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首页> 外文期刊>Polymers for advanced technologies >Polymerization of anilinium-DBSA in the presence of clay particles: kinetics and formation of core-shell structures
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Polymerization of anilinium-DBSA in the presence of clay particles: kinetics and formation of core-shell structures

机译：粘土颗粒存在下苯胺-DBSA的聚合：动力学和核-壳结构的形成

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This paper is an extension of previous work on polymerization of anilinium-DBSA (dodecylbenzenesulfonic acid) in an aqueous dispersion in the presence of mica or talc silicate particles. The presence of mica or talc particles greatly accelerates the polymerization process of anilinium-DBSA and an encapsulated structure is farmed as well. The catalytic effect of various metallic cations which exist in the chemical compositions of mica or talc on the polymerization kinetics of anilinium-DBSA was investigated. The conductivity results along with microscopy observations prove a well farmed encapsulated structure for the polyaniline/mica composites, but less far the polyaniline/talc composites. The anilinium-DBSA complex and mica aqueous dispersions pretreated at different temperatures prior to polymerization have shown a significant effect on the polymerization rate of anilinium-DBSA. The higher the dispersion temperature, the higher is the polymerization rate found.
机译：本文是在云母或滑石硅酸盐颗粒存在下，在水分散液中聚合苯胺-DBSA（十二烷基苯磺酸）的先前工作的扩展。云母或滑石颗粒的存在极大地促进了苯胺-DBSA的聚合过程，并且还封装了一种封装结构。研究了云母或滑石的化学组成中存在的各种金属阳离子对苯胺-DBSA聚合动力学的催化作用。电导率结果和显微镜观察结果证明，聚苯胺/云母复合材料具有良好的封装结构，而聚苯胺/滑石复合材料的结构远没有那么广泛。在聚合之前在不同温度下预处理的苯胺-DBSA配合物和云母水分散体已显示出对苯胺-DBSA的聚合速率的显着影响。分散温度越高，发现的聚合速率越高。

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