When VSEPR Fails: Experimental and Theoretical Investigations of the Behavior of Alkaline-Earth-Metal Acetylides

Marites A. Guino-o; Jacob S. Alexander; Michael L. McKee; Haon Hope; Ulrich B. Englich; Karin Ruhlandt-Senge

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When VSEPR Fails: Experimental and Theoretical Investigations of the Behavior of Alkaline-Earth-Metal Acetylides

机译：当VSEPR失败时：碱土金属乙炔行为的实验和理论研究

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The synthesis, structural, and spectral characterization as well as a theoretical study of a family of alkaline-earth-metal acetylides provides insights into synthetic access and the structural and bonding characteristics of this group of highly reactive compounds. Based on our earlier communication that reported unusual geometry for a family of triphenylsilyl-substituted alkaline-earth-metal acetylides, we herein present our studies on an expanded family of target derivatives, providing experimental and theoretical data to offer new insights into the intensively debated theme of structural chemistry in heavy alkaline-earth-metal chemistry.

机译：一系列碱土金属乙炔化物的合成，结构和光谱表征以及理论研究，为这组高反应性化合物的合成途径以及结构和键合特征提供了见识。基于我们较早的报道，该报道报道了三苯基甲硅烷基取代的碱土金属乙炔化物家族的异常几何形状，我们在此介绍我们对扩展的目标衍生物家族的研究，提供实验和理论数据，为深入讨论的主题提供新见解重碱土金属化学中的结构化学

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《Chemistry: A European journal》 |2009年第44期|共11页
作者
Marites A. Guino-o; Jacob S. Alexander; Michael L. McKee; Haon Hope; Ulrich B. Englich; Karin Ruhlandt-Senge;
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正文语种 eng
中图分类应用化学;
关键词
acetylides; alkaline; earth metals; secondary interactions; structure-determining; factors; structure elucidation;

机译：乙炔化物;碱;地球金属;二次相互作用;结构确定;因素;结构阐明;

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1. When VSEPR Fails: Experimental and Theoretical Investigations of the Behavior of Alkaline-Earth-Metal Acetylides [J] . Marites A. Guino-o, Jacob S. Alexander, Michael L. McKee, Chemistry: A European journal . 2009,第44期

机译：当VSEPR失败时：碱土金属乙炔行为的实验和理论研究
2. The electronic structure and chemical bonding of aluminum acetylide:Al_2C_2 and Al_2C_2~-:An experimental and theoretical investigation [J] . Nathan A.Cannon, Alexander I.Boldyrev, Xi Li, The Journal of Chemical Physics . 2000,第7期

机译：乙炔铝：Al_2C_2和Al_2C_2〜-的电子结构和化学键合：实验和理论研究
3. The electronic structure and chemical bonding of aluminum acetylide:Al_2C_2 and Al_2C_2~-:An experimental and theoretical investigation [J] . Nathan A.Cannon, Alexander I.Boldyrev, Xi Li, The Journal of Chemical Physics . 2000,第7期

机译：乙炔铝：Al_2C_2和Al_2C_2〜-的电子结构和化学键合：实验和理论研究
4. Investigation of the Dynamic Behaviors of Cranes under Seismic Effects with Theoretical and Experimental Study [C] . Ahmet Sagirli, C. Oktay Azeloglu International Conference on Advances in Materials and Processing Technologies . 2012

机译：理论与实验研究对地震效应下起重机动力学的调查
5. Rheological behaviors of the fresh SFRCC extrudate: Experimental, theoretical and numerical investigations. [D] . Zhou, Xiangming. 2004

机译：新鲜SFRCC挤出物的流变行为：实验，理论和数值研究。
6. When VSEPR Fails: Experimental and Theoretical Investigations of the Behavior of Alkaline-Earth-Metal Acetylides [O] . Dr. Marites A. Guino-o, Dr. Jacob S. Alexander, Prof. Dr. Michael L. McKee, -1

机译：当vsepr失败时：碱土金属乙酰乙酰氨基的行为的实验和理论研究
7. Experimental investigation on the size effect of tensile and compression behavior of concrete and theoretical modeling of experimental data [O] . Κανός Αργύρης 2004

机译：混凝土拉伸效应尺寸和压缩性能的试验研究及理论实验数据建模
8. Dynamic Fail-Safe Behavior of Steel Structures: Theoretical and Experimental Studies of Some Steel Structures in the Area of Primary Damage [R] . Girhammar, U. A. 1980

机译：钢结构动态失效安全行为：某些钢结构在主要损伤区域的理论与实验研究

When VSEPR Fails: Experimental and Theoretical Investigations of the Behavior of Alkaline-Earth-Metal Acetylides

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