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The mechanism for fracture resistance in β-nucleated isotactic polypropylene

机译:β-成核等规聚丙烯的抗断裂机理

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The effects of molecular weight (MW) of isotactic polypropylene (iPP), the content of β-PP, the size of its spherulites and the morphology of its α-phase and β-phase (α- and β-PP) on the impact strength, with different contents of β-nucleating agent, were investigated by two ways. The results show that the impact strength of iPPs increased initially, and then decreased with the content of β-nucleating agent (maximum at 0.1 wt%). The impact strength was related to the size of β-spherulites and had no apparent correlation with the content of β-PP. The morphology of the bundle shape and intercrossing boundaries of β-spherulites were dominant in improving impact strength with low content of β-nucleating agent, while the MW of iPP was dominant with high content of β-nucleating agent.
机译:等规聚丙烯(iPP)的分子量(MW),β-PP的含量,其球晶的尺寸以及其α相和β相(α-和β-PP)的形态对其影响的影响通过两种方法研究了不同含量的β-成核剂的强度。结果表明,iPPs的冲击强度先增加,然后随β成核剂含量的增加而降低(最大为0.1 wt%)。冲击强度与β-球晶的大小有关,与β-PP的含量没有明显的相关性。 β-成球剂的束形状和交叉边界的形态在降低冲击强度方面占主导地位,而β-成核剂的含量低,而iPP的MW占主导地位,而β-成核剂的含量高。

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