Fluorinated fullerenes

Taylor R.

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Fluorinated fullerenes

机译：氟化富勒烯

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Recent developments in fluorination of fullerenes coupled with HPLC separation have permitted the isolation and subsequent structural characterisation of many derivatives, a number of which have novel and unexpected structures. The good solubility of fluorofullerenes, high reactivity towards nucleophiles and enhanced dienophilicity of the unsubstituted part of the cage, as a result of electron withdrawal by the fluorines, makes fluorofullerenes promising synthons. In particular that may have enhanced performance in donor-acceptor complexes with respect to bare fullerenes. [References: 75]

机译：富勒烯氟化与HPLC分离相结合的最新发展已使许多衍生物的分离和随后的结构表征成为可能，其中许多衍生物具有新颖且出乎意料的结构。氟富勒烯的良好溶解性，对亲核试剂的高反应性以及笼中未取代部分的亲二烯性增强，这是由于氟将电子撤出的结果，使得氟富勒烯成为很有前景的合成子。特别是对于富勒烯而言，在供体-受体复合物中可能具有增强的性能。 [参考：75]

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《Chemistry: A European journal》 |2001年第19期|共10页
作者
Taylor R.;
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正文语种 eng
中图分类化学;应用化学;
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1. Facile and efficient synthesis of fluorinated fullerene-fused 1,3-dioxolanes: reaction of C_(60) with fluorinated aromatic aldehyde mediated by lithium perchlorate [J] . Hao-Nan Cheng, Yuan-Hai Zou, Jian-Min Zhang, Tetrahedron . 2014,第35期

机译：氟化富勒烯稠合的1,3-二氧戊环的简便有效合成：C_（60）与高氯酸锂介导的氟化芳香醛的反应
2. A Fluorinated Polythiophene Derivative with Stabilized Backbone Conformation for Highly Efficient Fullerene and Non-Fullerene Polymer Solar Cells [J] . Zhang Shaoqing, Qin Yunpeng, Uddin Mohammad Afsar, Macromolecules . 2016,第8期

机译：具有稳定骨架构型的氟化聚噻吩衍生物，用于高效富勒烯和非富勒烯聚合物太阳能电池
3. Solvation of C-60 Fullerene and C60F48 Fluorinated Fullerene in Molecular and Ionic Liquids [J] . Szala-Bilnik Joanna, Gomes Margarida F. Costa, Padua Agilio A. H. The journal of physical chemistry, C. Nanomaterials and interfaces . 2016,第34期

机译：C-60富勒烯和C60F48氟化富勒烯在分子和离子液体中的溶剂化
4. Structural and electrochemical properties of fullerene C_(60) and fluorinated fullerenes treated at high pressure and high temperature [C] . Akifumi Yao, Narihiro Asano, Yusuke Matsuoka, The Meeting of the Electrochemical Society . 2003

机译：富勒烯C_（60）的结构和电化学性能和高压和高温处理的氟化富硒
5. The specific heat of C(70) fullerene, nanotubes, photo-polymerized C(60) fullerene, potassium doped fullerenes, and rubidium doped fullerenes. [D] . Budraa, Nasser Khalifa. 1996

机译：C（70）富勒烯，纳米管，光聚合的C（60）富勒烯，钾掺杂的富勒烯和rub掺杂的富勒烯的比热。
6. Interaction in Li@Fullerenes and Li+@Fullerenes: First Principle Insights to Li-Based Endohedral Fullerenes [O] . Hongcun Bai, Hongfeng Gao, Wei Feng, 2019

机译：Li @ Fullerenes和Li + @ Fullerenes中的相互作用：基于锂的内面体富勒烯的第一原理见解
7. Step-Wise Computational Synthesis of Fullerene C60 derivatives. 1.Fluorinated Fullerenes C60F2k [O] . Sheka, Elena F. 2009

机译：富勒烯C60衍生物的逐步计算合成。 1.氟化富勒烯C60F2k
8. Ionic properties of hydrogenated and fluorinated fullerenes [R] . Compton, R, Hettich, R, Jin, C, 1994

机译：氢化和氟化富勒烯的离子性质

Fluorinated fullerenes

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