On the mechano-chiral effect of vortical flows on the dichroic spectra of 5-phenyl-10,15,20-tris(4-sulfonatophenyl)porphyrin J-aggregates

El-Hachemi Z; Arteaga O; Canillas A; Crusats J; Escudero C; Kuroda R; Harada T; Rosa M; Ribo JM

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On the mechano-chiral effect of vortical flows on the dichroic spectra of 5-phenyl-10,15,20-tris(4-sulfonatophenyl)porphyrin J-aggregates

机译：旋流的机械手性效应对5-苯基-10,15,20-三（4-磺酰基苯基）卟啉J聚集体的二向色光谱的影响

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Phase-modulated ellipsometry of the J-aggregates of the title porphyrin shows that the material gives a true CD signal. This confirms that there is a real chiral transfer by mechanical forces, mediated by shear gradient flows, from the macroscopic to the electronic transition level. Dislocations in the structure of the aggregate could justify the formation of chirality at the level of the electronic transitions once the mesophases can be sculptured by hydrodynamic gradient flows.

机译：标题卟啉的J-聚集体的相调制椭圆偏光法显示该物质给出了真实的CD信号。这证实了由剪切力梯度流介导的机械力存在着从宏观到电子跃迁的真正手性转移。一旦中间相可以通过流体动力学梯度流进行雕刻，聚集体结构中的位错可以证明在电子跃迁水平上形成手性是合理的。

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《Chemistry: A European journal》 |2008年第21期|共6页
作者
El-Hachemi Z; Arteaga O; Canillas A; Crusats J; Escudero C; Kuroda R; Harada T; Rosa M; Ribo JM;
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正文语种 eng
中图分类化学;
关键词
chirality; circular dichroism; porphyrinoids; self-assembly; TRANSMISSION ELLIPSOMETRY; PORPHYRINS; MOLECULES; FILM;

机译：手性;圆二色性;卟啉类;自组装;透射椭圆法;卟啉;分子;薄膜;

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1. On the mechano-chiral effect of vortical flows on the dichroic spectra of 5-phenyl-10,15,20-tris(4-sulfonatophenyl)porphyrin J-aggregates [J] . El-Hachemi Z, Arteaga O, Canillas A, Chemistry: A European journal . 2008,第21期

机译：旋流的机械手性效应对5-苯基-10,15,20-三（4-磺酰基苯基）卟啉J聚集体的二向色光谱的影响
2. 5-Phenyl-10,15,20-Tris(4-sulfonatophenyl)porphyrin: Synthesis, Catalysis, and Structural Studies [J] . Aitor Arlegui, Zoubir El-Hachemi, Joaquim Crusats, Molecules . 2018,第12期

机译：5-Phenyl-10,15,20-Tris（4-sulfonatophenyl）porphyrin：合成，催化和结构研究
3. Folding and Hydrodynamic Forces in J-Aggregates of 5-Phenyl-10,15,20-tris(4-sulfophenyl)porphyrin [J] . Carlos Escudero, Joaquim Crusats, Ismael Díez-Pérez, Angewandte Chemie . 2006,第47期

机译：5-苯基-10,15,20-三（4-磺苯基）卟啉的J聚集体的折叠和流体动力
4. Improved Synthesis of 5-(R-group)-10, 15, 20-tris(4-methylphenyl)porphyrins as Starting Compounds for the Preparation of Potential Sensitizer in Solar Cells [C] . Tingwen Jia, Yuanbin She, Haiyan Fu, International Conference on Flexible and Printed Electronics . 2015

机译：改善了5-（R-GA10）-10,15,20-TRIS（4-甲基苯基）卟啉作为制备太阳能电池潜在敏化剂的起始化合物的合成
5. Time spectral method for rotorcraft flow with vorticity confinement [D] . Butsuntorn, Nawee 2008

机译：具有旋涡约束的旋翼飞机流动的时谱方法
6. Kinetic Investigation on Tetrakis(4-Sulfonatophenyl)Porphyrin J-Aggregates Formation Catalyzed by Cationic Metallo-Porphyrins [O] . Ilaria Giuseppina Occhiuto, Roberto Zagami, Mariachiara Trapani, 2020

机译：阳离子金属卟啉催化催化催化的四（4-磺酰苯基）卟啉J-骨料形成的动力学研究
7. On the Mechano-Chiral Effect of Vortical Flows on the Dichroic Spectra of 5-Phenyl-10,15,20-tris(4-sulfonatophenyl)porphyrin J-Aggregates [O] . Zoubir El-Hachemi, Oriol Arteaga, Adolf Canillas, 2008

机译：关于5-苯基-10,15,20-Tris（4-磺酰基）卟啉J-聚集体的二色性光谱对涡流的机械手性效应

On the mechano-chiral effect of vortical flows on the dichroic spectra of 5-phenyl-10,15,20-tris(4-sulfonatophenyl)porphyrin J-aggregates

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