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Fugitive emission measurements above a hard chromium plating tank using spark-induced breakdown spectroscopy(SIBS)

机译:使用火花感应击穿光谱法(SIBS)测量硬质镀铬槽上方的逸散排放

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This paper presents the results of total chromiumfugitive emissions measurements above a hard chromiumelectroplating tank at the Marine Corps Logistics Base (MCLB) inAlbany, GA. The measurements were made using OSHA DraftMethod ID-215 and a newly developed real-time monitor based onspark-induced breakdown spectroscopy (SIBS). The SIBS monitoracquired data on a five-sec time scale and was used to survey thetotal chromium concentrations above the plating bath surface overa range of ventilation rates in conjunction with operation of anexperimental liquid recirculation system. The SIBS-measuredconcentrations varied from <10#mu#g/m~3 (the lower limit ofdetection) to >1000<10#mu#g/m~3. The measured concentrationswere well correlated to distance from the plating bath surface,smoke test indications of poorly ventilated areas and ventilationflow rate. The SIBS data quantitatively agree with simultaneousinternal filter results and with the OSHA-approved air samplingfilter measurements. These results indicate the SIBS monitor iscapable of industrial hygiene monitoring of chromium in a plating environment.
机译:本文介绍了佐治亚州阿尔巴尼市海军陆战队物流基地(MCLB)的硬铬电镀槽上方的总铬逸出排放测量结果。使用OSHA DraftMethod ID-215和基于火花感应击穿光谱法(SIBS)的最新开发的实时监控器进行测量。 SIBS监控器在5秒的时间范围内获取数据,并结合实验液体再循环系统的运行情况,用于在通风速率范围内调查镀液表面上方的总铬浓度。 SIBS测得的浓度范围从<10#mu#g / m〜3(检测下限)到> 1000 <10#mu#g / m〜3。所测量的浓度与距电镀液表面的距离,通风不良区域的烟气测试指标和通风流量均具有良好的相关性。 SIBS数据在数量上与同时进行的内部过滤器结果以及OSHA认可的空气采样过滤器测量结果吻合。这些结果表明,SIBS监测仪能够在电镀环境中对铬进行工业卫生监测。

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