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The preparation of biodegradable polyurethane/carbon nanotube composite based on in situ cross-linking

机译:基于原位交联的可生物降解聚氨酯/碳纳米管复合材料的制备

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摘要

A biodegradable polyurethane (PU)/carbon nanotube (CNT) composite was prepared by bulk polymerization based on in situ cross-linking of hydroxyl-terminated polylactic acid functionalized CNTs. As parallel experiments, PU/CNT blend and pure PU were prepared. The obtained products were characterized by Fourier transform infrared (FTIR), thermogravimetric analyses (TGA) and differential scanning calorimetry (DSC), hydrogen nuclear magnetic resonance (1{sup left}H NMR) and field emission scanning electron microscopy (FESEM). The properties and morphology of composites were discussed including both blending and cross-linking composites. The results showed that the functionalized CNTs were dispersed well in the PU matrix, and its initial thermal decomposition temperature was higher than that of the blend.
机译:基于羟基封端的聚乳酸官能化碳纳米管的原位交联,通过本体聚合制备了可生物降解的聚氨酯(PU)/碳纳米管(CNT)复合材料。作为平行实验,制备了PU / CNT共混物和纯PU。所获得的产物通过傅里叶变换红外光谱(FTIR),热重分析(TGA)和差示扫描量热法(DSC),氢核磁共振(1H NMR)和场发射扫描电子显微镜(FESEM)进行表征。讨论了复合材料的性能和形态,包括共混和交联复合材料。结果表明,功能化的CNTs分散在PU基体中,其初始热分解温度高于共混物。

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