RDX and HMX with Reduced Sensitivity Towards Shock Initiation-RS-RDX and RS-HMX

Oyvind Hammer Johansen; Jern Digre Kristiansen; Richard Gjersoe

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RDX and HMX with Reduced Sensitivity Towards Shock Initiation-RS-RDX and RS-HMX

机译：RDX和HMX的震动触发灵敏度降低-RS-RDX和RS-HMX

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Reduced Sensitivity RDX (RS-RDX) has received a lot of attention and interest from the explosive community in the recent years.There are several producers of RS-RDX,most of them using a direct nitration (Woolwich process) for the RDX synthesis,while Chemring Nobel uses the Bachmann process.The processes for obtaining the RS properties probably differ between the various producers.Chemring Nobel has also developed an HMX quality that shows Reduced Sensitivity (RS-HMX) of different particle size distributions.The shock sensitivity is at the same level as for RS-RDX in comparable compositions.Reduced shock sensitivity has been obtained for RS-RDX and Reduced Sensitivity (RS-HMX) in both pressable and cast-cured compositions.By using a pressable composition,it is possible to get the results from a BICT gap test faster than from a cast-cured composition that has to go through a curing process.Chemring Nobel in cooperation with FFI have performed an extensive accelerated ageing testing of RS-RDX produced by the Bachmann process.The samples have been aged at 60 and 70 °C and the shock sensitivity tested by two different gap tests.The results demonstrate that the Chemring Nobel RS-RDX retain the insensitivity towards shock during ageing and show no degradation at all.Accelerated ageing testing of RS-HMX has also been performed and shows no degradation in the shock sensitivity.

机译：降低灵敏度的RDX（RS-RDX）近年来受到炸药界的广泛关注和关注。有几家RS-RDX生产商，其中大多数使用直接硝化（Woolwich工艺）进行RDX合成， Chemring Nobel还采用了巴合曼（Bachmann）工艺来获得RS特性的过程可能因生产商的不同而不同。在可比较的成分中与RS-RDX的水平相同。在可压制和浇铸固化的成分中，RS-RDX的减震敏感性降低，灵敏度降低（RS-HMX）。通过使用可压制的成分，可以获得BICT间隙测试的结果比必须经过固化过程的铸造固化组合物要快。诺贝尔化学与FFI合作对RS进行了广泛的加速老化测试-RDX是由巴合曼（Bachmann）工艺生产的，样品分别在60和70°C下进行了老化，并通过两种不同的间隙测试对冲击敏感性进行了测试，结果表明Chemring Nobel RS-RDX保留了老化过程中对冲击的不敏感性。 RS-HMX的加速老化测试也已经执行，并且没有显示出冲击灵敏度的下降。

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来源
《Propellants, Explosives, Pyrotechnics》 |2008年第1期|共5页
作者
Oyvind Hammer Johansen; Jern Digre Kristiansen; Richard Gjersoe;
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正文语种 eng
中图分类爆炸物工业、火柴工业;
关键词
Ageing; Crystals; RS-HMX; RS-RDX; Shock Sensitivity;

机译：老化;晶体;RS-HMX;RS-RDX;电击感度;

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1. RDX and HMX with Reduced Sensitivity Towards Shock Initiation-RS-RDX and RS-HMX [J] . Oyvind Hammer Johansen, Jern Digre Kristiansen, Richard Gjersoe Propellants, Explosives, Pyrotechnics . 2008,第1期

机译：RDX和HMX的震动触发灵敏度降低-RS-RDX和RS-HMX
2. Research on the Size of Defects inside RDX/HMX Crystal and Shock Sensitivity [J] . Hua Cheng, Zhang Pan-Jun, Lu Xiao-Jun, Propellants, Explosives, Pyrotechnics . 2013,第6期

机译：RDX / HMX晶体内部缺陷尺寸和冲击敏感性的研究
3. Fabrication of RDX, HMX and CL-20 based microcapsules via in situ polymerization of melamine-formaldehyde resins with reduced sensitivity [J] . Yang Zhijian, Ding Ling, Wu Peng, Chemical engineering journal . 2015,第Null期

机译：通过三聚氰胺-甲醛树脂的原位聚合制备具有敏感性的RDX，HMX和CL-20型微胶囊
4. Shock Sensitivity of PBX Formulations based on the RS-RDX, RS-HMX, and Fine/Ultra-Fine HE Particles Bonded with the Inert Binders:Real Time Measurements from the Registration of the Reaction Front Radiation Growth and Emission Absorption [C] . Igor Plaksin, Jose Campos, Ricardo Mendes, Energetic Materials: Processing and Product Design . 2008

机译：基于RS-RDX，RS-HMX和精细/超细HE粒子并结合有惰性粘合剂的PBX配方的震动敏感性：反应前沿辐射生长和发射吸收的配准实时测量
5. Biological treatment of 2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), and octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), and the hydrolysates of RDX and HMX. [D] . Reinhart, George Albetz, III. 2001

机译：2,4,6-三硝基甲苯（TNT），六氢-1,3,5-三硝基-1,3,5-三嗪（RDX）和八氢-1,3,5,7-四硝基-1的生物处理， 3,5,7-四唑嗪（HMX），以及RDX和HMX的水解产物。
6. Preparation and Characterization of Cyclotrimethylenetrinitramine (RDX) with Reduced Sensitivity [O] . Yuqiao Wang, Xin Li, Shusen Chen, 2017

机译：灵敏度降低的环三亚甲基三硝胺（RDX）的制备和表征
7. Effects of nano-HMX on the properties of RDX-CMDB propellant: Higher energy and lower sensitivity [O] . Gao Han, Hou Xiao-ting, Ke Xiang, 2017

机译：纳米HmX对RDX-CmDB推进剂性能的影响：能量更高，灵敏度更低
8. Theoretical Prediction of the Heats of Formation, Densities and Relative Sensitivities, and/or Synthetic Approaches Toward the Synthesis of High Energy Dense Materials (HEDMs): 3,5-Dinitro-1,3,5-Oxadiazinane, Bis-Adjacent RDX, Bis-Adjacent HMX, 4,4',6,6'-Tetranitro-1,1'-Bis(N-oxide)-5,5',6,6'-4H,4'H-5,5'-Bisimidazo Oxadiazole, and the Open-Cage Derivative of CL-20. [R] . Byrd, E. F., Sabatini, J. J. 2015

机译：形成热，密度和相对灵敏度的理论预测，和/或合成高能量密集材料（HEDms）的合成方法：3,5-二硝基-1,3,5-恶二唑烷，双相邻RDX，Bis - 相邻的HmX，4,4'，6,6'-四硝基-1,1'-双（N-氧化物）-5,5'，6,6'-4H，4'H-5,5'-双咪唑恶二唑和CL-20的开笼衍生物。

RDX and HMX with Reduced Sensitivity Towards Shock Initiation-RS-RDX and RS-HMX

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