWCNTs的掺入提高了NCPTPEGs的热稳定性和力学性能。

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