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首页> 外文期刊>Chemical Reviews >Pillar-Shaped Macrocyclic Hosts Pillar[n]arenes: New Key Players for Supramolecular Chemistry
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Pillar-Shaped Macrocyclic Hosts Pillar[n]arenes: New Key Players for Supramolecular Chemistry

机译：柱状大环主体柱[n]芳烃：超分子化学的新关键参与者

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In 2008, we reported a new class of pillar-shaped macrocyclic hosts, known as "pillar[n]arenes". Today, pillar[n]arenes are recognized as key players in supramolecular chemistry because of their facile synthesis, unique pillar shape, versatile functionality, interesting host-guest properties, and original supramolecular assembly characteristics, which have resulted in numerous electrochemical and biomedical material applications. In this Review, we have provided historical background to macrocyclic chemistry, followed by a detailed discussion of the fundamental properties of pillar[n]arenes, including their synthesis, structure, and host guest properties. Furthermore, we have discussed the applications of pillar[n]arenes to materials science, as well as their applications in supramolecular chemistry, in terms of their fundamental properties. Finally, we have described the future perspectives of pillar[n]arene chemistry. We hope that this Review will provide a useful reference for researchers working in the field and inspire discoveries concerning pillar[n]arene chemistry.
机译：在2008年，我们报告了一种新型的柱状大环宿主，称为“柱芳烃”。如今，支柱[n]芳烃因其易于合成，独特的支柱形状，多功能的功能，有趣的主体-客体特性以及原始的超分子组装特性而被公认为超分子化学的关键参与者，从而导致了众多电化学和生物医学材料的应用。在本综述中，我们提供了大环化学的历史背景，然后详细讨论了支柱芳烃的基本性质，包括其合成，结构和宿主客体性质。此外，就其基本性质而言，我们已经讨论了支柱芳烃在材料科学中的应用及其在超分子化学中的应用。最后，我们描述了芳烃化学的未来前景。我们希望这篇综述将为从事该领域的研究人员提供有用的参考，并激发有关芳烃化学的发现。

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