Recent Advances in the Stereoselective Synthesis of Aziridines

Leonardo Degennaro; Piera Trinchera; Renzo Luisi

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Recent Advances in the Stereoselective Synthesis of Aziridines

机译：氮丙啶立体选择性合成的最新进展

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Aziridines, the smallest nitrogen-containing heterocycles, are useful building blocks in synthesis, as well as important synthetic targets (Scheme 1). The interest toward synthetic methodologies for the preparation of the aziridinyl system has increased in the last decades. Such interest for this small heterocycle is dictated either by the biological activity, mainly as antitumor agents, displayed by some naturally occurring compounds bearing the aziridine ring or by the ring strain of those spring-loaded heterocycles that make them useful precursors of more complex molecules. By ring cleavage, several useful molecules, such as amines, amino acids, amino alcohols, and other nitrogen-containing compounds, could be obtained.

机译：氮丙啶是最小的含氮杂环，是合成中的重要组成部分以及重要的合成靶标（方案1）。在最近的几十年中，对用于制备叠氮基系统的合成方法的兴趣增加了。对这种小杂环化合物的兴趣由生物学活性（主要是作为抗肿瘤药），某些带有氮丙啶环的天然存在的化合物或那些弹簧加载的杂环的环应变所决定，这些弹簧使其成为更复杂分子的有用前体。通过环裂解，可以获得几种有用的分子，例如胺，氨基酸，氨基醇和其他含氮化合物。

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来源
《Chemical Reviews》 |2014年第16期|共49页
作者
Leonardo Degennaro; Piera Trinchera; Renzo Luisi;
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正文语种 eng
中图分类化学;
关键词
Stereoselective; Synthesis; Aziridines;

机译：立体选择性;合成;氮丙啶;

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1. Recent Advances in the Stereoselective Synthesis of Aziridines [J] . Leonardo Degennaro, Piera Trinchera, Renzo Luisi Chemical Reviews . 2014,第16期

机译：氮丙啶立体选择性合成的最新进展
2. Regio- and Stereoselective Synthesis of N-H Aziridines by N-N Bond Reduction of N-Quinazolinyl Aziridines [J] . Koohang Ali Tetrahedron . 1999,第32期

机译：N-喹唑啉基氮丙啶的N-N键还原反应，选择性合成N-H氮丙啶
3. Synthesis of Methyl L-Kijanosides by Regio- and Stereoselective Ring Opening of 2-Oxazolidinone-Fused Aziridines [J] . Liu Chi-Yun, Angamuthu Venkatachalam, Chen Wei-Chen, Organic letters . 2020,第6期

机译：用2-恶唑烷酮融合的含二氮胺胺的Regio-and立体选择环开口合成甲基L- kijanoSides
4. ONE-POT SYNTHESIS OF PSEUDO-THIODISACCHARIDES THROUGH AZIRIDINE OPENING REACTIONS [C] . Alice Tamburrini, Nives Hribernik, Corinne Deniaud International Carbohydrate Symposium . 2018

机译：通过氮化氨酸开口反应的单壶合成假致氢糖
5. Regio- and stereoselective synthesis of quaternary centers from chiral trisubstituted aziridines and its application toward the total synthesis of ceanothine D. [D] . Forbeck, Erin M. 2009

机译：从手性三取代的氮丙啶进行的季位中心的区域和立体选择性合成及其在鲸蜡素D的全合成中的应用
6. Stereoselective Multicomponent Reactions in the Synthesis or Transformations of Epoxides and Aziridines [O] . Allan Ribeiro da Silva, Deborah Araujo dos Santos, Marcio Weber Paixão, 2019

机译：环氧和氮丙啶的合成或转化中的立体选择性多组分反应
7. Stereoselective Synthesis of (R)-((R)-1-Phenyl-2,2,2-trichloroethyl)2-(2-bromophenyl)aziridine-1-carboxylate [O] . Hélène Lebel 2019

机译：（R） - （（R）-1-苯基-2,2,2,2,2,2,2,2,2-三氯乙基）2-（2-溴苯基）二氮丁-1-羧酸盐的立体选择
8. Enolboration 7. Dicyclohexyliodoborane, a Highly Stereoselective Reagent For theEnolboration Of Tertiary Amides. Effects of Solvent And Aldolization Temperature on Stereochemistry Achieving the Stereoselective Synthesis of Either Syn or Anti Aldols [R] . Ganesan, K., Brown, H. C. 1994

机译：配合7.二环己基碘硼烷，一种高立体选择性试剂，用于叔酰胺的合成。溶剂和醛醇化温度对立体化学实现syn或anti aldols立体选择性合成的影响

Recent Advances in the Stereoselective Synthesis of Aziridines

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