C80Cl12: A Chlorine Derivative of the Chiral D-2-C-80 Isomer-Empirical Rationale of Halogen-Atom Addition Pattern

Simeonov KS; Amsharov KY; Jansen M

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C80Cl12: A Chlorine Derivative of the Chiral D-2-C-80 Isomer-Empirical Rationale of Halogen-Atom Addition Pattern

机译：C80Cl12：手性D-2-C-80异构体的氯衍生物-卤素原子加成模式的经验依据

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Welcome to the family! The constitution of the chiral D-2-C-80 fullerene has been confirmed through single-crystal X-ray analysis of the chlorinated C(80C)l(12). The addition pattern of the chlorine atoms in the structure of C80Cl12 together with other structures of halogenated higher fullerenes is discussed. A stepwise principle of higher fullerene reactivity is proposed. Unusual short intermolecular chlorine-chlorine contacts are reported.

机译：欢迎来到这个家庭！通过对氯化的C（80C）1（12）进行单晶X射线分析已确定了手性D-2-C-80富勒烯的组成。讨论了C80Cl12结构中氯原子与卤代高级富勒烯其他结构的加成方式。提出了较高的富勒烯反应性的逐步原理。据报道，异常短的分子间氯-氯接触。

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《Chemistry: A European journal》 |2009年第8期|共4页
作者
Simeonov KS; Amsharov KY; Jansen M;
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正文语种 eng
中图分类化学;
关键词
chirality; chlorination; fullerenes; structure elucidation; CRYSTALLOGRAPHIC CHARACTERIZATION; HIGHER FULLERENES; CRYSTAL-STRUCTURE; CHEMISTRY; C60CL30; C-80; C-76; CAGE; NMR; CL;

机译：手性;氯化;富勒烯;结构解析;结晶学特征;富勒烯;晶体结构;化学性质;C60CL30;C-80;C-76;笼;NMR;CL;

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1. C80Cl12: A Chlorine Derivative of the Chiral D-2-C-80 Isomer-Empirical Rationale of Halogen-Atom Addition Pattern [J] . Simeonov KS, Amsharov KY, Jansen M Chemistry: A European journal . 2009,第8期

机译：C80Cl12：手性D-2-C-80异构体的氯衍生物-卤素原子加成模式的经验依据
2. 2,4,6-tri[(S)-1 '-methylbenzylamino]-1,3,5-triazine: a new NMR chiral solvating agent for 3,5-dinitrophenyl derivatives; an attempt at a chiral discrimination rationale [J] . Uccello-Barretta G., Menicagli R., Salvadori P., Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2000,第19期

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3. Chiral Guanidines-catalyzed Nucleophilic Addition Reactions Using 5H-Oxazol-4-ones: Development of Catalytic Asymmetric Syntheses of Chiral alpha-Tetrasubstituted Hydroxycarboxylic Acid Derivatives [J] . Misaki Tomonori, Sugimura Takashi 有機合成化学協会誌 . 2018,第2期

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C80Cl12: A Chlorine Derivative of the Chiral D-2-C-80 Isomer-Empirical Rationale of Halogen-Atom Addition Pattern

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