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Difference in bound rubber formation of silica and carbon black with styrene butadiene rubber

机译:二氧化硅和炭黑与丁苯橡胶的结合橡胶形成差异

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摘要

Formation of bound rubber is affected by the physical structure and surface chemistry of filler and the property of rubber. Variation of the bound rubber formation in styrene-butadiene rubber compounds filled with silica and/or carbon black was studied. Influence of temperature on extraction of loosely bound rubber was also investigated. For the both silica and carbon black-filled compounds, the bound rubber content increases with increase in the silica content ratio. The bound rubber content decreases with increasing the extracting temperature. The loosely bound rubber content of the silica-filled compound is higher than that of the carbon black-filled one. Activation energy for the extraction of the unbound and loosely bound rubbers becomes higher as the total filler content increases. The activation energy of the silica-filled compound is higher (almost double the value) than for the carbon black-filled one.
机译:粘合橡胶的形成受填料的物理结构和表面化学性质以及橡胶性能的影响。研究了填充有二氧化硅和/或炭黑的丁苯橡胶胶料中结合橡胶形成的变化。还研究了温度对松散结合的橡胶提取的影响。对于二氧化硅和炭黑填充的化合物,结合的橡胶含量随二氧化硅含量比的增加而增加。结合橡胶含量随提取温度的升高而降低。填充二氧化硅的化合物的松散结合橡胶含量高于填充炭黑的橡胶。随着总填料含量的增加,用于萃取未结合和松散结合的橡胶的活化能变得更高。二氧化硅填充的化合物的活化能比炭黑填充的化合物高(几乎是该值的两倍)。

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