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Synthesis of high performance, conductive PEDOT-coated polyester yarns by OCVD technique

机译:用OCVD技术合成高性能,导电的PEDOT包覆的涤纶纱

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Production of high performance conductive textile yarn fibers for different electronic applications has become a prominent area of many research groups throughout the world. We have used oxidative chemical vapor deposition (OCVD) technique to coat flexible and high strength polyester yarns with conjugated polymer, poly(3,4-ethylenedioxythiophene) (PEDOT) in presence of ferric (III) chloride (FeCl_3) oxidant. OCVD is an efficient solvent free technique used to get uniform, thin, and highly conductive polymer layers on different substrates. In this paper, PEDOT-coated polyester (PET) yarns were prepared under specific reaction conditions, and the electrical, mechanical and thermal properties were compared to previously studied PEDOT-coated viscose yarns. Scanning electron microscopy (SEM) and FT-IR analysis revealed that polymerization of PEDOT on the surface of the polyester yarns has been taken place successfully and structural analysis showed that PEDOT has strong interactions with viscose yarns as compared to PET yarns. The voltage-current (V-I) characteristics showed that PET yarns are more conductive than PEDOT-coated viscose yarns. The variation in the conductivity of PEDOT-coated yarns and the heat generation properties during the flow of current through coated yarns for longer period of time, was studied by time-current (t-I) characteristics. Thermogravimeteric analysis (TGA) was employed to investigate the thermal properties and the amount of PEDOT in PEDOT-coated PET yarns compared to PEDOT-coated viscose. The effect of PEDOT coating and ferric (III) chloride concentration on the mechanical properties of coated yarns was evaluated by tensile testing. The obtained PEDOT-coated conductive polyester yarns could be used in smart clothing for medical and military applications.
机译:用于不同电子应用的高性能导电纺织纱线纤维的生产已成为全世界许多研究小组的重点领域。我们已经使用氧化化学气相沉积(OCVD)技术在氯化铁(III)(FeCl_3)氧化剂存在的情况下,用共轭聚合物,聚(3,4-乙撑二氧噻吩)(PEDOT)涂覆柔性高强度聚酯纱线。 OCVD是一种有效的无溶剂技术,用于在不同的基板上获得均匀,薄而高导电性的聚合物层。在本文中,在特定的反应条件下制备了涂有PEDOT的聚酯(PET)纱线,并将电,机械和热性能与先前研究的涂有PEDOT的粘胶纱线进行了比较。扫描电子显微镜(SEM)和FT-IR分析表明,PEDOT在聚酯纱线表面上已经成功地发生了聚合,并且结构分析表明,与PET纱线相比,PEDOT与粘胶纱线具有很强的相互作用。电压-电流(V-I)特性表明,PET纱线比PEDOT包覆的粘胶纱线更具导电性。通过时间-电流(t-I)特性研究了PEDOT包覆纱线的导电率和电流在较长时间内流过包覆纱线的过程中的发热特性。使用热重分析(TGA)来研究与PEDOT包覆的粘胶相比,PEDOT包覆的PET纱线的热性能和PEDOT的含量。通过拉伸试验评估了PEDOT涂层和氯化铁(III)浓度对涂层纱线机械性能的影响。所得的涂覆PEDOT的导电聚酯纱可用于医疗和军事应用的智能服装。

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