From Azides to Nitrogen-Centered Radicals: Applications of Azide Radical Chemistry to Organic Synthesis

Matteo Minozzi; Daniele Nanni; Piero Spagnolo

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From Azides to Nitrogen-Centered Radicals: Applications of Azide Radical Chemistry to Organic Synthesis

机译：从叠氮化物到以氮为中心的自由基：叠氮化物自由基化学在有机合成中的应用

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Over the last thirty years organic azides have drawn a great deal of attention as radical traps for carbon- and heteroatom-centered radicals, both in intraand in intermolecular processes. The resulting intermediates (nitrogen-centered radicals such as triazenyls, aminyls, or even iminyls) can be conveniently employed in the synthesis of a variety of cyclic and acyclic nitrogen-containing compounds.

机译：在过去的三十年中，有机叠氮化物作为分子内和分子间过程中以碳和杂原子为中心的自由基的自由基陷阱而受到了广泛的关注。所得的中间体（以氮为中心的基团，例如三氮烯基，氨基基或什至亚氨基）可方便地用于合成各种环状和无环含氮化合物。

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《Chemistry: A European journal》 |2009年第32期|共11页
作者
Matteo Minozzi; Daniele Nanni; Piero Spagnolo;
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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
aminyl radicals; azides; iminyl radicals; radicals; synthetic methods;

机译：氨基自由基;叠氮化物;亚氨基自由基;基团;合成方法;

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1. From Azides to Nitrogen-Centered Radicals: Applications of Azide Radical Chemistry to Organic Synthesis [J] . Matteo Minozzi, Daniele Nanni, Piero Spagnolo Chemistry: A European journal . 2009,第32期

机译：从叠氮化物到以氮为中心的自由基：叠氮化物自由基化学在有机合成中的应用
2. Fragmentation of Carbohydrate Anomeric Alkoxyl Radicals. A New Synthesis of Chiral β-Iodo Azides, Vinyl Azides, and 2H-Azirines [J] . Carmen R. Alonso-Cruz, Alan R. Kennedy, Maria S. Rodriguez, Organic letters . 2003,第20期

机译：碳水化合物端基烷氧基的断裂。手性β-碘叠氮化物，乙烯基叠氮化物和2H-叠氮基的新合成
3. One-pot synthesis of polymer monolithic column by combination of free radical polymerization and azide-alkyne cycloaddition "click" reaction and its application in capillary liquid chromatography [J] . Yu Ruifang, Hu Wenli, Lin Guo, RSC Advances . 2015,第13期

机译：通过自由基聚合和Azide-alkyne环加成的组合单壶合成聚合物整体柱“点击”反应及其在毛细管液相色谱中的应用
4. Femtosecond UV-pump mid-IR probe spectroscopy of the ultrafast photodissociation of azide radicals from an azidoiron(lll) complex [C] . Hendrik Vennekate, Dirk Schwarzer, Joel Torres-Alacan, International Conference on Ultrafast Phenomena . 2013

机译：Femtosecond UV-PUMP中IR探针光谱从AzidoIron（LLL）复合物中叠氮化物的超叠氮探测光谱
5. Synthesis of functionalized organic molecules using copper catalyzed cyclopropanation, atom transfer radical reactions and sequential azide-alkyne cycloaddition [D] . Ricardo, Carolynne Lacar 2011

机译：铜催化环丙烷化，原子转移自由基反应和叠氮化物-炔烃环加成反应合成功能化有机分子
6. Paradoxical potentiation of methylene blue-mediated antimicrobial photodynamic inactivation by sodium azide: Role of ambient oxygen and azide radicals [O] . Liyi Huang, Tyler G St. Denis, Yi Xuan, -1

机译：叠氮化钠的亚甲基蓝介导的抗菌光动力动力灭活的矛盾性促性：环境氧气和叠氮基的作用
7. A Strategy for Synthesis of Azide Polymers via Controlled/Living Free Radical Copolymerization of Allyl Azide under 60Co g-ray Irradiation [O] . -1

机译：60CO G射线照射下通过受控/活性自由基共聚合成叠氮化物聚合物的策略
8. Collaborative Experimental and Theoretical Study of the Photodissociation andReactions of the Azide Radical [R] . Dagdigian, P. J., Alexander, M. H. 1991

机译：叠氮自由基光解离反应的协同实验与理论研究

From Azides to Nitrogen-Centered Radicals: Applications of Azide Radical Chemistry to Organic Synthesis

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