Diastereoselective, One-Pot Synthesis of Polyfunctionalized Bicyclo[3.3.1]nonanes by an Anionic Domino Process

Luciano Barboni; Serena Gabrielli; Alessandro Palmieri; Cristina Femoni; Roberto Ballini

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Diastereoselective, One-Pot Synthesis of Polyfunctionalized Bicyclo[3.3.1]nonanes by an Anionic Domino Process

机译：阴离子多米诺法非对映选择性合成多官能化双环[3.3.1]壬烷

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At the beginning of the new century, a shift in emphasis in chemistry is apparent with the desire to develop environmentally benign routes to a myriad of materials.~[1] Green chemistry approaches hold out significant potential not only for reduction of waste formation and lowering of energy costs, but also in the development of new methodologies toward previously unobtainable materials by using existing technologies.~[2, 3] Of all the existing areas of chemistry, medicinal and pharmaceutical chemistry, with their traditionally large volume of waste/product ratio, are perhaps the most ripe for greening.~[4]

机译：在新世纪之初，化学的重点已经明显转移，人们希望发展对多种材料无害于环境的途径。[1]绿色化学方法不仅在减少废物形成和减少排放方面具有巨大潜力。 [2，3]在化学，药物和药物化学的所有现有领域中，传统上浪费大量的废物/产品比例，也许是最成熟的绿化了。〜[4]

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来源
《Chemistry: A European journal》 |2009年第32期|共4页
作者
Luciano Barboni; Serena Gabrielli; Alessandro Palmieri; Cristina Femoni; Roberto Ballini;
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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
bicyclo3.3.1nonanes; dinitroalkanes; domino reactions; Michael addition; one-pot synthesis;

机译：双环[3.3.1]壬烷;二硝基烷烃;多米诺反应;迈克尔加成;一锅合成;

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1. Diastereoselective, One-Pot Synthesis of Polyfunctionalized Bicyclo[3.3.1]nonanes by an Anionic Domino Process [J] . Luciano Barboni, Serena Gabrielli, Alessandro Palmieri, Chemistry: A European journal . 2009,第32期

机译：阴离子多米诺法非对映选择性合成多官能化双环[3.3.1]壬烷
2. Domino Michael-aldol annulations for the stereocontrolled synthesis of bicyclo[3.3.1]nonane and bicyclo[3.2.1]octane derivatives [J] . Rossella Promontorio, Jean-Alexandre Richard, Charles?M. Marson RSC Advances . 2016,第115期

机译：Domino Michael-aldol用于立体控制合成的双环[3.3.1]壬烷和双环[3.2.1]辛烷衍生物
3. Progress toward the Synthesis of Garsubellin A and Related Phloroglucins: The Direct Diastereoselective Synthesis of the Bicyclo[3.3.1nonane Core [J] . Sarah J. Spessard, Brian M. Stoltz Organic letters . 2002,第11期

机译：Garsubellin A和相关的半乳糖苷合成的进展：双环[3.3.1nonane核心的直接非对映选择性合成。
4. A stepwise strategy for the synthesis of HMX from 3,7-dipropionyl-1,3,5,7-tetraazabicyclo3.3.1 nonane [C] . Yu Zhang Seminar on new trends in research of energetic materials . 2019

机译：由3,7-二丙酰基-1,3,5,7-四氮杂双环3.3.1壬烷合成HMX的分步策略
5. CHEMISTRY OF BICYCLO(3.3.1)NONANES, SOLVOLYSIS OF 1-CHLORO-3,3-DIMETHYL-2-AZABICYCLO(2.2.2)OCTANE, AND AMINATION OF ALKANES WITH TRICHLORAMINE - ALUMINUM-CHLORIDE. [D] . WNUK, THOMAS ALLAN. 1975

机译：双环（3.3.1）壬烷的化学，1-氯-3,3-二甲基-2-氮杂双环（2.2.2）辛烷的溶解以及用三氯三嗪-氯化铝胺化碱。
6. Crystal structures and supramolecular features of 99-dimethyl-37-diazabicyclo3.3.1nonane-2468-tetraone 37-diazaspirobicyclo3.3.1nonane-91′-cyclopentane-2468-tetraone and 9-methyl-9-phenyl-37-diazabicyclo3.3.1nonane-2468-tetraone dimethylformamide monosolvate [O] . Sergey Z. Vatsadze, Marina A. Manaenkova, Evgeny V. Vasilev, 2017

机译：99-二甲基-37-二氮杂双环3.3.1壬烷-2468-四酮37-二氮杂螺并双环3.3.1壬烷-9的晶体结构和超分子特征1-环戊烷 -2468-丁酮和9-甲基-9-苯基-37-二氮杂双环3.3.1壬烷-2468-丁酮二甲基甲酰胺单溶剂化物
7. Domino Michael-aldol annulations for the stereocontrolled synthesis of bicyclo3.3.1nonane and bicyclo3.2.1octane derivatives [O] . Rossella Promontorio, Jean-Alexandre Richard, Charles M. Marson 2016

机译：Domino Michael-aldol用于立体控制合成的双环3.3.1壬烷和双环3.2.1辛烷衍生物
8. Chiral Synthesis via Organoboranes. 15. Selective Reductions. 42. Asymmetric Reduction of Representative Prochiral Ketones with Potassium 9-O-(1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranosyl)-9- boratabicyclo(3.3.1)-nonane [R] . Brown, H. C., Cho, B. T., Park, W. S. 1988

机译：有机硼烷的手性合成。 15.选择性减少。 42.用9-O-（1,2：5,6-二-O-异亚丙基-α-D-葡呋喃糖基）-9-硼三环（3.3.1） - 壬烷钾不对称还原代表性前手性酮

Diastereoselective, One-Pot Synthesis of Polyfunctionalized Bicyclo[3.3.1]nonanes by an Anionic Domino Process

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