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Super absorbent resins, their synthesis, structure and characterization

机译:高吸水性树脂,其合成,结构和表征

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摘要

Superabsorbent resin (SAP) is a kind of functional polymer material which can absorbs hundreds, even more than thousand, times of water as much as its own weight with good water retention performance under pressure. Owning to its excellent properties, SAP has wide uses and prospects in such areas including hygiene, medical, food, cosmetic, soil amelioration, plant cultivation, packaging, construction materials etc., and received ever-increasing interest among the peoples. Nowadays, SAP comprised of poly (acrylic acid-sodium acrylate) can be achieved by the common polymerization methods including suspension polymerization, solution polymerization, grafting copolymerization and inverse emulsion polymerization. In this paper, we proposed an example of fast, easy controlled UV photopolymerization method in the synthesis of poly (acrylic acid-sodium acrylate) SAP. The effects of the photoinitiators, crosslinking agents, degree of neutralization and exposing time on the properties of thus-synthesized SAP were also studied.
机译:超吸收性树脂(SAP)是一种功能性高分子材料,可吸收相当于其自重的数百倍甚至数千倍的水,并在压力下具有良好的保水性能。由于其优异的性能,SAP在卫生,医疗,食品,化妆品,土壤改良,植物栽培,包装,建筑材料等领域具有广泛的应用和前景,受到了人们越来越多的关注。如今,由聚(丙烯酸-丙烯酸钠)组成的SAP可以通过常见的聚合方法来实现,包括悬浮聚合,溶液聚合,接枝共聚和反相乳液聚合。在本文中,我们提出了一个快速,易于控制的紫外光聚合方法在聚(丙烯酸-丙烯酸钠)SAP合成中的实例。还研究了光引发剂,交联剂,中和度和曝光时间对如此合成的SAP性能的影响。

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