• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Chemistry: A European journal >Structure–Function Relationships in Unsymmetrical Zinc Phthalocyanines for Dye-Sensitized Solar Cells
【24h】

Structure–Function Relationships in Unsymmetrical Zinc Phthalocyanines for Dye-Sensitized Solar Cells

机译：染料敏化太阳能电池中不对称锌酞菁中的结构-功能关系

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

A series of unsymmetrical zinc phthalocyanines bearing an anchoring carboxylic function linked to the phthalocyanine ring through different spacers were designed for dye-sensitised solar cells (DSSC). The modification of the spacer group allows not only a variable distance between the dye and the nanocrystalline TiO2, but also a distinct orientation of the phthalocyanine on the semiconductor surface. The photovoltaic data show that the nature of the spacer group plays a significant role in the electron injection from the photo-excited dye into the nanocrystalline TiO2 semiconductor, the recombination rates and the efficiency of the cells. The incident monochromatic photon-to-current conversion efficiency (IPCE) for phthalocyanines bearing an insulating spacer is as low as 9%, whereas for those with a conducting spacer an outstanding IPCE 80% was obtained.
机译：为染料敏化太阳能电池（DSSC）设计了一系列带有锚定羧基官能团的不对称锌酞菁锌，它们通过不同的间隔基连接到酞菁环上。间隔基团的修饰不仅允许染料与纳米晶体TiO2之间的距离可变，而且还允许酞菁在半导体表面上的不同取向。光伏数据显示，间隔基团的性质在从光激发染料向纳米晶TiO2半导体的电子注入，重组率和电池效率中起着重要作用。带有绝缘垫片的酞菁的入射单色光子-电流转换效率（IPCE）低至9％，而对于带有导电垫片的酞菁，则获得了出色的IPCE 80％。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号