Vinyl Epoxides in Organic Synthesis

Jiayun He; Jesse Ling; Pauline Chiu

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Vinyl Epoxides in Organic Synthesis

机译：有机合成中的乙烯基环氧

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Vinyl epoxides are molecules with a rich chemistry because of the strained oxirane, already a reactive moiety on its own, in proximity with a carbon-carbon double bond. The chemistry of vinyl epoxides is uniquely characterized by the conjugated reactivity of these two functional groups, which is not offered by either one of them separately. Moreover, in spite of the reactivity that vinyl epoxides exhibit, they are easily procured via simple synthetic routes. Hence, they are important building blocks having a vast potential for organic synthesis.

机译：乙烯基环氧化物是一种具有丰富化学成分的分子，这是因为应变的环氧乙烷本身已经是一个反应性部分，与碳-碳双键相邻。环氧乙烯基化合物的化学独特之处在于这两个官能团的共轭反应性，而这两个官能团中的任何一个都不能单独提供。此外，尽管环氧乙烯基化合物表现出反应性，但它们仍可通过简单的合成途径容易地获得。因此，它们是重要的组成部分，具有巨大的有机合成潜力。

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来源
《Chemical Reviews》 |2014年第16期|共92页
作者
Jiayun He; Jesse Ling; Pauline Chiu;
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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Epoxides; Organic; Synthesis;

机译：环氧;有机;合成;

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1. TELLURIUM IN ORGANIC SYNTHESIS - PREPARATION OF Z-VINYLIC CUPRATES FROM Z-VINYLIC TELLURIDES AND THEIR REACTION WITH ENONES AND EPOXIDES [Review] [J] . Tucci FC., Comasseto JV., Marino JP., The Journal of Organic Chemistry . 1996,第15期

机译：有机合成中的碲-由Z-乙烯基碲化物制备Z-乙烯基杯状产物及其与烯酮和环氧乙烷的反应[综述]
2. The practical stereocontrolled synthesis of vicinal halohydrins and haloamines from vinyl epoxides and vinyl aziridines [J] . Weselinski Lukasz J., Grillo Michael J., Tanasova Marina Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2016,第40期

机译：从乙烯基环氧化合物和乙烯基氮丙啶实际合成邻位卤代醇和卤代胺的立体控制
3. The Use of Vinyl Sulfonium Salts in the Stereocontrolled Asymmetric Synthesis of Epoxide- and Aziridine-Fused Heterocycles: Application to the Synthesis of (-)-Balanol [J] . Matthew G. Unthank, Nigel Hussain, Varinder K. Aggarwal Angewandte Chemie . 2006,第42期

机译：乙烯基ulf盐在立体控制的环氧和氮丙啶基稠合杂环的不对称合成中的应用：在合成（-）-Balanol中的应用
4. Stereoselective synthesis and use of vinyl epoxides displaying a Morita-Baylis-Hillman backbone(Abstracts) [C] . Marion Davoust, Jean-Francois, Briere European Symposium on Organic Chemistry . 2007

机译：立体选择性合成和使用乙烯基环氧化物展示Morita-Baylis-Hillman骨架（摘要）
5. Photocatalytic reactions on quantum-sized semiconductor colloids: Photoinitiated polymerization of vinylic monomers, formation of hydrogen peroxide and organic peroxides, oxidation of carboxylic acids, and synthesis of humic-like material [D] . Hoffman, Amy Jo 1993

机译：量子尺寸半导体胶体的光催化反应：乙烯基单体的光引发聚合，过氧化氢和有机过氧化物的形成，羧酸的氧化以及类腐殖质的合成
6. Enantioselective Synthesis of Oxetanes Bearing All-Carbon Quaternary Stereocenters via Iridium Catalyzed Alcohol-Vinyl Epoxide C-C Coupling [O] . Dr. Yi-An Guo, Dr. Wonchul Lee, Prof. Michael J. Krische -1

机译：铱催化的醇-乙烯基环氧C-C偶联对映合成全碳四元立体中心的氧杂环丁烷
7. Regio- and stereocontrolled synthesis of 3-substituted 1,2-diazetidines by asymmetric allylic amination of vinyl epoxide [O] . Rajkumar, Sundaram, Clarkson, Guy J., Shipman, Michael 2017

机译：通过环氧乙烯的不对称烯丙基胺化反应进行区域和立体控制的3-取代的1,2-二氮杂环丁烷的合成

Vinyl Epoxides in Organic Synthesis

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