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Curing behavior and toughening performance of epoxy resins containing hyperbranched polyester

机译:含超支化聚酯的环氧树脂的固化行为和增韧性能

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摘要

The effects of the hyperbranched polyester with hydroxyl end groups (HBPE-OH) on the curing behavior and toughening performance of a commercial epoxy resin (diglycidyl ether of bisphenol A, DGEBA) were presented. The addition of HBPE-OH into DGEBA strongly increased its curing rate and conversion of epoxide group due to the catalytic effect of hydroxyl groups in HBPE-OH and the low viscosity of the blend at curing temperature. The improvements on impact strength and critical stress intensity factor (or fracture toughness, K{sub}(1C)) were observed with adding HBPE-OH. The impact strength was 8.04 kjm{sup}(-1) when HBPE-OH reached 15wt% and the K{sub}(1C) value was approximately two times the value of pure epoxy resin when HBPE-OH content was 20wt%. The morphology of the blends was also investigated, which indicated that HBPE-OH particles, as a second phase in the epoxy matrix, combined with each other as the concentration of HBPE-OH increased.
机译:提出了具有羟基端基的超支化聚酯(HBPE-OH)对市售环氧树脂(双酚A的二缩水甘油醚,DGEBA)的固化行为和增韧性能的影响。由于HBPE-OH中羟基的催化作用以及共混物在固化温度下的低粘度,向DGEBA中添加HBPE-OH极大地提高了其固化速率和环氧基的转化率。加入HBPE-OH后,观察到冲击强度和临界应力强度因子(或断裂韧性​​,K {sub}(1C))的改善。当HBPE-OH达到15wt%时,冲击强度为8.04kjm {sup}(-1),并且当HBPE-OH含量为20wt%时,K {sub}(1C)值约为纯环氧树脂的两倍。还研究了共混物的形态,这表明作为环氧基质中第二相的HBPE-OH颗粒随着HBPE-OH浓度的增加而彼此结合。

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