Synthesis of Energetic Polymers by the Introduction of Energetic Groups onto Polymeric Primary and Secondary Amines

Anthony J.Bellamy; David S.King; Peter Golding

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Synthesis of Energetic Polymers by the Introduction of Energetic Groups onto Polymeric Primary and Secondary Amines

机译：通过在聚合物伯胺和仲胺上引入高能基团来合成高能聚合物

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Energetic polymers have been synthesised by the introduction of picryl groups onto linear polyethylenimine and polyvinylamine.The degree of substitution was 70-97% for polyethylenimine,depending upon the molecular weight of the polymer,and around 70% for polyvinylamine.N-Picrylation of low molecular weight,model compounds was also studied.The results illustrate the influence of molecular weight on the chemical accessibility of a reaction site and reflect the difficulty of modelling polymer modification reactions using small molecules.

机译：通过在直链聚乙烯亚胺和聚乙烯胺上引入苦味基合成高能聚合物。聚乙烯亚胺的取代度为70-97％，取决于聚合物的分子量，聚乙烯胺的取代度为70％左右。结果表明了分子量对反应位点化学可及性的影响，并反映了使用小分子模拟聚合物改性反应的难度。

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《Propellants, Explosives, Pyrotechnics》 |2004年第3期|共12页
作者
Anthony J.Bellamy; David S.King; Peter Golding;
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正文语种 eng
中图分类爆炸物工业、火柴工业;
关键词
polyethylenimine; polyvinylamine; energetic polymers; picrylation;

机译：聚乙烯亚胺;聚乙烯胺;高能聚合物;去甲基化;

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1. Synthesis of Energetic Polymers by the Introduction of Energetic Groups onto Polymeric Primary and Secondary Amines [J] . Anthony J.Bellamy, David S.King, Peter Golding Propellants, Explosives, Pyrotechnics . 2004,第3期

机译：通过在聚合物伯胺和仲胺上引入高能基团来合成高能聚合物
2. Pressure-Induced Polymerization of Carbon Monoxide:Disproportionation and Synthesis of an Energetic Lactonic Polymer [J] . W.J.Evans, M.J.Lipp, C.-S.Yoo, Chemistry of Materials: A Publication of the American Chemistry Society . 2006,第10期

机译：一氧化碳的压力诱导聚合：高能内酯聚合物的歧化和合成
3. Polymer-anchored Ru(II) complex as an efficient catalyst for the synthesis of primary amides from nitriles and of secondary amides from alcohols and amines [J] . Islam Sk Manirul, Ghosh Kajari, Roy Anupam Singha, Applied Organometallic Chemistry . 2014,第12期

机译：聚合物固定的Ru（II）配合物，可作为有效的催化剂，用于从腈类合成伯酰胺以及从醇类和胺类合成仲酰胺
4. SYNTHESIS AND PROPERTIES OF RANDOM CO-POLYMER POLY-(GA/BAMO) AS ENERGETIC BINDER [C] . Thomas Keicher, Wieland Janitschek, Uwe Schaller, International annual conference of ICT . 2014

机译：含能量的无规共聚物聚（GA / BAMO）的合成与性能
5. Reversible carbon dioxide gels: Synthesis and characterization of energetic ionic liquids; Synthesis and characterization of tetrazole monomers and polymers; Encapsulation of sodium azide for controlled release [D] . Samanta, Susnata 2007

机译：可逆的二氧化碳凝胶：高能离子液体的合成与表征；四唑单体和聚合物的合成与表征；叠氮化钠的包封控制释放
6. Synthesis Characterization Thermal Stability and Sensitivity Properties of New Energetic Polymers—PVTNP-g-GAPs Crosslinked Polymers [O] . Bo Jin, Juan Shen, Xiaoshuang Gou, 2016

机译：新型含能聚合物PVTNP-g-GAPs交联聚合物的合成表征热稳定性和敏感性
7. Synthesis, Characterization, Thermal Stability and Sensitivity Properties of New Energetic Polymers—PVTNP-g-GAPs Crosslinked Polymers [O] . Bo Jin, Juan Shen, Xiaoshuang Gou, 2016

机译：新型含能聚合物-pWTNp-g-Gaps交联聚合物的合成，表征，热稳定性和敏感性

Synthesis of Energetic Polymers by the Introduction of Energetic Groups onto Polymeric Primary and Secondary Amines

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