Architectures of novel fluorinated block copolymers fuelled by a poor radical polymerizable characteristic of 1,3-divinyltetramethyldisiloxane

Hideo Sawada; Masaru Suzuki; Masaki Mugisawa

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Architectures of novel fluorinated block copolymers fuelled by a poor radical polymerizable characteristic of 1,3-divinyltetramethyldisiloxane

机译：1,3-二乙烯基四甲基二硅氧烷自由基聚合性差的新型氟化嵌段共聚物的结构

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Fluoroalkanoyl peroxide was reacted with 1,3-divinyltetramethyldisiloxane under very mild conditions to afford the fluoroalkyl end-capped vinylsilane oligomer containing vinyldimethylsiloxane segments. This fluoroalkyl end-capped vinylsilane oligomer was applied to the preparation of novel fluorinated block copolymers by the copolymerizations with traditional radical polymerizable monomers. It was demonstrated that these fluorinated block copolymers thus obtained can form the dendritic-type unimolecular micelles in aqueous solutions, and these fluorinated block copolymers were able to provide suitable host moieties to interact with fullerenes as guest molecules.

机译：使氟代烷酰基过氧化物与1，3-二乙烯基四甲基二硅氧烷在非常温和的条件下反应，得到含乙烯基二甲基硅氧烷链段的氟代烷基封端的乙烯基硅烷低聚物。通过与传统的自由基可聚合单体共聚，将该氟代烷基封端的乙烯基硅烷低聚物用于制备新型氟化嵌段共聚物。证明了由此获得的这些氟化嵌段共聚物可以在水溶液中形成树枝状型单分子胶束，并且这些氟化嵌段共聚物能够提供合适的主体部分以作为客体分子与富勒烯相互作用。

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《Polymers for advanced technologies》 |2006年第1期|共4页
作者
Hideo Sawada; Masaru Suzuki; Masaki Mugisawa;
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正文语种 eng
中图分类高分子化学（高聚物）;
关键词
Block copolymers; Fluoroalkanoyl peroxide; Fluorinated vinylsilanes; Fullerene; Micelles;

机译：嵌段共聚物;氟代链烷酰过氧化物;氟化乙烯基硅烷;富勒烯;胶束;

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1. Architectures of novel fluorinated block copolymers fuelled by a poor radical polymerizable characteristic of 1,3-divinyltetramethyldisiloxane [J] . Hideo Sawada, Masaru Suzuki, Masaki Mugisawa Polymers for advanced technologies . 2006,第1期

机译：1,3-二乙烯基四甲基二硅氧烷自由基聚合性差的新型氟化嵌段共聚物的结构
2. Sulfonated fluorinated multi-block copolymer hybrid containing sulfonated(poly ether ether ketone) and graphene oxide: A ternary hybrid membrane architecture for electrolyte applications in proton exchange membrane fuel cells [J] . Ae Rhan Kim, Mohanraj Vinothkannan, Dong Jin Yoo 天然气化学（英文版） . 2018,第004期

机译：含磺化（聚醚醚酮）和氧化石墨烯的磺化氟化多嵌段共聚物杂化物：质子交换膜燃料电池电解质应用的三元杂化膜结构
3. Sulfonated fluorinated multi-block copolymer hybrid containing sulfonated（poly ether ether ketone） and graphene oxide： A ternary hybrid membrane architecture for electrolyte applications in proton exchange membrane fuel cells [J] . Ae Rhan Kim, Mohanraj Vinothkannan, Dong Jin Yoo 能源化学：英文版 . 2018,第004期

机译：含磺化（聚醚醚酮）和氧化石墨烯的磺化氟化多嵌段共聚物杂化物：质子交换膜燃料电池电解质应用的三元杂化膜结构
4. Study on Synthesis of a Fluorinated Block Copolymer by Atom Transfer Radical Polymerization(ATRP) [C] . Jian-AnJiang, Jia-JuiYuan, Yong-MingZhang Sino-Japan Conference of Fluorochemical Engineering amp; Fine Chemicals(FChina2001); 20010522-26; Xi'an(CN) . 2001

机译：原子转移自由基聚合（ATRP）合成含氟嵌段共聚物的研究
5. I.Polyhomologation. Application for the synthesis of polymethylene block copolymers and discovery of new polymerizable ylides. II. Synthesis and evaluation of molecularly imprinted polymer membranes. [D] . Zhou, Xianzhi. 2002

机译：一，多同源。在聚亚甲基嵌段共聚物的合成中的应用以及发现新的可聚合烷基化物。二。分子印迹聚合物膜的合成和评估。
6. Comparing blends and blocks: Synthesis of partially fluorinated diblock polythiophene copolymers to investigate the thermal stability of optical and morphological properties [O] . Pierre Boufflet, Sebastian Wood, Jessica Wade, 2016

机译：共混物和嵌段的比较：部分氟化的二嵌段聚噻吩共聚物的合成以研究光学和形态学性质的热稳定性
7. Fluorinated Poly(ionic liquid) Diblock Copolymers Obtained by Cobalt-Mediated Radical Polymerization-Induced Self-Assembly [O] . -1

机译：通过钴介导的自由基聚合诱导的自组装获得的氟化聚（离子液体）二嵌段共聚物

Architectures of novel fluorinated block copolymers fuelled by a poor radical polymerizable characteristic of 1,3-divinyltetramethyldisiloxane

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