Chiral 2,2'-Bipyridines, 1,10-Phenanthrolines, and 2,2':6,2''-Terpyridines: Syntheses and Applications in Asymmetric Homogeneous Catalysis

Giorgio Chelucci; Randolph P. Thummel

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Chiral 2,2'-Bipyridines, 1,10-Phenanthrolines, and 2,2':6,2''-Terpyridines: Syntheses and Applications in Asymmetric Homogeneous Catalysis

机译：手性2,2'-联吡啶，1,10-菲咯啉和2,2'：6,2''-三联吡啶：合成和在不对称均相催化中的应用

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Although chiral phosphines have enjoyed a long-time popularity in the design of enantioselective catalytic systems, there has been a recent renaissance in the use of nitrogen ligands for this same purpose. This renaissance partly arises from several distinct advantages presented by nitrogen-containing ligands. First, they can often be employed in catalytic processes where the use of phosphines may be incompatible with the reaction conditions. Second, many nitrogen ligands are now available in enantiomerically pure form. Third, ligands that bind through nitrogen are known to coordinate with a wide variety of metal ions, and considerable progress has been made in understanding the role which these ligands play in affecting catalytic processes.

机译：尽管手性膦在对映选择性催化体系的设计中已长期受到欢迎，但最近将氮配体用于此目的已开始复兴。这种复兴部分源于含氮配体所呈现的几个独特优势。首先，它们通常可以用于其中膦的使用可能与反应条件不相容的催化过程中。其次，现在有许多对映体纯形式的氮配体。第三，已知通过氮结合的配体与多种金属离子配位，并且在理解这些配体在影响催化过程中所起的作用方面已经取得了相当大的进步。

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《Chemical Reviews》 |2002年第9期|共42页
作者
Giorgio Chelucci; Randolph P. Thummel;
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中图分类化学;化学工业;
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1. Chiral 2,2'-Bipyridines, 1,10-Phenanthrolines, and 2,2':6,2''-Terpyridines: Syntheses and Applications in Asymmetric Homogeneous Catalysis [J] . Giorgio Chelucci, Randolph P. Thummel Chemical Reviews . 2002,第9期

机译：手性2,2'-联吡啶，1,10-菲咯啉和2,2'：6,2''-三联吡啶：合成和在不对称均相催化中的应用
2. N-15 NMR coordination shifts in Pd(II), Pt(II), Au(III), Co(III), Rh(III), Ir(III), Pd(IV), and Pt(IV) complexes with pyridine, 2,2 '-bipyridine, 1,10-phenanthroline, quinoline, isoquinoline, 2,2 '-biquinoline, 2,2 ': 6 ', 2 '-terpyridine and their alkyl or aryl derivatives [J] . Pazderski L Magnetic Resonance in Chemistry: MRC . 2008,第Suppla期

机译：Pd（II），Pt（II），Au（III），Co（III），Rh（III），Ir（III），Pd（IV）和Pt（IV）与吡啶配合物中的N-15 NMR配位移位，2,2'-联吡啶，1,10-菲咯啉，喹啉，异喹啉，2,2'-联喹啉，2,2'：6'，2'-联吡啶及其烷基或芳基衍生物
3. N-15 NMR coordination shifts in Pd(II), Pt(II), Au(III), Co(III), Rh(III), Ir(III), Pd(IV), and Pt(IV) complexes with pyridine, 2,2 '-bipyridine, 1,10-phenanthroline, quinoline, isoquinoline, 2,2 '-biquinoline, 2,2 ': 6 ', 2 '-terpyridine and their alkyl or aryl derivatives [J] . Pazderski L Magnetic Resonance in Chemistry: MRC . 2008,第Suppla期

机译：Pd（II），Pt（II），Au（III），Co（III），Rh（III），Ir（III），Pd（IV）和Pt（IV）与吡啶配合物中的N-15 NMR配位移位，2,2'-联吡啶，1,10-菲咯啉，喹啉，异喹啉，2,2'-联喹啉，2,2'：6'，2'-联吡啶及其烷基或芳基衍生物
4. Copper-Catalyzed Coupling Reactions of Aryl Halides and Phenols by 4,4’-Dimethoxy-2,2’-bipyridine and 4,7-dimethoxy-1,10-phenanthroline [C] . Yingying Zhao, Xiangyong Wang, Koichi Kodama 日本化学会春季年会講演予稿集 . 2018

机译：芳基卤化物和酚的铜催化偶联反应4,4'-二甲氧基-2,2'-Bi吡啶和4,7-二甲氧基-1,10-菲咯啉
5. Synthesis and Characterization of [Ru(tpyOH)(bpy)(H2O)][OTf]2 (tpyOH = 4′-Hydroxy-2,2’:6′, 2″- Terpyridine, Bpy = 2,2′-Bipyridine) for Water Oxidation Catalysis [D] . Isaacs, Diane Pearl. 2019

机译：[Ru（TPYOH）（BPY）（H2O）] [otf] 2（TPYOH = 4'-羟基-2,2'：6'，2“ - Terpyridine，BPy = 2,2'- Bi吡啶）的合成与表征用于水氧化催化
6. (5,5′-Dicarboxybiphenyl-2,2′-dicarboxylato-κ2 O 2,O 2′)bis(1,10-phenanthroline-κ2 N,N′)cobalt(II) dihydrate [O] . Ruizhan Chen, Feijun Guo, Fanlei Meng 2015

机译：（5,5'-二羧基联苯-2,2'-二羧基lato-κ2 Ø 2，O 2'）双（1,10-菲咯啉-κ2） N，N'）二水合钴（II）
7. 2,2′-Dipyridylamines: more than just sister members of the bipyridine family. Applications and achievements in homogeneous catalysis and photoluminescent materials [O] . S. Wang, C. Bruneau, J.-L. Renaud, 2019

机译：2,2'-双吡啶胺：不仅仅是Biphyridine家族的姐妹成员。均匀催化和光致发光材料中的应用和成果
8. Electropolymerization of Ruthenium Bis(1,10-phenanthroline)(4-methyl-4'vinyl-2,2'-bipyridine) Complexes through Direct Attack on the Ligand Ring System [R] . Guarr, T. F., Anson, F. C. 1987

机译：直接攻击配体环系统对双（1,10-菲咯啉）（4-甲基-4'-乙烯基-2,2'-联吡啶）配合物的电聚合

Chiral 2,2'-Bipyridines, 1,10-Phenanthrolines, and 2,2':6,2''-Terpyridines: Syntheses and Applications in Asymmetric Homogeneous Catalysis

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