Synthesis, Characterization and Electrochemical Properties of StableOsmabenzenes Containing PPh3 Substituents

Hong Zhang; Liqiong Wu; Ran Lin; Qianyi Zhao; Guomei He; Fangzu Yang; Ting Bin Wen; Haiping Xia

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Synthesis, Characterization and Electrochemical Properties of StableOsmabenzenes Containing PPh3 Substituents

机译：含PPh3取代基稳定的间苯二酚的合成，表征和电化学性能

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Treatment of[OsCl2ACHTUNGTRENUNG(PPh3)3]with HCCCH(OH)CCH/PPh3 produces the osmabenzene[OsACHTUNGTRENUNG{CHCACHTUNGTRENUNG(PPh3)CHCACHTUNGTRENUNG(PPh3)CH}Cl2ACHTUNGTRENUNG(PPh3)2][OH](2),which is air stable in both solution and solid state.The key intermediate of the one-pot reaction,[OsCl2ACHTUNGTRENUNG{CH=CACHTUNGTRENUNG(PPh3)CH(OH)CCH}ACHTUNGTRENUNG(PPh3)2](3),and the related complex[OsACHTUNGTRENUNG(NCS)2ACHTUNGTRENUNG{CHCACHTUNGTRENUNG(PPh3)CH(OH)CCH}ACHTUNGTRENUNG(PPh3)2](7)have been isolated and characterized,further supporting the proposed mechanisms for the reaction.

机译：用HCCCH（OH）CCH / PPh3处理[OsCl2ACHTUNGTRENUNG（PPh3）3]会产生the苯[OsACHTUNGTRENUNG {CHCACHTUNGTRENUNG（PPh3）CHCACHTUNGTRENUNG（PPh3）CH} Cl2ACHTUNGTRENUNG（PPh3）2稳定的]]一锅反应的关键中间体[OsCl2ACHTUNGTRENUNG {CH = CACHTUNGTRENUNG（PPh3）CH（OH）CCH} ACHTUNGTRENUNG（PPh3）2]（3）以及相关的配合物[OsACHTUNGTRENUNG（NCS））2ACHTUNGTRENUNG {CHCACHTUNGTRENUNG（PPh3）CH（OH）CCH} ACHTUNGTRENUNG（PPh3）2]（7）已被分离和表征，进一步支持提出的反应机理。

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《Chemistry: A European journal》 |2009年第14期|共14页
作者
Hong Zhang; Liqiong Wu; Ran Lin; Qianyi Zhao; Guomei He; Fangzu Yang; Ting Bin Wen; Haiping Xia;
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正文语种 eng
中图分类应用化学;
关键词
electrochemistry; metallabenzenes; metallacycles; osmium; phosphonium salts;

机译：电化学;金属苯;金属环;phosph盐;

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1. Synthesis, Characterization and Electrochemical Properties of StableOsmabenzenes Containing PPh3 Substituents [J] . Hong Zhang, Liqiong Wu, Ran Lin, Chemistry: A European journal . 2009,第14期

机译：含PPh3取代基稳定的间苯二酚的合成，表征和电化学性能
2. Synthesis, characterization, photophysical and electrochemical properties of a new non - planar perylene diimide with electron donating substituent [J] . Mostafanejad S. Melika, Bodapati Jagadeesh B., Ozkar Saim, Optical Materials . 2018,第auga期

机译：带有给电子取代基的新型非平面per二酰亚胺的合成，表征，光物理和电化学性质
3. Synthesis, characterization, photophysical and electrochemical properties of a new non - planar perylene diimide with electron donating substituent [J] . Mostafanejad S. Melika, Bodapati Jagadeesh B., Ozkar Saim, Optical Materials . 2018,第Auga期

机译：带有给电子取代基的新型非平面per二酰亚胺的合成，表征，光物理和电化学性质
4. Synthesis, characterization and optoelectronic properties of oligo(p-phenylenvinylidenequinolines) with different substituents [C] . Justo Fabian Montiel Hernandez, Pedro Garcia Bernal, Rosa Angeles Vazquez Garcia National Congress of Science and Materials Engineering . 2014

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6. The synthesis and structural characterization of the technetium nitrosyl complexes TcCl(NO)(SC5H4N)(PPh3)2 and Tc(NO)(SC5H4N)2(PPh3) [O] . Terrence L. Nicholson, Ashfaq Mahmood, Peter Muller, -1

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7. New synthesis routes, characterization, electrochemical and spectral properties of p-substituted N-phenylpyrroles. Substituent effects [O] . A. K. D. Diaw, A. Yassar, D. Gningue-Sall, 2008

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Synthesis, Characterization and Electrochemical Properties of StableOsmabenzenes Containing PPh3 Substituents

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