Total syntheses of carbohydrates: Organocatalyzed aldol additions of dihydroxyacetone

Markert M; Mahrwald R

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Total syntheses of carbohydrates: Organocatalyzed aldol additions of dihydroxyacetone

机译：碳水化合物的总合成：二羟基丙酮的有机催化羟醛加成

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The selective total synthesis of carbohydrates with defined configuration has been of great interest for a long time. This field has been the domain of enzymatic methods so far. But now the recent development of several organocatalyzed aldol methodologies has made a selective synthetic approach to configuratively defined carbohydrates possible. Ibis development and different strategies will be discussed in this concept article.

机译：长期以来，具有确定构型的碳水化合物的选择性全合成一直备受关注。迄今为止，该领域一直是酶学方法的领域。但是现在，几种有机催化的醇醛缩酮方法学的最新发展使得选择性合成的方法成为可能，从而可以构型确定碳水化合物。此概念文章将讨论宜必思的发展和不同的策略。

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《Chemistry: A European journal》 |2008年第1期|共9页
作者
Markert M; Mahrwald R;
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正文语种 eng
中图分类化学;
关键词
aldol reaction; aldolase; base catalysis; carbohydrates; organocatalysis; CATALYTIC ASYMMETRIC-SYNTHESIS; MANNICH-TYPE REACTIONS; DE-NOVO SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; ORGANIC-SYNTHESIS; AQUEOUS-MEDIA; AMINO-ACID; SMALL PEPTIDES; STEREOSELECTIVE-SYNTHESIS; CHEMOENZYMATIC SYNTHESIS;

机译：醛醇缩合反应;醛缩酶;碱催化;碳水化合物;有机催化;催化不对称合成;曼尼希型反应;从头合成;对映选择性合成;有机合成;水性介质;酰胺酸;小肽;固溶体合成;

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1. Total syntheses of carbohydrates: Organocatalyzed aldol additions of dihydroxyacetone [J] . Markert M, Mahrwald R Chemistry: A European journal . 2008,第1期

机译：碳水化合物的总合成：二羟基丙酮的有机催化羟醛加成
2. Practical Formal Total Syntheses of the Homocamptothecin Derivative and Anticancer Agent Diflomotecan via Asymmetric Acetate Aldol Additions to Pyridine Ketone Substrates [J] . Rene Peters, Martin Althaus, Christian Diolez The Journal of Organic Chemistry . 2006,第20期

机译：实用的形式全合成的喜树碱衍生物和抗癌药Diflomotecan通过不对称的乙酸羟醛添加到吡啶酮基质上。
3. A novel efficient synthesis of dihydroxyacetone phosphate and bromoacetol phosphate for use in enzymatic aldol syntheses [J] . Thierry Gefflaut, Marielle Lemaire, Marie-Lise Valentin The Journal of Organic Chemistry . 1997,第17期

机译：一种新型的高效合成磷酸二羟丙酮酯和磷酸溴丙酮醇的方法，可用于酶促羟醛合成
4. Direct Metal- and Organocatalyzed Aldol Additions of Dihydroxyacetone(Abstracts) [C] . Markert, Morris, Schetter European Symposium on Organic Chemistry . 2007

机译：直接金属和有机催化的醛醇添加二羟基丙酮（摘要）
5. Development of organocatalytic direct aldol transformations, total syntheses of brasoside and littoralisone, and progress toward the total synthesis of diazonamide A. [D] . Mangion, Ian Kyle. 2006

机译：有机催化直接羟醛转化的发展，巴西苷和立异内酯的总合成以及向重氮酰胺A的总合成方面的进展。
6. Reoptimization of the Organocatalyzed Double Aldol Domino Process to a Key Enal Intermediate and Its Application to the Total Synthesis of Δ12‐Prostaglandin J3 [O] . Dr. Andrejs Pelšs, Dr. Narasimhulu Gandhamsetty, Dr. James R. Smith, -1

机译：将有机催化的双羟醛多米诺骨牌工艺重新优化为关键的中间体中间体及其在Δ12-前列腺素J3的总合成中的应用
7. Practical Formal Total Syntheses of the Homocamptothecin Derivative and Anticancer Agent Diflomotecan via Asymmetric Acetate Aldol Additions to Pyridine Ketone Substrates [O] . -1

机译：通过不对称醋酸丙醇添加到吡啶酮底物的实际正式总合成衍生物和抗癌剂二氟锰。添加到吡啶酮基材

Total syntheses of carbohydrates: Organocatalyzed aldol additions of dihydroxyacetone

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