Aliphatic poly(silyl ether)s by Ru-catalyzed hydrosilylation copolymerization of aliphatic α,ω-diketones with α,ω-dihydrido-oligodimethylsiloxanes

Joseph M. Mabry; William P. Weber

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Aliphatic poly(silyl ether)s by Ru-catalyzed hydrosilylation copolymerization of aliphatic α,ω-diketones with α,ω-dihydrido-oligodimethylsiloxanes

机译：脂肪族α，ω-二酮与α，ω-二氢-低聚二甲基硅氧烷的Ru催化加氢硅烷化共聚合的脂肪族聚甲硅烷基醚

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The hydrosilylation copolymerization of aliphatic α,ω-diketones with α,ω-dihydrido-oligodimethylsiloxanes is catalyzed by dihydridocarbonyltris-(triphenylphosphine)ruthenium (Ru), activated with a stoichiometric amount of styrene, to yield poly(silyl ether)s. These copolymers have been characterized spectroscopically by ~1H, ~(13)C, and ~(29)Si NMR, as well as by IR. Their molecular weight distributions (M_w/M_n) have been determined by GPC, their thermal stability by TGA, and their glass transition temperatures (T_gs) measured by DSC. End group analysis provides an independent measure of M_n. The effect of the length of the oligodimethylsiloxane unit on T_g, and chiral centers on ~(13)C and ~(29)Si NMR spectra are discussed.

机译：脂肪族α，ω-二酮与α，ω-二氢-低聚二甲基硅氧烷的硅氢加成共聚反应是由化学计量的苯乙烯活化的二氢羰基三（三苯基膦）钌（Ru）催化的，从而得到聚（甲硅烷基醚）。这些共聚物已通过〜1H，〜（13）C和〜（29）Si NMR以及IR进行了光谱表征。它们的分子量分布（M_w / M_n）由GPC确定，其热稳定性由TGA确定，其玻璃化转变温度（T_gs）由DSC测量。端基分析提供了M_n的独立度量。讨论了低聚二甲基硅氧烷单元的长度对T_g的影响以及手性中心对〜（13）C和〜（29）Si NMR谱的影响。

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《Polymer Preprints》 |2001年第1期|共2页
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Joseph M. Mabry; William P. Weber;
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正文语种 eng
中图分类高分子化学（高聚物）;有机化学;
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1. Aliphatic poly(silyl ether)s by Ru-catalyzed hydrosilylation copolymerization of aliphatic α,ω-diketones with α,ω-dihydrido-oligodimethylsiloxanes [J] . Joseph M. Mabry, William P. Weber Polymer Preprints . 2001,第1期

机译：脂肪族α，ω-二酮与α，ω-二氢-低聚二甲基硅氧烷的Ru催化加氢硅烷化共聚合的脂肪族聚甲硅烷基醚
2. Aliphatic poly(silyl ether)s by Ru-catalyzed hydrosilylation copolymerization of aliphatic α,ω-diketones with α,ω-dihydrido-oligodimethylsiloxanes [J] . Joseph M. Mabry, William P. Weber Polymer Preprints . 2001,第1期

机译：脂肪族α，ω-二酮与α，ω-二氢-低聚二甲基硅氧烷的Ru催化加氢硅烷化共聚合的脂肪族聚甲硅烷基醚
3. Poly(silyl ether)s by ruthenium-catalyzed hydrosilylation polymerization of aliphatic omega-dimethylsilyloxy ketones and copolymerization of aliphatic alpha,omega-diketones with alpha,omega-dihydridooligodimethylsiloxanes [J] . Mabry JM., Runyon MK., Weber WP. Macromolecules . 2002,第6期

机译：脂肪族ω-二甲基甲硅烷氧基酮的钌催化加氢硅烷化聚合反应，以及脂肪族α，ω-二酮与α，ω-二氢低聚二甲基硅氧烷的共聚
4. Ru-Catalyzed Hydrosilylation Polymerization: An Overview of RuH_2(CO)(PPh_3)_3-Catalyzed Hydrosilylation Copolymerizations of α,ω-Diketones with α,ω-Dihydrido-oligo-dimethylsiloxanes and Polymerizations of ω-Dimethylsilyloxy Ketones [C] . Joseph M. Mabry, Matthew K. Runyon, Jyri K. Paulasaari, American Chemical Society . 2003

机译：Ru催化的氢化硅烷化聚合：α，ω-二酮与α，ω-二羟基 - 寡聚二甲基硅氧烷和ω-二甲基甲硅烷基酮的聚合的α，ω-diketone的α，ω-diketone的β-催化氢化硅烷化共聚的概述
5. Block copolyesters based on poly(lactide) and aromatic-aliphatic polyesters of the AA/BB type and acid functionalized poly(lactide) and poly(ester-urethane)s therefrom. [D] . Cooper, Timothy Russell. 2007

机译：基于AA / BB型聚（丙交酯）和芳族脂族聚酯以及由其制得的酸官能化聚（丙交酯）和聚（酯-氨基甲酸酯）的嵌段共聚酯。
6. Organocatalyzed ring-opening copolymerization of α-bromo-γ-butyrolactone with ε-caprolactone for the synthesis of functional aliphatic polyesters – pre-polymers for graft copolymerization [O] . Chen Gao, Chi-Hui Tsou, Chun-Yan Zeng, 2018

机译：α-溴-γ-丁内酯与ε-己内酯的有机催化开环共聚反应以合成功能性脂肪族聚酯-接枝共聚的预聚物
7. EFSA ; Scientific Opinion on Flavouring Group Evaluation 59, Revision 1 (FGE.59Rev1): Consideration of aliphatic and aromatic ethers evaluated by JECFA (61st meeting and 63rd meeting) structurally related to aliphatic, alicyclic and aromatic ethers including anisole derivatives evaluated by EFSA in FGE.23 Rev2 (2010) [O] . Larsen John Christian, Nørby Karin Kristiane, Beltoft Vibe Meister, 2011

机译：EFsa;关于调味组评价的科学观点59，修订版1（FGE.59Rev1）：考虑由JECFa（第61次会议和第63次会议）评价的脂族和芳族醚在结构上与脂肪族，脂环族和芳族醚相关，包括由EFsa在FGE中评价的苯甲醚衍生物。 23 Rev2（2010）
8. Scientific Literature Review of Aliphatic Ethers in Flavor Usage. Volume 1. Introduction and Summary, Tables of Data, Bibliography [R] . 1983

机译：风味剂中脂肪族醚的科学文献综述。第1卷。简介和摘要，数据表，参考书目

Aliphatic poly(silyl ether)s by Ru-catalyzed hydrosilylation copolymerization of aliphatic α,ω-diketones with α,ω-dihydrido-oligodimethylsiloxanes

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